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#  aug-cc-pwCVQZ-DK  EMSL  Basis Set Exchange Library  3/15/13 10:17 AM
# Elements                             References
# --------                             ----------
# Sc - Zn: N.B. Balabanov and K.A. Peterson, J. Chem. Phys., accepted (2005).
#   

# Elements                             References
# --------                             ----------
# H    :  T.H. Dunning, Jr. J. Chem. Phys. 90, 1007 (1989).
# He   :  D.E. Woon and T.H. Dunning, Jr., J. Chem. Phys. 100, 2975 (1994).
# B - F:  R.A. Kendall, T.H. Dunning, Jr. and R.J. Harrison, J. Chem. Phys. 96,
# 6796 (1992).
# Al - Cl: D.E. Woon and T.H. Dunning, Jr. J. Chem. Phys. 98, 1358 (1993).
# Sc - Zn: N.B. Balabanov and K.A. Peterson, J. Chem. Phys, 123, 064107 (2005)
# 



basis "Sc_aug-cc-pwCVQZ-DK" SPHERICAL
Sc    S
 8417909.0000000             0.0000450             -0.0000260              0.0000050             -0.0000010             -0.0000020             -0.0000030             -0.0000040        
 1260312.0000000             0.0001300             -0.0000750              0.0000150             -0.0000040             -0.0000060             -0.0000100             -0.0000100        
 286798.4000000              0.0003520             -0.0002020              0.0000400             -0.0000100             -0.0000170             -0.0000260             -0.0000280        
  81234.6900000              0.0008820             -0.0005070              0.0001000             -0.0000240             -0.0000420             -0.0000670             -0.0000700        
  26503.1100000              0.0021990             -0.0012640              0.0002490             -0.0000600             -0.0001030             -0.0001600             -0.0001810        
   9568.7010000              0.0055320             -0.0031910              0.0006330             -0.0001530             -0.0002720             -0.0004350             -0.0004320        
   3732.4970000              0.0140830             -0.0081610              0.0016220             -0.0003920             -0.0006550             -0.0010050             -0.0012120        
   1548.4220000              0.0350930             -0.0206010              0.0041490             -0.0010030             -0.0018210             -0.0029490             -0.0027520        
    675.5420000              0.0814300             -0.0489160              0.0100150             -0.0024210             -0.0039590             -0.0059720             -0.0077240        
    307.2522000              0.1645690             -0.1043990              0.0224020             -0.0054190             -0.0101080             -0.0166370             -0.0142930        
    144.6672000              0.2626320             -0.1854760              0.0427710             -0.0103610             -0.0162010             -0.0236840             -0.0351350        
     70.0438700              0.2731620             -0.2443340              0.0651430             -0.0158320             -0.0318930             -0.0549230             -0.0368140        
     34.3225000              0.1412160             -0.1538870              0.0450750             -0.0110030             -0.0102390             -0.0072170             -0.0559630        
     15.6122400              0.0704600              0.1868870             -0.0858650              0.0211590              0.0155450              0.0034090              0.1117600        
      7.7437220              0.1249190              0.5333670             -0.3310660              0.0853750              0.2031530              0.3895120              0.2141660        
      3.8442600              0.0881650              0.3687560             -0.3584680              0.0964150              0.0891500              0.0925470              0.6131590        
      1.7197660              0.0113260              0.0495060              0.2210450             -0.0709410              0.0262840             -0.0164440             -1.4758760        
      0.8325230             -0.0004190             -0.0039720              0.6853970             -0.2398400             -0.9642330             -2.3078390             -0.6976530        
      0.3855640              0.0001250              0.0001950              0.3601480             -0.2720170              0.2264090              2.7174500              2.9768830        
      0.0967000             -0.0000430             -0.0003590              0.0191690              0.3127010              2.0955710              0.0384980             -5.7468710        
      0.0477780              0.0000400              0.0002880             -0.0058640              0.6137670             -1.1942840             -2.5297130              6.9531630        
Sc    S
      0.0223630              1.0000000        
Sc    S
      3.1672000              1.0000000        
Sc    S
      1.6879000              1.0000000        
Sc    S
      0.0104700              1.0000000        
Sc    P
  22640.9700000              0.0000390             -0.0000130             -0.0000030              0.0000040              0.0000080             -0.0000090        
   5357.5450000              0.0001730             -0.0000570             -0.0000140              0.0000170              0.0000330             -0.0000440        
   1740.3730000              0.0007840             -0.0002570             -0.0000630              0.0000760              0.0001590             -0.0001670        
    666.6163000              0.0031410             -0.0010350             -0.0002520              0.0003070              0.0005920             -0.0008330        
    283.6384000              0.0111150             -0.0036790             -0.0009000              0.0010930              0.0022770             -0.0023500        
    129.7976000              0.0338110             -0.0113360             -0.0027610              0.0033720              0.0064620             -0.0091880        
     62.6795600              0.0871300             -0.0298480             -0.0073230              0.0088800              0.0186080             -0.0185450        
     31.5044100              0.1810660             -0.0640540             -0.0156550              0.0191230              0.0360080             -0.0537550        
     16.2352500              0.2894700             -0.1060770             -0.0262660              0.0317460              0.0694180             -0.0596530        
      8.5183240              0.3269550             -0.1280140             -0.0315690              0.0387620              0.0707610             -0.1569490        
      4.5190050              0.2089190             -0.0515380             -0.0120800              0.0146420              0.0575890              0.0129350        
      2.3665910              0.0541810              0.1753060              0.0527840             -0.0606900             -0.1767470              0.0894440        
      1.2152350              0.0016720              0.3929150              0.1138130             -0.1356270             -0.3333020              1.2768110        
      0.6143480             -0.0015710              0.3955600              0.1457620             -0.1751720             -0.5698890             -1.0591470        
      0.3007450             -0.0010160              0.1755030              0.0132030             -0.0771000              1.1782580             -1.3241720        
      0.1258340             -0.0000590              0.0190220             -0.3522610              0.5646910              0.5507190              2.3680990        
      0.0547190             -0.0000200              0.0000740             -0.5500870              0.5410650             -0.9782210             -1.1750710        
Sc    P
      0.0234880              1.0000000        
Sc    P
      4.0719000              1.0000000        
Sc    P
      0.9994000              1.0000000        
Sc    P
      0.0100800              1.0000000        
Sc    D
    148.0280000              0.0004900             -0.0005030             -0.0006520              0.0008350        
     43.8528000              0.0041290             -0.0042440             -0.0054270              0.0083830        
     16.6646000              0.0186860             -0.0192830             -0.0252250              0.0331020        
      6.9789300              0.0578540             -0.0603550             -0.0772000              0.1257230        
      3.1236900              0.1370780             -0.1437060             -0.1898980              0.2477730        
      1.4468700              0.2310160             -0.2301500             -0.2877690              0.4535390        
      0.6674070              0.2956830             -0.2631470             -0.1763680             -0.5351160        
      0.3016330              0.3047830             -0.0555990              0.5992450             -0.8932680        
      0.1326740              0.2399250              0.4054920              0.5002360              1.4396580        
      0.0567390              0.1100890              0.4846050             -0.6733890             -0.4547520        
Sc    D
      0.0231750              1.0000000        
Sc    D
      2.1282000              1.0000000        
Sc    D
      0.9691000              1.0000000        
Sc    D
      0.0094700              1.0000000        
Sc    F
      2.7590000              1.0000000        
Sc    F
      1.0490000              1.0000000        
Sc    F
      0.3989000              1.0000000        
Sc    F
      0.1106000              1.0000000        
Sc    F
      0.0306700              1.0000000        
Sc    G
      2.4852000              1.0000000        
Sc    G
      0.9067000              1.0000000        
Sc    G
      0.2530000              1.0000000        
Sc    G
      0.0706000              1.0000000        
Sc    H
      2.0405000              1.0000000        
Sc    H
      0.4934000              1.0000000        
Sc    H
      0.1193100              1.0000000        
end
basis "Ti_aug-cc-pwCVQZ-DK" SPHERICAL
Ti    S
 9317034.0000000             0.0000480             -0.0000270              0.0000060             -0.0000010             -0.0000020             -0.0000040             -0.0000040        
 1394971.0000000             0.0001370             -0.0000780              0.0000160             -0.0000040             -0.0000070             -0.0000110             -0.0000120        
 317453.1000000              0.0003690             -0.0002090              0.0000430             -0.0000100             -0.0000190             -0.0000290             -0.0000330        
  89921.0000000              0.0009180             -0.0005220              0.0001060             -0.0000250             -0.0000470             -0.0000740             -0.0000800        
  29338.1600000              0.0022650             -0.0012900              0.0002630             -0.0000620             -0.0001140             -0.0001770             -0.0002080        
  10592.6600000              0.0056370             -0.0032220              0.0006590             -0.0001560             -0.0002980             -0.0004720             -0.0004770        
   4132.0560000              0.0142060             -0.0081580              0.0016720             -0.0003970             -0.0007100             -0.0010940             -0.0013800        
   1714.2350000              0.0351600             -0.0204590              0.0042500             -0.0010080             -0.0019660             -0.0031320             -0.0029340        
    747.9151000              0.0813360             -0.0484440              0.0102280             -0.0024260             -0.0042390             -0.0064710             -0.0088360        
    340.1991000              0.1643130             -0.1033990              0.0228630             -0.0054310             -0.0108910             -0.0175340             -0.0148350        
    160.2060000              0.2627320             -0.1841860              0.0437150             -0.0103860             -0.0173170             -0.0259950             -0.0412370        
     77.5885100              0.2747630             -0.2439660              0.0667600             -0.0159460             -0.0346520             -0.0574830             -0.0353130        
     38.0448900              0.1433810             -0.1550920              0.0466230             -0.0111360             -0.0106910             -0.0112000             -0.0745600        
     17.3536200              0.0699260              0.1879170             -0.0882470              0.0212810              0.0155810              0.0114700              0.1566220        
      8.6420620              0.1217330              0.5361260             -0.3414970              0.0868200              0.2245120              0.4086420              0.1970970        
      4.3044040              0.0854080              0.3679910             -0.3594440              0.0946190              0.0886640              0.1257640              0.7633560        
      1.9377180              0.0109570              0.0494090              0.2370220             -0.0736970              0.0159690             -0.1612930             -2.1344110        
      0.9365940             -0.0003620             -0.0038250              0.6874350             -0.2412180             -1.0519990             -2.2350150              0.4049510        
      0.4326240              0.0000950              0.0000870              0.3500250             -0.2563650              0.3677290              2.8573850              2.1153220        
      0.1073520             -0.0000310             -0.0003080              0.0179040              0.3168670              2.0024320             -0.4826880             -5.0821820        
      0.0520340              0.0000390              0.0002850             -0.0054380              0.6062010             -1.2263140             -1.8788870              6.4423500        
Ti    S
      0.0240380              1.0000000        
Ti    S
      4.0519000              1.0000000        
Ti    S
      1.0592000              1.0000000        
Ti    S
      0.0111000              1.0000000        
Ti    P
  25537.3300000              0.0000410             -0.0000140              0.0000030              0.0000040              0.0000080             -0.0000100        
   6042.2430000              0.0001750             -0.0000590              0.0000140              0.0000180              0.0000340             -0.0000450        
   1962.6530000              0.0007800             -0.0002620              0.0000630              0.0000790              0.0001610             -0.0001770        
    751.7338000              0.0030920             -0.0010410              0.0002490              0.0003140              0.0005930             -0.0008240        
    319.8833000              0.0109090             -0.0036910              0.0008880              0.0011130              0.0022830             -0.0024550        
    146.4300000              0.0332110             -0.0113840              0.0027250              0.0034320              0.0064630             -0.0090560        
     70.7486100              0.0858830             -0.0300860              0.0072650              0.0090940              0.0187630             -0.0196030        
     35.5908800              0.1795240             -0.0650050              0.0156150              0.0196660              0.0364410             -0.0531680        
     18.3689300              0.2888880             -0.1085090              0.0264500              0.0330480              0.0710110             -0.0659310        
      9.6586550              0.3276960             -0.1312330              0.0317660              0.0402020              0.0710910             -0.1487020        
      5.1367300              0.2100700             -0.0513800              0.0120800              0.0150120              0.0583500             -0.0224680        
      2.6988720              0.0549250              0.1797250             -0.0532040             -0.0640970             -0.1859340              0.1803870        
      1.3897030              0.0018240              0.3962200             -0.1129400             -0.1398750             -0.3293680              1.1704710        
      0.7031630             -0.0015830              0.3915750             -0.1429220             -0.1795270             -0.5446980             -1.0091870        
      0.3441230             -0.0010010              0.1730820             -0.0096270             -0.0499880              1.1603920             -1.2804130        
      0.1413750             -0.0000600              0.0188130              0.3540680              0.5710180              0.5310260              2.2836230        
      0.0607910             -0.0000160             -0.0002960              0.5482170              0.5224460             -0.9673130             -1.1335330        
Ti    P
      0.0258310              1.0000000        
Ti    P
      4.8241000              1.0000000        
Ti    P
      1.2211000              1.0000000        
Ti    P
      0.0109800              1.0000000        
Ti    D
    199.9720000              0.0003870             -0.0003950             -0.0006270             -0.0007040        
     59.1869000              0.0033620             -0.0034330             -0.0054590             -0.0070290        
     22.6013000              0.0161370             -0.0165460             -0.0266700             -0.0306810        
      9.5739100              0.0519050             -0.0538430             -0.0882250             -0.1179840        
      4.3177100              0.1286240             -0.1356220             -0.2246980             -0.2736880        
      2.0237300              0.2291190             -0.2281990             -0.3285440             -0.3822080        
      0.9471690              0.3019170             -0.2563190             -0.1158350              0.5416700        
      0.4338770              0.3096490             -0.0539210              0.6164880              0.7650710        
      0.1921260              0.2346190              0.3874070              0.4178460             -1.2834360        
      0.0814040              0.1048760              0.4995520             -0.6084680              0.2757400        
Ti    D
      0.0322330              1.0000000        
Ti    D
      2.7829000              1.0000000        
Ti    D
      1.3657000              1.0000000        
Ti    D
      0.0127600              1.0000000        
Ti    F
      3.7192000              1.0000000        
Ti    F
      1.4838000              1.0000000        
Ti    F
      0.5920000              1.0000000        
Ti    F
      0.1796000              1.0000000        
Ti    F
      0.0544900              1.0000000        
Ti    G
      3.2099000              1.0000000        
Ti    G
      1.2652000              1.0000000        
Ti    G
      0.3947000              1.0000000        
Ti    G
      0.1231300              1.0000000        
Ti    H
      2.7676000              1.0000000        
Ti    H
      0.8524000              1.0000000        
Ti    H
      0.2625300              1.0000000        
end
basis "V_aug-cc-pwCVQZ-DK" SPHERICAL
V    S
 10251780.0000000            0.0000510             -0.0000280              0.0000060             -0.0000010             -0.0000030             -0.0000040             -0.0000050        
 1534920.0000000             0.0001450             -0.0000800              0.0000170             -0.0000040             -0.0000080             -0.0000120             -0.0000140        
 349300.9000000              0.0003880             -0.0002150              0.0000450             -0.0000110             -0.0000200             -0.0000320             -0.0000370        
  98942.0500000              0.0009590             -0.0005330              0.0001130             -0.0000260             -0.0000510             -0.0000810             -0.0000890        
  32281.3600000              0.0023460             -0.0013050              0.0002760             -0.0000640             -0.0001220             -0.0001910             -0.0002320        
  11655.2700000              0.0057780             -0.0032250              0.0006850             -0.0001590             -0.0003180             -0.0005020             -0.0005200        
   4546.5480000              0.0144180             -0.0080890              0.0017220             -0.0004010             -0.0007480             -0.0011630             -0.0015180        
   1886.1850000              0.0354410             -0.0201520              0.0043460             -0.0010120             -0.0020610             -0.0032710             -0.0031210        
    822.9417000              0.0817150             -0.0475820              0.0104260             -0.0024260             -0.0044150             -0.0068350             -0.0096880        
    374.3439000              0.1649650             -0.1015860              0.0232820             -0.0054310             -0.0113810             -0.0181850             -0.0155290        
    176.3069000              0.2641750             -0.1814790              0.0445480             -0.0103840             -0.0180080             -0.0276530             -0.0457170        
     85.4066100              0.2776330             -0.2418400              0.0681470             -0.0159960             -0.0363880             -0.0593360             -0.0354600        
     41.9043500              0.1460600             -0.1546910              0.0477830             -0.0111760             -0.0109160             -0.0139910             -0.0871400        
     19.1552500              0.0683250              0.1906220             -0.0909640              0.0214850              0.0158660              0.0177810              0.1876050        
      9.5716170              0.1153650              0.5397270             -0.3509110              0.0878790              0.2385610              0.4239440              0.2022650        
      4.7800860              0.0802700              0.3667050             -0.3582080              0.0922920              0.0861270              0.1443250              0.8408220        
      2.1618600              0.0102060              0.0489360              0.2523820             -0.0762840              0.0045110             -0.2717610             -2.5807070        
      1.0427110             -0.0003070             -0.0037570              0.6881350             -0.2409190             -1.0936470             -2.1448410              1.1903460        
      0.4802820              0.0000610             -0.0000410              0.3404340             -0.2425420              0.4530570              2.9061280              1.4732050        
      0.1176380             -0.0000200             -0.0002620              0.0167320              0.3201900              1.9309090             -0.7881850             -4.5441610        
      0.0561740              0.0000370              0.0002880             -0.0049670              0.5991660             -1.2327630             -1.4659060              5.9967610        
V    S
      0.0256610              1.0000000        
V    S
      4.4632000              1.0000000        
V    S
      1.3107000              1.0000000        
V    S
      0.0117200              1.0000000        
V    P
  28563.3200000              0.0000430             -0.0000150              0.0000040              0.0000040              0.0000090             -0.0000110        
   6757.1910000              0.0001780             -0.0000610              0.0000150              0.0000180              0.0000360             -0.0000500        
   2194.6520000              0.0007810             -0.0002670              0.0000650              0.0000810              0.0001680             -0.0001900        
    840.5257000              0.0030620             -0.0010490              0.0002520              0.0003180              0.0006150             -0.0008750        
    357.6666000              0.0107680             -0.0037070              0.0008980              0.0011240              0.0023560             -0.0026070        
    163.7534000              0.0327920             -0.0114380              0.0027560              0.0034680              0.0066770             -0.0096130        
     79.1446600              0.0850360             -0.0303200              0.0073760              0.0092140              0.0194410             -0.0209460        
     39.8385800              0.1785820             -0.0658710              0.0159330              0.0200460              0.0380200             -0.0570950        
     20.5853600              0.2887830             -0.1106360              0.0271950              0.0338840              0.0743940             -0.0712500        
     10.8430700              0.3282520             -0.1337960              0.0325940              0.0412880              0.0746660             -0.1585200        
      5.7779690              0.2104570             -0.0504700              0.0118210              0.0147000              0.0596980             -0.0187930        
      3.0431700              0.0551900              0.1841380             -0.0558370             -0.0662180             -0.2028460              0.2409470        
      1.5702390              0.0018830              0.3986760             -0.1156350             -0.1436870             -0.3467910              1.1423850        
      0.7949750             -0.0016270              0.3877830             -0.1386370             -0.1780180             -0.4971730             -1.1366200        
      0.3889800             -0.0010070              0.1710070              0.0022130             -0.0335830              1.1593020             -1.0774880        
      0.1573350             -0.0000620              0.0185650              0.3520420              0.5764400              0.4791120              2.1602070        
      0.0665830             -0.0000130             -0.0005590              0.5411560              0.5110710             -0.9455920             -1.1313370        
V    P
      0.0278440              1.0000000        
V    P
      5.6501000              1.0000000        
V    P
      1.4350000              1.0000000        
V    P
      0.0117200              1.0000000        
V    D
    244.3470000              0.0003510             -0.0003720             -0.0005750             -0.0007310        
     72.2926000              0.0030850             -0.0032770             -0.0050770             -0.0070950        
     27.6493000              0.0152580             -0.0162790             -0.0255170             -0.0331860        
     11.7778000              0.0502450             -0.0543160             -0.0868340             -0.1269420        
      5.3373100              0.1265230             -0.1399110             -0.2285650             -0.3250860        
      2.5176000              0.2292800             -0.2390000             -0.3376560             -0.3625000        
      1.1888100              0.3034060             -0.2538070             -0.0917660              0.6689130        
      0.5499670              0.3088670             -0.0303220              0.6199220              0.6037430        
      0.2457380              0.2310890              0.3839470              0.3937470             -1.2164810        
      0.1045040              0.1037090              0.4879820             -0.6029800              0.2817010        
V    D
      0.0411450              1.0000000        
V    D
      3.4437000              1.0000000        
V    D
      1.7638000              1.0000000        
V    D
      0.0162000              1.0000000        
V    F
      4.6999000              1.0000000        
V    F
      1.9221000              1.0000000        
V    F
      0.7861000              1.0000000        
V    F
      0.2516000              1.0000000        
V    F
      0.0805300              1.0000000        
V    G
      3.9718000              1.0000000        
V    G
      1.6355000              1.0000000        
V    G
      0.5564000              1.0000000        
V    G
      0.1892900              1.0000000        
V    H
      3.6433000              1.0000000        
V    H
      1.2875000              1.0000000        
V    H
      0.4549900              1.0000000        
end
basis "Cr_aug-cc-pwCVQZ-DK" SPHERICAL
Cr    S
 11016640.0000000            0.0000540             -0.0000300              0.0000060             -0.0000010             -0.0000030             -0.0000050             -0.0000050        
 1649423.0000000             0.0001540             -0.0000860              0.0000180             -0.0000040             -0.0000080             -0.0000130             -0.0000150        
 375358.9000000              0.0004120             -0.0002280              0.0000490             -0.0000110             -0.0000220             -0.0000350             -0.0000420        
 106323.6000000              0.0010120             -0.0005620              0.0001210             -0.0000280             -0.0000550             -0.0000870             -0.0000990        
  34689.7600000              0.0024600             -0.0013670              0.0002940             -0.0000670             -0.0001310             -0.0002080             -0.0002590        
  12524.8300000              0.0060080             -0.0033520              0.0007250             -0.0001660             -0.0003380             -0.0005320             -0.0005660        
   4885.7520000              0.0148700             -0.0083390              0.0018090             -0.0004120             -0.0007860             -0.0012540             -0.0016830        
   2026.9180000              0.0363090             -0.0206480              0.0045400             -0.0010390             -0.0021660             -0.0033990             -0.0033080        
    884.3645000              0.0833080             -0.0485430              0.0108370             -0.0024630             -0.0045870             -0.0073610             -0.0107390        
    402.3170000              0.1673620             -0.1032880              0.0241590             -0.0055480             -0.0119040             -0.0186100             -0.0160340        
    189.5271000              0.2661030             -0.1836520              0.0459620             -0.0104380             -0.0184920             -0.0301280             -0.0511580        
     91.8609500              0.2761380             -0.2426780              0.0698970             -0.0162390             -0.0378720             -0.0587280             -0.0331430        
     45.1247600              0.1429680             -0.1497000              0.0466910             -0.0103850             -0.0093630             -0.0190270             -0.1014980        
     20.6251200              0.0695690              0.2061910             -0.0999290              0.0224250              0.0177020              0.0388480              0.2332710        
     10.3197300              0.1153580              0.5462950             -0.3685700              0.0924750              0.2547990              0.4187920              0.2014630        
      5.1577230              0.0760500              0.3519330             -0.3424530              0.0833650              0.0707240              0.1853590              0.8803140        
      2.3126280              0.0089700              0.0434510              0.2985130             -0.0821470             -0.0257070             -0.5215690             -3.1030870        
      1.1030790             -0.0002630             -0.0034870              0.6976530             -0.2590250             -1.1363580             -1.8075870              2.3290390        
      0.4980420              0.0000710              0.0000520              0.2956920             -0.2041760              0.6281400              2.8725050              0.4451650        
      0.1182470             -0.0000110             -0.0001960              0.0095900              0.3777770              1.8833370             -1.3448820             -3.8882070        
      0.0573560              0.0000400              0.0002860             -0.0010750              0.5588970             -1.3929490             -0.7200920              5.5615460        
Cr    S
      0.0257600              1.0000000        
Cr    S
      4.7991000              1.0000000        
Cr    S
      1.4287000              1.0000000        
Cr    S
      0.0115700              1.0000000        
Cr    P
  31539.8900000              0.0000460             -0.0000160              0.0000040              0.0000050              0.0000100             -0.0000130        
   7460.2340000              0.0001840             -0.0000640              0.0000150              0.0000190              0.0000390             -0.0000540        
   2422.6220000              0.0007930             -0.0002750              0.0000650              0.0000830              0.0001790             -0.0002070        
    927.7547000              0.0030740             -0.0010700              0.0002520              0.0003250              0.0006500             -0.0009320        
    394.8041000              0.0107650             -0.0037650              0.0008930              0.0011440              0.0024720             -0.0027990        
    180.8027000              0.0327480             -0.0116070              0.0027370              0.0035350              0.0070230             -0.0101970        
     87.4239300              0.0849950             -0.0308030              0.0073310              0.0093750              0.0204050             -0.0225810        
     44.0342700              0.1788510             -0.0671020              0.0158860              0.0205310              0.0402100             -0.0608530        
     22.7770400              0.2896740             -0.1130240              0.0271800              0.0346480              0.0784580             -0.0779640        
     12.0154700              0.3283500             -0.1359580              0.0324270              0.0423890              0.0794720             -0.1676820        
      6.4117510              0.2090050             -0.0478150              0.0108710              0.0133730              0.0588510             -0.0107790        
      3.3811360              0.0543940              0.1907310             -0.0565060             -0.0684010             -0.2240270              0.3109570        
      1.7470540              0.0020050              0.4011900             -0.1144660             -0.1487620             -0.3702630              1.0976240        
      0.8850040             -0.0014380              0.3827710             -0.1329640             -0.1732490             -0.4376700             -1.2795560        
      0.4330280             -0.0009110              0.1674310              0.0047140             -0.0207630              1.1645370             -0.8569200        
      0.1739620             -0.0000520              0.0180400              0.3440550              0.5782720              0.4154860              2.0411650        
      0.0728230             -0.0000120             -0.0006540              0.5412790              0.5031920             -0.9143280             -1.1202710        
Cr    P
      0.0299520              1.0000000        
Cr    P
      6.4552000              1.0000000        
Cr    P
      1.6531000              1.0000000        
Cr    P
      0.0123200              1.0000000        
Cr    D
    281.3120000              0.0003470             -0.0003940             -0.0005630              0.0007970        
     83.1885000              0.0030700             -0.0034940             -0.0050080              0.0076390        
     31.8396000              0.0153950             -0.0175900             -0.0254920              0.0369700        
     13.6026000              0.0513190             -0.0596210             -0.0881820              0.1424390        
      6.1829800              0.1296680             -0.1545140             -0.2353990              0.3758710        
      2.9227000              0.2347810             -0.2603230             -0.3396410              0.3231850        
      1.3821600              0.3080430             -0.2500610             -0.0376150             -0.8334330        
      0.6394600              0.3080560              0.0227810              0.6602460             -0.3730540        
      0.2848980              0.2239250              0.4192340              0.2965440              1.2135530        
      0.1200450              0.0946790              0.4520610             -0.6557610             -0.4829450        
Cr    D
      0.0462290              1.0000000        
Cr    D
      4.0848000              1.0000000        
Cr    D
      2.1405000              1.0000000        
Cr    D
      0.0178000              1.0000000        
Cr    F
      5.6633000              1.0000000        
Cr    F
      2.3365000              1.0000000        
Cr    F
      0.9639000              1.0000000        
Cr    F
      0.3142000              1.0000000        
Cr    F
      0.1024200              1.0000000        
Cr    G
      4.6690000              1.0000000        
Cr    G
      1.9538000              1.0000000        
Cr    G
      0.6848000              1.0000000        
Cr    G
      0.2400200              1.0000000        
Cr    H
      4.4133000              1.0000000        
Cr    H
      1.6472000              1.0000000        
Cr    H
      0.6147900              1.0000000        
end
basis "Mn_aug-cc-pwCVQZ-DK" SPHERICAL
Mn    S
 12210500.0000000            0.0000580             -0.0000280              0.0000070             -0.0000020             -0.0000030             -0.0000050             -0.0000060        
 1828157.0000000             0.0001650             -0.0000790              0.0000190             -0.0000040             -0.0000090             -0.0000140             -0.0000160        
 416030.3000000              0.0004380             -0.0002090              0.0000510             -0.0000110             -0.0000230             -0.0000370             -0.0000440        
 117843.6000000              0.0010700             -0.0005120              0.0001250             -0.0000280             -0.0000570             -0.0000910             -0.0001040        
  38448.1400000              0.0025760             -0.0012360              0.0003020             -0.0000670             -0.0001340             -0.0002130             -0.0002660        
  13881.7100000              0.0062270             -0.0030000              0.0007350             -0.0001640             -0.0003410             -0.0005440             -0.0005870        
   5415.0020000              0.0152550             -0.0073920              0.0018160             -0.0004050             -0.0007900             -0.0012540             -0.0016770        
   2246.4600000              0.0369930             -0.0181990              0.0045200             -0.0010090             -0.0021450             -0.0034240             -0.0034070        
    980.1463000              0.0847020             -0.0427750              0.0107630             -0.0023990             -0.0045600             -0.0072400             -0.0105060        
    445.8952000              0.1707500             -0.0916740              0.0239650             -0.0053570             -0.0117340             -0.0187740             -0.0167510        
    210.0558000              0.2743970             -0.1657000              0.0458380             -0.0102290             -0.0185180             -0.0294560             -0.0495550        
    101.8046000              0.2920430             -0.2259060              0.0701710             -0.0157930             -0.0375870             -0.0606780             -0.0381420        
     50.0112600              0.1562220             -0.1460020              0.0489920             -0.0109470             -0.0109190             -0.0172460             -0.0951520        
     22.9393900              0.0570620              0.2013410             -0.0969430              0.0218960              0.0172930              0.0278370              0.2112910        
     11.5226400              0.0808350              0.5511090             -0.3667830              0.0881540              0.2491810              0.4339450              0.2315620        
      5.7763380              0.0554240              0.3649400             -0.3506890              0.0858360              0.0803670              0.1645920              0.8752810        
      2.6259590              0.0066290              0.0468620              0.2826890             -0.0805790             -0.0187700             -0.4097160             -2.9729550        
      1.2603220             -0.0002790             -0.0049100              0.6877440             -0.2334220             -1.0968980             -1.9645600              1.9405330        
      0.5771300             -0.0000720             -0.0008110              0.3208270             -0.2180350              0.5280050              2.8395490              0.8065440        
      0.1365820             -0.0000030             -0.0002310              0.0142970              0.3213000              1.8057720             -0.9662380             -3.8652740        
      0.0635350              0.0000180              0.0002610             -0.0039610              0.5871860             -1.1683710             -1.1393420              5.3654950        
Mn    S
      0.0285210              1.0000000        
Mn    S
      5.3389000              1.0000000        
Mn    S
      1.6013000              1.0000000        
Mn    S
      0.0128000              1.0000000        
Mn    P
  35005.1200000              0.0000480             -0.0000170             -0.0000040              0.0000050              0.0000110             -0.0000150        
   8279.4620000              0.0001870             -0.0000650             -0.0000150              0.0000200              0.0000420             -0.0000600        
   2688.4650000              0.0007950             -0.0002760             -0.0000640              0.0000870              0.0001890             -0.0002330        
   1029.4900000              0.0030450             -0.0010630             -0.0002440              0.0003310              0.0006700             -0.0009920        
    438.0708000              0.0106220             -0.0037280             -0.0008620              0.0011680              0.0025720             -0.0031070        
    200.6153000              0.0323120             -0.0114960             -0.0026400              0.0035830              0.0072120             -0.0108160        
     97.0076900              0.0841060             -0.0306030             -0.0071040              0.0096140              0.0213320             -0.0253500        
     48.8705200              0.1778670             -0.0670670             -0.0154490              0.0209630              0.0415820             -0.0647510        
     25.2928100              0.2896740             -0.1137030             -0.0266700              0.0360950              0.0832960             -0.0906570        
     13.3538200              0.3295160             -0.1370730             -0.0317120              0.0432600              0.0812140             -0.1700890        
      7.1317860              0.2101060             -0.0467790             -0.0106380              0.0145930              0.0663900             -0.0386240        
      3.7643650              0.0543090              0.1938100              0.0556750             -0.0739170             -0.2544520              0.4446210        
      1.9462650              0.0009210              0.4032800              0.1103720             -0.1508130             -0.3788380              1.0592000        
      0.9854550             -0.0025450              0.3802000              0.1279880             -0.1784340             -0.3911210             -1.5463780        
      0.4818650             -0.0013860              0.1659910             -0.0059250              0.0078630              1.1724280             -0.4568530        
      0.18822219            -0.0001010              0.0176060             -0.3403060              0.5895700              0.3433290              1.7988000        
      0.07753957            -0.0000060             -0.0009790             -0.5399780              0.4812390             -0.8913400             -1.0962300        
Mn    P
      0.03154945             1.0000000        
Mn    P
      7.3423000              1.0000000        
Mn    P
      1.9340000              1.0000000        
Mn    P
      0.0128400              1.0000000        
Mn    D
    313.1090000              0.0003590             -0.0003660             -0.0005780             -0.0007350        
     92.5276000              0.0031830             -0.0032550             -0.0051700             -0.0066420        
     35.4191000              0.0160470             -0.0164410             -0.0263440             -0.0338840        
     15.1577000              0.0537480             -0.0558650             -0.0919750             -0.1226080        
      6.9096400              0.1349810             -0.1438070             -0.2428130             -0.3500800        
      3.2725600              0.2407980             -0.2453650             -0.3418720             -0.3191570        
      1.5493600              0.3099540             -0.2370140             -0.0269540              0.7228530        
      0.7170940              0.3033480              0.0168210              0.6038520              0.4559420        
      0.3193100              0.2162990              0.3826800              0.3360190             -1.0589930        
      0.1341570              0.0917180              0.4703680             -0.5511860              0.1545530        
Mn    D
      0.0514000              1.0000000        
Mn    D
      4.6851000              1.0000000        
Mn    D
      2.4217000              1.0000000        
Mn    D
      0.0196900              1.0000000        
Mn    F
      6.6540000              1.0000000        
Mn    F
      2.7676000              1.0000000        
Mn    F
      1.1511000              1.0000000        
Mn    F
      0.3812000              1.0000000        
Mn    F
      0.1262400              1.0000000        
Mn    G
      5.4683000              1.0000000        
Mn    G
      2.3327000              1.0000000        
Mn    G
      0.8520000              1.0000000        
Mn    G
      0.3111900              1.0000000        
Mn    H
      5.1185000              1.0000000        
Mn    H
      1.9660000              1.0000000        
Mn    H
      0.7551300              1.0000000        
end
basis "Fe_aug-cc-pwCVQZ-DK" SPHERICAL
Fe    S
      0.1327714E+08          0.0000600             -0.0000310              0.0000070             -0.0000020             -0.0000030             -0.0000050             -0.0000060        
 1987888.0000000             0.0001700             -0.0000880              0.0000210             -0.0000040             -0.0000090             -0.0000150             -0.0000170        
 452387.1000000              0.0004500             -0.0002320              0.0000540             -0.0000120             -0.0000240             -0.0000390             -0.0000450        
 128143.7000000              0.0010930             -0.0005650              0.0001320             -0.0000290             -0.0000590             -0.0000960             -0.0001070        
  41809.1700000              0.0026130             -0.0013530              0.0003160             -0.0000690             -0.0001370             -0.0002240             -0.0002720        
  15095.3300000              0.0062600             -0.0032560              0.0007640             -0.0001670             -0.0003440             -0.0005620             -0.0005940        
   5888.4380000              0.0151950             -0.0079480              0.0018690             -0.0004080             -0.0007940             -0.0013010             -0.0016900        
   2442.8760000              0.0365770             -0.0194130              0.0046210             -0.0010090             -0.0021300             -0.0034750             -0.0033830        
   1065.8570000              0.0833750             -0.0453820              0.0109610             -0.0023900             -0.0045440             -0.0074620             -0.0105020        
    484.9096000              0.1676340             -0.0967990              0.0243640             -0.0053290             -0.0115700             -0.0188700             -0.0164400        
    228.4585000              0.2688600             -0.1739720              0.0465960             -0.0101780             -0.0184810             -0.0305680             -0.0496220        
    110.7453000              0.2852350             -0.2350940              0.0713740             -0.0157200             -0.0369330             -0.0602890             -0.0365410        
     54.4311600              0.1525320             -0.1511880              0.0498900             -0.0109200             -0.0115290             -0.0205920             -0.0969090        
     25.0109600              0.0633810              0.2012780             -0.0995880              0.0220630              0.0192290              0.0357860              0.2140750        
     12.5926200              0.0967240              0.5494000             -0.3739230              0.0880750              0.2443040              0.4216870              0.2010450        
      6.3232020              0.0654700              0.3609330             -0.3489040              0.0836500              0.0827020              0.2092330              0.9699410        
      2.8833840              0.0079630              0.0465600              0.2920800             -0.0817500             -0.0399450             -0.4975030             -3.1426280        
      1.3828680             -0.0002530             -0.0040160              0.6871120             -0.2293920             -1.0397040             -1.8683190              2.1267050        
      0.6322010             -0.0000320             -0.0004730              0.3152790             -0.2098240              0.4953030              2.7545840              0.6989570        
      0.1492380             -0.0000070             -0.0002090              0.0138550              0.3095030              1.6957440             -0.8331090             -3.7298890        
      0.0684940              0.0000190              0.0002150             -0.0034390              0.5849850             -0.9636980             -1.2311520              5.1457330        
Fe    S
      0.0303810              1.0000000        
Fe    S
      5.7900000              1.0000000        
Fe    S
      1.7335000              1.0000000        
Fe    S
      0.0134800              1.0000000        
Fe    P
  38282.0500000              0.0000510             -0.0000180              0.0000040              0.0000060              0.0000130             -0.0000160        
   9061.5560000              0.0001930             -0.0000680              0.0000150              0.0000230              0.0000460             -0.0000650        
   2944.4500000              0.0008070             -0.0002850              0.0000620              0.0000960              0.0002060             -0.0002560        
   1128.1580000              0.0030540             -0.0010820              0.0002350              0.0003580              0.0007160             -0.0010400        
    480.3380000              0.0105910             -0.0037730              0.0008270              0.0012700              0.0027590             -0.0033700        
    220.1368000              0.0321420             -0.0116110              0.0025220              0.0038420              0.0076430             -0.0112410        
    106.5482000              0.0836490             -0.0309030              0.0067960              0.0104410              0.0228730             -0.0275820        
     53.7426200              0.1771500             -0.0678610              0.0147820              0.0224790              0.0440810             -0.0670210        
     27.8631800              0.2890860             -0.1153490              0.0256530              0.0395990              0.0899840             -0.1006940        
     14.7438200              0.3291570             -0.1389140              0.0303130              0.0459830              0.0853400             -0.1703110        
      7.8933510              0.2104230             -0.0466250              0.0102010              0.0175790              0.0772780             -0.0783230        
      4.1794970              0.0551740              0.1946700             -0.0531930             -0.0850280             -0.2972450              0.6077450        
      2.1656690              0.0015110              0.4040100             -0.1036780             -0.1609090             -0.4067180              0.9645760        
      1.0972400             -0.0021830              0.3786780             -0.1209980             -0.1945280             -0.3121550             -1.7927730        
      0.5360850             -0.0012180              0.1665960              0.0031080              0.0582050              1.2052550             -0.0262890        
      0.2024530             -0.0000850              0.0175340              0.3283150              0.6259810              0.1894990              1.5460990        
      0.0816950             -0.0000020             -0.0013550              0.5422430              0.4271460             -0.8424540             -1.0949690        
Fe    P
      0.0326140              1.0000000        
Fe    P
      8.3687000              1.0000000        
Fe    P
      2.2601000              1.0000000        
Fe    P
      0.0130200              1.0000000        
Fe    D
    350.9950000              0.0003590             -0.0003950             -0.0005700             -0.0008190        
    103.6670000              0.0031850             -0.0035300             -0.0051170             -0.0070130        
     39.7043000              0.0161760             -0.0179410             -0.0262340             -0.0378470        
     17.0310000              0.0545530             -0.0614610             -0.0920690             -0.1314140        
      7.7890200              0.1367300             -0.1583160             -0.2464400             -0.4094000        
      3.6995500              0.2420240             -0.2693400             -0.3502150             -0.2893670        
      1.7553200              0.3084870             -0.2412260              0.0307360              0.9175770        
      0.8128450              0.3004030              0.0585700              0.6477360              0.2020840        
      0.3614410              0.2164630              0.4116150              0.2400240             -1.0761670        
      0.1513460              0.0943300              0.4361600             -0.6048030              0.4017690        
Fe    D
      0.0575130              1.0000000        
Fe    D
      5.4967000              1.0000000        
Fe    D
      2.8925000              1.0000000        
Fe    D
      0.0218600              1.0000000        
Fe    F
      7.7828000              1.0000000        
Fe    F
      3.2584000              1.0000000        
Fe    F
      1.3641000              1.0000000        
Fe    F
      0.4564000              1.0000000        
Fe    F
      0.1527000              1.0000000        
Fe    G
      6.3816000              1.0000000        
Fe    G
      2.7717000              1.0000000        
Fe    G
      1.0505000              1.0000000        
Fe    G
      0.3981500              1.0000000        
Fe    H
      5.8964000              1.0000000        
Fe    H
      2.3448000              1.0000000        
Fe    H
      0.9324500              1.0000000        
end
basis "Co_aug-cc-pwCVQZ-DK" SPHERICAL
Co    S
      0.1437022E+08          0.0000630             -0.0000330              0.0000080             -0.0000020             -0.0000030             -0.0000060             -0.0000060        
 2151540.0000000             0.0001780             -0.0000940              0.0000220             -0.0000050             -0.0000090             -0.0000160             -0.0000180        
 489625.7000000              0.0004680             -0.0002460              0.0000570             -0.0000120             -0.0000240             -0.0000420             -0.0000470        
 138690.3000000              0.0011300             -0.0005960              0.0001390             -0.0000300             -0.0000590             -0.0001020             -0.0001110        
  45249.8900000              0.0026830             -0.0014180              0.0003300             -0.0000700             -0.0001380             -0.0002390             -0.0002800        
  16337.6200000              0.0063740             -0.0033820              0.0007910             -0.0001690             -0.0003430             -0.0005910             -0.0006050        
   6373.0730000              0.0153380             -0.0081850              0.0019200             -0.0004100             -0.0007880             -0.0013670             -0.0017140        
   2643.9580000              0.0366560             -0.0198490              0.0047140             -0.0010070             -0.0020850             -0.0035830             -0.0033760        
   1153.6140000              0.0831830             -0.0461910              0.0111330             -0.0023760             -0.0044670             -0.0077820             -0.0105710        
    524.8606000              0.1668550             -0.0982720              0.0246990             -0.0052860             -0.0112370             -0.0192710             -0.0161940        
    247.3069000              0.2672920             -0.1763040              0.0472060             -0.0100900             -0.0181850             -0.0320140             -0.0500370        
    119.9063000              0.2833740             -0.2377920              0.0722950             -0.0155790             -0.0356690             -0.0609120             -0.0349470        
     58.9642900              0.1517480             -0.1523860              0.0503830             -0.0107950             -0.0119320             -0.0236150             -0.0993410        
     27.1361600              0.0652490              0.2036220             -0.1023930              0.0222270              0.0212370              0.0437420              0.2194560        
     13.6891200              0.1004050              0.5501680             -0.3802180              0.0876570              0.2348300              0.4195750              0.1784260        
      6.8827710              0.0672310              0.3578070             -0.3454400              0.0809210              0.0848480              0.2454930              1.0401950        
      3.1446470              0.0081260              0.0457660              0.3024920             -0.0827610             -0.0615640             -0.5913480             -3.3014820        
      1.5062660             -0.0002610             -0.0038900              0.6860590             -0.2246610             -0.9633490             -1.7723080              2.3454950        
      0.6872680             -0.0000390             -0.0004840              0.3089540             -0.2015800              0.4435460              2.6790200              0.5436570        
      0.1609720             -0.0000080             -0.0002010              0.0132060              0.3017660              1.5994950             -0.7274990             -3.5761260        
      0.0730170              0.0000140              0.0001790             -0.0031170              0.5810930             -0.7695260             -1.2747080              4.9421090        
Co    S
      0.0320710              1.0000000        
Co    S
      6.2451000              1.0000000        
Co    S
      1.7752000              1.0000000        
Co    S
      0.0140900              1.0000000        
Co    P
  41961.4000000              0.0000530             -0.0000190              0.0000040              0.0000070              0.0000140              0.0000180        
   9928.3060000              0.0001980             -0.0000710              0.0000160              0.0000250              0.0000490              0.0000680        
   3224.9710000              0.0008160             -0.0002910              0.0000640              0.0001030              0.0002170              0.0002720        
   1235.2930000              0.0030540             -0.0010940              0.0002400              0.0003800              0.0007530              0.0010650        
    525.8469000              0.0105440             -0.0037960              0.0008410              0.0013410              0.0028520              0.0035430        
    240.9762000              0.0319630             -0.0116670              0.0025640              0.0040530              0.0080000              0.0114310        
    116.6418000              0.0832750             -0.0310950              0.0069140              0.0110330              0.0236410              0.0291160        
     58.8483400              0.1768010             -0.0684730              0.0150970              0.0238220              0.0464590              0.0681050        
     30.5291000              0.2892520             -0.1168130              0.0262560              0.0421320              0.0930840              0.1082440        
     16.1694300              0.3294090             -0.1403400              0.0310480              0.0489260              0.0921130              0.1709700        
      8.6642360              0.2103030             -0.0455310              0.0100640              0.0182370              0.0774220              0.1038320        
      4.5919430              0.0551480              0.1979890             -0.0546020             -0.0927790             -0.3214270             -0.7477390        
      2.3810480              0.0015780              0.4052460             -0.1063460             -0.1742910             -0.4386490             -0.8092780        
      1.2062460             -0.0021450              0.3766180             -0.1210550             -0.1949580             -0.2191060              1.8373640        
      0.5888220             -0.0011880              0.1642500              0.0063130              0.0866440              1.1794450             -0.1406610        
      0.2248930             -0.0000800              0.0173260              0.3283220              0.6196070              0.1324390             -1.4398920        
      0.0904480             -0.0000030             -0.0011590              0.5404380              0.4155170             -0.8109210              1.0498300        
Co    P
      0.0358200              1.0000000        
Co    P
      9.4150000              1.0000000        
Co    P
      2.5758000              1.0000000        
Co    P
      0.0141900              1.0000000        
Co    D
    371.5660000              0.0003980             -0.0004600             -0.0006110             -0.0009190        
    110.1150000              0.0034810             -0.0040610             -0.0054160             -0.0075970        
     42.4255000              0.0173620             -0.0202580             -0.0272350             -0.0410110        
     18.3369000              0.0576820             -0.0685820             -0.0942080             -0.1379990        
      8.4573000              0.1418110             -0.1734630             -0.2495960             -0.4392740        
      4.0417900              0.2456560             -0.2858720             -0.3440740             -0.2345360        
      1.9260300              0.3075020             -0.2288420              0.0830320              0.9736790        
      0.8942810              0.2955950              0.1000240              0.6510980              0.0750400        
      0.3979880              0.2121670              0.4213280              0.1778030             -1.0306680        
      0.1665000              0.0928960              0.4054680             -0.6155820              0.4434900        
Co    D
      0.0630250              1.0000000        
Co    D
      6.2748000              1.0000000        
Co    D
      3.3097000              1.0000000        
Co    D
      0.0238600              1.0000000        
Co    F
      8.9724000              1.0000000        
Co    F
      3.7773000              1.0000000        
Co    F
      1.5902000              1.0000000        
Co    F
      0.5363000              1.0000000        
Co    F
      0.1808700              1.0000000        
Co    G
      7.3377000              1.0000000        
Co    G
      3.2254000              1.0000000        
Co    G
      1.2510000              1.0000000        
Co    G
      0.4852100              1.0000000        
Co    H
      6.7172000              1.0000000        
Co    H
      2.7485000              1.0000000        
Co    H
      1.1246100              1.0000000        
end
basis "Ni_aug-cc-pwCVQZ-DK" SPHERICAL
Ni    S
 15503020.0000000            0.0000680             -0.0000310              0.0000080             -0.0000020             -0.0000040             -0.0000060             -0.0000070        
 2321071.0000000             0.0001920             -0.0000870              0.0000230             -0.0000050             -0.0000100             -0.0000170             -0.0000190        
 528180.2000000              0.0005030             -0.0002280              0.0000600             -0.0000130             -0.0000260             -0.0000450             -0.0000500        
 149604.0000000              0.0012080             -0.0005490              0.0001450             -0.0000310             -0.0000630             -0.0001080             -0.0001170        
  48809.0700000              0.0028490             -0.0012970              0.0003430             -0.0000730             -0.0001460             -0.0002530             -0.0002940        
  17622.3900000              0.0067150             -0.0030720              0.0008140             -0.0001730             -0.0003590             -0.0006140             -0.0006290        
   6874.2010000              0.0160260             -0.0073790              0.0019600             -0.0004150             -0.0008240             -0.0014330             -0.0017690        
   2851.8570000              0.0380450             -0.0178050              0.0047790             -0.0010130             -0.0021470             -0.0036470             -0.0034530        
   1244.3340000              0.0860160             -0.0413840              0.0112410             -0.0023810             -0.0046300             -0.0081260             -0.0108110        
    566.1547000              0.1724730             -0.0884770              0.0248800             -0.0052860             -0.0114660             -0.0193360             -0.0163970        
    266.7873000              0.2771470             -0.1605330              0.0475220             -0.0100820             -0.0188850             -0.0337780             -0.0511320        
    129.3752000              0.2968780             -0.2211450              0.0727080             -0.0155550             -0.0360910             -0.0597330             -0.0347730        
     63.6516100              0.1607220             -0.1429300              0.0504870             -0.0107280             -0.0131930             -0.0291950             -0.1020090        
     29.3330200              0.0532090              0.2105090             -0.1049100              0.0225870              0.0249350              0.0576720              0.2248130        
     14.8221200              0.0670780              0.5571780             -0.3841580              0.0878230              0.2351510              0.3962980              0.1666290        
      7.4605130              0.0451040              0.3587470             -0.3405100              0.0787500              0.0995590              0.3262820              1.1504080        
      3.4135760              0.0051630              0.0448050              0.3128690             -0.0841310             -0.0991250             -0.7659990             -3.6677600        
      1.6328840             -0.0001680             -0.0047710              0.6787890             -0.2212350             -0.9520230             -1.5951110              2.9089060        
      0.7435790             -0.0000810             -0.0009710              0.3074190             -0.1943700              0.4790000              2.6051560              0.1233070        
      0.1725920              0.0000000             -0.0002250              0.0146650              0.2958150              1.4997280             -0.7647690             -3.2568870        
      0.0774200              0.0000000              0.0001450             -0.0039540              0.5768850             -0.6533590             -1.1749130              4.6303440        
Ni    S
      0.0337010              1.0000000        
Ni    S
      6.7511000              1.0000000        
Ni    S
      1.8578000              1.0000000        
Ni    S
      0.0146700              1.0000000        
Ni    P
  45066.6200000              0.0000570             -0.0000200              0.0000040              0.0000090              0.0000150              0.0000210        
  10662.6400000              0.0002080             -0.0000740              0.0000150              0.0000310              0.0000540              0.0000770        
   3463.4310000              0.0008460             -0.0003020              0.0000620              0.0001290              0.0002330              0.0003040        
   1326.6240000              0.0031340             -0.0011260              0.0002270              0.0004670              0.0008060              0.0011710        
    564.7414000              0.0107650             -0.0038860              0.0007940              0.0016690              0.0030230              0.0039020        
    258.8288000              0.0325410             -0.0119180              0.0024100              0.0049420              0.0085050              0.0124890        
    125.3115000              0.0846200             -0.0317080              0.0065010              0.0137030              0.0249740              0.0320120        
     63.2423300              0.1792530             -0.0697490              0.0141420              0.0288820              0.0493100              0.0742030        
     32.8240600              0.2920770             -0.1185830              0.0246010              0.0525090              0.0977120              0.1186720        
     17.3969200              0.3290800             -0.1405920              0.0284870              0.0575250              0.0978230              0.1888440        
      9.3243940              0.2060500             -0.0391820              0.0079730              0.0233410              0.0747930              0.1042450        
      4.9388390              0.0521800              0.2070370             -0.0524750             -0.1314790             -0.3728930             -0.9857230        
      2.5620250              0.0007930              0.4068660             -0.0961500             -0.2125180             -0.4521070             -0.5224120        
      1.2992940             -0.0024970              0.3672130             -0.1098910             -0.2149510             -0.0831810              2.0084850        
      0.6346780             -0.0013400              0.1625320              0.0052770              0.2264290              1.1810810             -0.6516730        
      0.2325994             -0.0000960              0.0179490              0.3160560              0.6390330             -0.0996300             -1.0910670        
      0.0915230              0.0000050             -0.0016100              0.5414170              0.3129740             -0.7437020              1.0098080        
Ni    P
      0.0355740              1.0000000        
Ni    P
     10.4540000              1.0000000        
Ni    P
      2.9156000              1.0000000        
Ni    P
      0.0138300              1.0000000        
Ni    D
    432.2741887              0.0003510             -0.0003600              0.0005070             -0.0007300        
    127.4570298              0.0031160             -0.0032190              0.0045770             -0.0062770        
     48.83096424             0.0160110             -0.0165480              0.0235490             -0.0340630        
     21.01674656             0.0546140             -0.0572710              0.0831870             -0.1184390        
      9.65710264             0.1364950             -0.1468730              0.2210890             -0.3663900        
      4.60305286             0.2389110             -0.2479010              0.3398130             -0.3205530        
      2.18924426             0.3000020             -0.2234890              0.0390780              0.6939770        
      1.01439313             0.2906960              0.0132390             -0.5221520              0.4623840        
      0.45035253             0.2209770              0.3104770             -0.3950570             -0.8214790        
      0.18765306             0.1203230              0.4522510              0.3656590             -0.1860170        
Ni    D
      0.07047793             1.0000000        
Ni    D
      6.8868000              1.0000000        
Ni    D
      3.5696000              1.0000000        
Ni    D
      0.0264700              1.0000000        
Ni    F
     10.2360000              1.0000000        
Ni    F
      4.3458000              1.0000000        
Ni    F
      1.8450000              1.0000000        
Ni    F
      0.6302000              1.0000000        
Ni    F
      0.2152600              1.0000000        
Ni    G
      8.4803000              1.0000000        
Ni    G
      3.7875000              1.0000000        
Ni    G
      1.5215000              1.0000000        
Ni    G
      0.6112100              1.0000000        
Ni    H
      7.5953000              1.0000000        
Ni    H
      3.1948000              1.0000000        
Ni    H
      1.3438200              1.0000000        
end
basis "Cu_aug-cc-pwCVQZ-DK" SPHERICAL
Cu    S
 16665490.0000000            0.0000690             -0.0000390              0.0000090             -0.0000020             -0.0000030             -0.0000070             -0.0000070        
 2495213.0000000             0.0001920             -0.0001080              0.0000240             -0.0000050             -0.0000090             -0.0000190             -0.0000200        
 567850.7000000              0.0005020             -0.0002830              0.0000640             -0.0000130             -0.0000240             -0.0000490             -0.0000520        
 160853.1000000              0.0012000             -0.0006760              0.0001530             -0.0000310             -0.0000590             -0.0001170             -0.0001210        
  52481.8600000              0.0028120             -0.0015880              0.0003590             -0.0000730             -0.0001370             -0.0002720             -0.0003000        
  18948.8500000              0.0065760             -0.0037300              0.0008470             -0.0001730             -0.0003320             -0.0006580             -0.0006410        
   7391.6550000              0.0155630             -0.0088800              0.0020240             -0.0004130             -0.0007580             -0.0015150             -0.0017830        
   3066.5170000              0.0366600             -0.0212230              0.0049000             -0.0010020             -0.0019560             -0.0038590             -0.0034630        
   1337.9940000              0.0824010             -0.0488990              0.0114730             -0.0023440             -0.0042140             -0.0084690             -0.0107780        
    608.7830000              0.1643320             -0.1033220              0.0253410             -0.0051920             -0.0103720             -0.0203920             -0.0163220        
    286.8980000              0.2621450             -0.1841780              0.0483250             -0.0098910             -0.0171440             -0.0348960             -0.0508210        
    139.1530000              0.2764660             -0.2462790              0.0738920             -0.0152450             -0.0325260             -0.0634080             -0.0344510        
     68.4945500              0.1478900             -0.1557580              0.0509150             -0.0104490             -0.0120170             -0.0280780             -0.1011720        
     31.6010800              0.0715990              0.2083890             -0.1083140              0.0225660              0.0239630              0.0570580              0.2246670        
     15.9915800              0.1144220              0.5500740             -0.3914490              0.0864480              0.2119610              0.4302750              0.1699430        
      8.0565100              0.0747330              0.3499800             -0.3369910              0.0753310              0.0842800              0.2973020              1.1132610        
      3.6903290              0.0089010              0.0438090              0.3223440             -0.0842130             -0.0894720             -0.7723650             -3.5632140        
      1.7629020             -0.0003240             -0.0036690              0.6829570             -0.2151650             -0.8091960             -1.5798620              2.7675090        
      0.8012690             -0.0000580             -0.0005070              0.2970280             -0.1866230              0.3242170              2.5350850              0.2188800        
      0.1842430             -0.0000130             -0.0001860              0.0119740              0.2899280              1.4472890             -0.5516530             -3.2660310        
      0.0817930              0.0000070              0.0001150             -0.0026920              0.5722780             -0.4431320             -1.3122570              4.5609720        
Cu    S
      0.0353030              1.0000000        
Cu    S
      7.2310000              1.0000000        
Cu    S
      1.9080000              1.0000000        
Cu    S
      0.0152400              1.0000000        
Cu    P
  48218.4100000              0.0000610             -0.0000220              0.0000040              0.0000090              0.0000170              0.0000210        
  11420.5500000              0.0002180             -0.0000790              0.0000150              0.0000300              0.0000580              0.0000800        
   3713.5690000              0.0008730             -0.0003170              0.0000620              0.0001240              0.0002460              0.0002990        
   1423.7620000              0.0031990             -0.0011670              0.0002260              0.0004430              0.0008420              0.0011990        
    606.6041000              0.0109150             -0.0040020              0.0007840              0.0015740              0.0031310              0.0037440        
    278.2564000              0.0328650             -0.0122280              0.0023700              0.0046340              0.0087870              0.0127080        
    134.8449000              0.0852580             -0.0324630              0.0063880              0.0128440              0.0257090              0.0303320        
     68.1225400              0.1802690             -0.0712940              0.0138590              0.0269700              0.0507520              0.0759830        
     35.4008800              0.2930290             -0.1210220              0.0241140              0.0491200              0.1002550              0.1085020        
     18.7902900              0.3282030             -0.1421450              0.0275710              0.0529930              0.1005250              0.2051540        
     10.0835600              0.2037720             -0.0363680              0.0070970              0.0206170              0.0733500              0.0570150        
      5.3461200              0.0514610              0.2125470             -0.0519240             -0.1226650             -0.3887260             -0.9117820        
      2.7752280              0.0013730              0.4098670             -0.0926040             -0.1911910             -0.4495470             -0.5409620        
      1.4075640             -0.0018930              0.3653240             -0.1055640             -0.2074430             -0.0766170              1.9497620        
      0.6872130             -0.0010340              0.1559160              0.0063780              0.1926460              1.1820700             -0.5880390        
      0.2473970             -0.0000600              0.0154970              0.3117760              0.6490010             -0.0996590             -1.1302240        
      0.0961870              0.0000000             -0.0015450              0.5407510              0.3287320             -0.7171210              1.0441460        
Cu    P
      0.0369480              1.0000000        
Cu    P
     11.9218000              1.0000000        
Cu    P
      3.2325000              1.0000000        
Cu    P
      0.0141900              1.0000000        
Cu    D
    556.3170000              0.0002610             -0.0003240              0.0003890             -0.0006030        
    163.6920000              0.0023440             -0.0029180              0.0035340             -0.0050540        
     62.7973000              0.0124860             -0.0155940              0.0189360             -0.0293200        
     27.2478000              0.0442820             -0.0559610              0.0689280             -0.1016320        
     12.6298000              0.1159340             -0.1518160              0.1972720             -0.3526730        
      6.1034100              0.2174500             -0.2797870              0.3487360             -0.4213890        
      2.9654480              0.2914210             -0.2715330              0.0597030              0.7343300        
      1.4126530              0.2983570              0.0180900             -0.5596990              0.5564940        
      0.6498450              0.2379860              0.3562040             -0.3880260             -0.9765450        
      0.2837010              0.1332530              0.4201600              0.4383270             -0.0899130        
Cu    D
      0.1133290              1.0000000        
Cu    D
      8.4804000              1.0000000        
Cu    D
      4.4553000              1.0000000        
Cu    D
      0.0452700              1.0000000        
Cu    F
     11.9463000              1.0000000        
Cu    F
      5.0345000              1.0000000        
Cu    F
      2.1217000              1.0000000        
Cu    F
      0.7284000              1.0000000        
Cu    F
      0.2500700              1.0000000        
Cu    G
      9.5934000              1.0000000        
Cu    G
      4.3083000              1.0000000        
Cu    G
      1.7494000              1.0000000        
Cu    G
      0.7103500              1.0000000        
Cu    H
      8.5704000              1.0000000        
Cu    H
      3.7293000              1.0000000        
Cu    H
      1.6227600              1.0000000        
end
basis "Zn_aug-cc-pwCVQZ-DK" SPHERICAL
Zn    S
      0.1785293E+08          0.0000790             -0.0000250              0.0000090             -0.0000020             -0.0000050              0.0000070             -0.0000100        
 2673038.0000000             0.0002200             -0.0000690              0.0000260             -0.0000050             -0.0000150              0.0000210             -0.0000280        
 608324.4000000              0.0005730             -0.0001810              0.0000690             -0.0000140             -0.0000390              0.0000540             -0.0000730        
 172317.6000000              0.0013640             -0.0004320              0.0001640             -0.0000330             -0.0000930              0.0001270             -0.0001710        
  56222.6900000              0.0031790             -0.0010080              0.0003820             -0.0000770             -0.0002130              0.0002990             -0.0004140        
  20299.8500000              0.0073820             -0.0023580              0.0008950             -0.0001820             -0.0005170              0.0006950             -0.0009140        
   7918.8710000              0.0173430             -0.0055880              0.0021220             -0.0004290             -0.0011580              0.0016700             -0.0023740        
   3285.3400000              0.0406290             -0.0133770              0.0051030             -0.0010360             -0.0030170              0.0039400             -0.0050120        
   1433.5240000              0.0911280             -0.0311060              0.0118880             -0.0024050             -0.0063280              0.0094460             -0.0139070        
    652.2889000              0.1824150             -0.0675820              0.0261860             -0.0053370             -0.0159920              0.0201520             -0.0245170        
    307.4360000              0.2944610             -0.1266200              0.0498050             -0.0100900             -0.0253830              0.0404710             -0.0633700        
    149.1466000              0.3208580             -0.1842860              0.0759660             -0.0156710             -0.0508780              0.0582110             -0.0618520        
     73.4510800              0.1763940             -0.1210030              0.0517660             -0.0104000             -0.0147930              0.0480920             -0.1068480        
     33.9256200              0.0269500              0.2220190             -0.1129780              0.0231260              0.0305570             -0.1061780              0.2254310        
     17.1894700             -0.0014620              0.5609470             -0.4012980              0.0899450              0.3475700             -0.3822290              0.5674800        
      8.6665950              0.0009880              0.3524860             -0.3347370              0.0735120              0.1094030             -0.5135870              1.0107520        
      3.9725050             -0.0004540              0.0454330              0.3331000             -0.0850030             -0.2208400              1.5357960             -5.5611700        
      1.8946650              0.0001670              0.0000520              0.6889720             -0.2289690             -1.3044110              0.6749030              6.9915000        
      0.8593850             -0.0000670              0.0010090              0.2848640             -0.1810930              1.0663570             -2.5422360             -3.5424600        
      0.1952560              0.0000210             -0.0001180              0.0082440              0.3479990              1.4271740              2.3368240              0.0395280        
      0.0858540             -0.0000150              0.0000890             -0.0030930              0.5700400             -1.2613610             -0.9072220              1.6266830        
Zn    S
      0.0367810              1.0000000        
Zn    S
      8.5751000              1.0000000        
Zn    S
      3.2475000              1.0000000        
Zn    S
      0.0157600              1.0000000        
Zn    P
  52867.9300000              0.0000630             -0.0000240              0.0000040              0.0000080              0.0000170             -0.0000220        
  12511.7900000              0.0002210             -0.0000830              0.0000150              0.0000270              0.0000580             -0.0000800        
   4065.2860000              0.0008710             -0.0003270              0.0000610              0.0001090              0.0002460             -0.0002860        
   1557.5950000              0.0031550             -0.0011910              0.0002180              0.0003850              0.0008210             -0.0011850        
    663.2892000              0.0107140             -0.0040650              0.0007550              0.0013540              0.0030900             -0.0034930        
    304.1561000              0.0322280             -0.0124020              0.0022760              0.0040080              0.0085000             -0.0125320        
    147.3680000              0.0837700             -0.0329760              0.0061530              0.0110550              0.0254170             -0.0281370        
     74.4546900              0.1778440             -0.0726830              0.0133900              0.0234910              0.0492100             -0.0760000        
     38.7149300              0.2905790             -0.1239840              0.0234670              0.0425770              0.1006690             -0.0985060        
     20.5702200              0.3275000             -0.1462900              0.0268920              0.0468610              0.0965090             -0.2143670        
     11.0542500              0.2059230             -0.0402280              0.0074420              0.0177220              0.0819270             -0.0265110        
      5.8746610              0.0549140              0.2098190             -0.0497760             -0.1003030             -0.3834010              0.7728880        
      3.0529360              0.0049090              0.4113650             -0.0890630             -0.1633930             -0.4182030              0.6874980        
      1.5472250              0.0009730              0.3688220             -0.1028810             -0.1893930             -0.1677070             -1.8748440        
      0.7541510              0.0001840              0.1542010              0.0042210              0.1172440              1.1948090              0.3864500        
      0.2655530              0.0000500              0.0141420              0.3049800              0.6469500             -0.0019210              1.2436150        
      0.1019080             -0.0000120             -0.0015040              0.5410500              0.3799520             -0.7337660             -1.0725970        
Zn    P
      0.0386230              1.0000000        
Zn    P
     12.6589000              1.0000000        
Zn    P
      3.4452000              1.0000000        
Zn    P
      0.0146400              1.0000000        
Zn    D
    690.0847000              0.0002080             -0.0002900             -0.0003220              0.0004570        
    202.3066000              0.0018800             -0.0026300             -0.0029800              0.0037910        
     77.4459400              0.0103150             -0.0145340             -0.0163530              0.0230360        
     33.6837800              0.0379340             -0.0539330             -0.0616730              0.0812020        
     15.6699800              0.1028900             -0.1524270             -0.1858900              0.2937930        
      7.6224700              0.2026810             -0.3000970             -0.3750080              0.4477370        
      3.7499780              0.2845300             -0.3103010             -0.0401820             -0.6033540        
      1.8181510              0.3024300              0.0218570              0.6109590             -0.6904040        
      0.8555970              0.2489250              0.3961220              0.3386520              0.9760680        
      0.3838420              0.1422960              0.3968090             -0.4891340              0.2286070        
Zn    D
      0.1579520              1.0000000        
Zn    D
      9.2106000              1.0000000        
Zn    D
      5.1966000              1.0000000        
Zn    D
      0.0650000              1.0000000        
Zn    F
     13.1492000              1.0000000        
Zn    F
      5.6206000              1.0000000        
Zn    F
      2.4025000              1.0000000        
Zn    F
      0.8403000              1.0000000        
Zn    F
      0.2939000              1.0000000        
Zn    G
     10.7622000              1.0000000        
Zn    G
      4.9010000              1.0000000        
Zn    G
      2.0378000              1.0000000        
Zn    G
      0.8473000              1.0000000        
Zn    H
      9.6056000              1.0000000        
Zn    H
      4.3396000              1.0000000        
Zn    H
      1.9605400              1.0000000        
end