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#  s3-21G  EMSL  Basis Set Exchange Library  3/15/13 10:17 AM
# Elements                             References
# --------                             ----------
# Sc-Zn: M. Swart, M. Güell, J.M. Luis and M. Solà, Spin-state corrected Gaussian-type orbital basis sets, J. Phys. Chem. A 114, 7191?7197 (2010).
# 



basis "Sc_s3-21G" SPHERICAL
Sc    S
   2119.887000000            0.06442100       
    320.429900000            0.37916000       
     69.898930000            0.67896300       
Sc    SP
     89.764500000           -0.10938400             0.13632800       
     19.385100000            0.10507000             0.54186000       
      5.731423000            0.95220500             0.49505500       
Sc    SP
      5.491938000           -0.28521100             0.01761400       
      1.743742000            0.32415500             0.43364500       
      0.566227000            0.85659200             0.64255100       
Sc    SP
      0.516802000           -0.26267800             0.00032700       
      0.067214000            1.10807900             0.99989300       
Sc    SP
      0.025985000            1.00000000             1.00000000       
Sc    D
      5.722215000            0.26523600       
      1.360849000            0.85586100       
Sc    D
      0.322652000            1.0000000        
Sc    D
      0.076620000            1.0000000        
end
basis "Ti_s3-21G" SPHERICAL
Ti    S
   2335.020000000            0.06421700       
    353.044100000            0.37841200       
     77.058450000            0.67968100       
Ti    SP
     99.573870000           -0.10947200             0.13729700       
     21.546710000            0.10194300             0.54587500       
      6.413965000            0.95462200             0.48906800       
Ti    SP
      6.238279000           -0.28613700             0.01923700       
      1.996108000            0.32182800             0.44044200       
      0.646490000            0.85955100             0.63562000       
Ti    SP
      0.573285000           -0.24245000             0.00029200       
      0.073119000            1.10007500             0.99990700       
Ti    SP
      0.026538000            1.00000000             1.00000000       
Ti    D
      7.083666000            0.26292100       
      1.709634000            0.85577200       
Ti    D
      0.414123000            1.0000000        
Ti    D
      0.100130000            1.0000000        
end
basis "V_s3-21G" SPHERICAL
V    S
   2563.877000000            0.06394800       
    387.534000000            0.37759400       
     84.598230000            0.68054200       
V    SP
    109.793800000           -0.10983600             0.13842100       
     23.769210000            0.10070700             0.55048900       
      7.122961000            0.95563300             0.48241700       
V    SP
      6.981204000           -0.28845900             0.02182100       
      2.219839000            0.33643600             0.45676200       
      0.719803000            0.84819000             0.61867500       
V    SP
      0.631262000           -0.23649000             0.00019000       
      0.080062000            1.09772100             0.99994000       
V    SP
      0.028865000            1.00000000             1.00000000       
V    D
      8.342917000            0.26406200       
      2.032944000            0.85396600       
V    D
      0.495712000            1.0000000        
V    D
      0.120830000            1.0000000        
end
basis "Cr_s3-21G" SPHERICAL
Cr    S
   2798.294000000            0.06382400       
    423.137000000            0.37708400       
     92.438860000            0.68098900       
Cr    SP
    120.280600000           -0.11777900             0.13987800       
     26.037270000            0.10143100             0.55598300       
      7.844172000            0.95719800             0.47481800       
Cr    SP
      7.793276000           -0.28885700             0.02218500       
      2.497196000            0.33511500             0.46162500       
      0.805142000            0.85024800             0.61453900       
Cr    SP
      0.703921000           -0.23225100             0.00018000       
      0.086162000            1.09367100             0.99994500       
Cr    SP
      0.032199000            1.00000000             1.00000000       
Cr    D
      9.625339000            0.26559600       
      2.362264000            0.85215600       
Cr    D
      0.577094000            1.0000000        
Cr    D
      0.141310000            1.0000000        
end
basis "Mn_s3-21G" SPHERICAL
Mn    S
   3041.686000000            0.06374500       
    460.090100000            0.37674900       
    100.595800000            0.68124700       
Mn    SP
    131.767300000           -0.11029600             0.14045400       
     28.569150000            0.09819000             0.55780200       
      8.660501000            0.95765900             0.47150100       
Mn    SP
      8.569081000           -0.29171400             0.02422400       
      2.768178000            0.34396300             0.46866000       
      0.887288000            0.84519800             0.60742100       
Mn    SP
      0.767443000           -0.23000400             0.00030800       
      0.092025000            1.09145000             0.99990700       
Mn    SP
      0.033265000            1.00000000             1.00000000       
Mn    D
     11.068840000            0.26527200       
      2.730707000            0.85179500       
Mn    D
      0.668509000            1.0000000        
Mn    D
      0.164290000            1.0000000        
end
basis "Fe_s3-21G" SPHERICAL
Fe    S
   3299.184000000            0.06358600       
    499.088600000            0.37620200       
    109.161400000            0.68178500       
Fe    SP
    143.465200000           -0.11055200             0.14110100       
     31.168580000            0.09684700             0.56038700       
      9.483612000            0.95879700             0.46764400       
Fe    SP
      9.464565000           -0.29205600             0.02376200       
      3.100373000            0.33752400             0.46891100       
      0.986493000            0.85194200             0.60831100       
Fe    SP
      0.853412000           -0.22794400            -0.00042600       
      0.098812000            1.08828700             1.00012400       
Fe    SP
      0.036442000            1.00000000             1.00000000       
Fe    D
     12.354490000            0.26861100       
      3.055605000            0.84927200       
Fe    D
      0.738591000            1.0000000        
Fe    D
      0.180600000            1.0000000        
end
basis "Co_s3-21G" SPHERICAL
Co    S
   3564.762000000            0.06348700       
    539.390800000            0.37581800       
    118.044900000            0.68212200       
Co    SP
    155.438200000           -0.11098700             0.14206400       
     33.815610000            0.09676700             0.56344400       
     10.333230000            0.95899200             0.46302400       
Co    SP
     10.381520000           -0.29226200             0.02631300       
      3.382714000            0.34325100             0.47691700       
      1.076954000            0.84696300             0.59915400       
Co    SP
      0.909015000           -0.21746000             0.00022800       
      0.105041000            1.08499800             0.99993400       
Co    SP
      0.037257000            1.00000000             1.00000000       
Co    D
     13.740700000            0.27095500       
      3.408983000            0.84734200       
Co    D
      0.818641000            1.0000000        
Co    D
      0.199850000            1.0000000        
end
basis "Ni_s3-21G" SPHERICAL
Ni    S
   3848.005000000            0.06326600       
    582.030700000            0.37517100       
    127.367400000            0.68282400       
Ni    SP
    168.289600000           -0.11111500             0.14249000       
     36.656330000            0.09532400             0.56554700       
     11.232120000            0.96016100             0.45999300       
Ni    SP
     11.358770000           -0.29206000             0.02613800       
      3.738846000            0.33754100             0.47659800       
      1.182463000            0.85253300             0.60038000       
Ni    SP
      0.988904000           -0.21368700             0.00029400       
      0.111025000            1.08193300             0.99991700       
Ni    SP
      0.039258000            1.00000000             1.00000000       
Ni    D
     15.220690000            0.27260600       
      3.786020000            0.84592800       
Ni    D
      0.904557000            1.0000000        
Ni    D
      0.220560000            1.0000000        
end
basis "Cu_s3-21G" SPHERICAL
Cu    S
   4134.302000000            0.06318800       
    625.491200000            0.37484500       
    136.955600000            0.68310000       
Cu    SP
    181.496000000           -0.11132000             0.14308400       
     39.574310000            0.09448700             0.56775600       
     12.162460000            0.96087900             0.45671400       
Cu    SP
     12.351110000           -0.29222300             0.02772700       
      4.049651000            0.34299100             0.48352400       
      1.279225000            0.84794600             0.59297800       
Cu    SP
      1.049804000           -0.20650800             0.00013900       
      0.116933000            1.07927300             0.99996100       
Cu    SP
      0.000751000            1.00000000             1.00000000       
Cu    D
     16.759380000            0.27411200       
      4.178977000            0.84462500       
Cu    D
      0.994327000            1.0000000        
Cu    D
      0.242260000            1.0000000        
end
basis "Zn_s3-21G" SPHERICAL
Zn    S
   4432.288000000            0.06309300       
    670.660100000            0.37450400       
    146.902400000            0.68341600       
Zn    SP
    195.004200000           -0.11162800             0.14380600       
     42.568890000            0.09433600             0.57000200       
     13.121430000            0.96110000             0.45331200       
Zn    SP
     13.402310000           -0.29178100             0.02870500       
      4.399906000            0.34261400             0.48625200       
      1.385148000            0.84828400             0.59023500       
Zn    SP
      1.121558000           -0.20237100             0.00034400       
      0.122944000            1.07703500             0.99990500       
Zn    SP
      0.042193000            1.00000000             1.00000000       
Zn    D
     18.368200000            0.27538600       
      4.591304000            0.84347700       
Zn    D
      1.090203000            1.0000000        
Zn    D
      0.265690000            1.0000000        
end