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# $Id: roos-ano-tz 19708 2010-10-29 18:04:21Z d3y133 $
#
#  Roos Augmented Triple Zeta ANO  EMSL  Basis Set Exchange Library  10/25/09 12:12 PM
# Elements                             References
# --------                             ----------
# H - Ne:  P.O. Widmark, P.A. Malmqvist, B. Roos, Theor. Chim. Acta, 77,
# 291 (1990).
# Na - Ar: P.O. Widmark, B. J. Persson and B. Roos Theor. Chim. Acta, 79,
# 419 (1991).
# Sc - Zn: R. Pou-Amerigo, M. Merchan, I. Nebot-Gil, P.O. Widmark and B. Roos,
# Theor. Chim. Acta, 92, 149 (1995).
# 
basis "H_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (8s,4p,3d) -> [4s,3p,2d]
H    S
    188.6144500              0.0009639             -0.0013119              0.0024224             -0.01157010       
     28.2765960              0.0074920             -0.0103451              0.0203382             -0.08371540       
      6.4248300              0.0375954             -0.0504953              0.0896394             -0.44516630       
      1.8150410              0.1433950             -0.2073855              0.4422907             -1.14627100       
      0.5910630              0.3486363             -0.4350885              0.5757144              2.50318710       
      0.2121490              0.4382974             -0.0247297             -0.9802890             -1.58284930       
      0.0798910              0.1651066              0.3225260             -0.6721538              0.03096569       
      0.0279620              0.0210229              0.7072754              1.1417685              0.30862864       
H    P
      2.3050000              0.1127902             -0.2108688              0.7599501        
      0.8067500              0.4185075             -0.5943796              0.1646159        
      0.2823620              0.4700077              0.0896889             -1.3710140        
      0.0988270              0.1826260              0.8611634              1.0593155        
H    D
      1.8190000              0.2705134             -0.7938035        
      0.7276000              0.5510125             -0.0914252        
      0.2910400              0.3310866              0.8620033        
end
basis "He_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (9s,4p,3d) -> [4s,3p,2d]
He    S
   1149.2705000              0.00035774            -0.00053060             0.00070544            -0.0004722        
    172.0445700              0.00277289            -0.00403300             0.00705199            -0.0104722        
     39.0804650              0.01429838            -0.02258040             0.03126037            -0.0194099        
     11.0361730              0.05586749            -0.10262550             0.32197965            -0.7127356        
      3.5641520              0.16336284            -0.45771141             1.00474880            -0.0101329        
      1.2404430              0.33133146            -0.60596530            -1.29080400             1.9343339        
      0.4473160              0.41429728             0.57131336            -0.47258960            -2.5416590        
      0.1642060              0.18903228             0.54758341             0.95308829             0.8981405        
      0.0574720              0.00515606             0.01165900             0.05061692             0.5439594        
He    P
      4.5500000              0.08926060            -0.18673500             0.85489228       
      1.5925000              0.38050238            -0.51173450             0.10926707       
      0.5573750              0.44912372            -0.19815060            -1.26381200       
      0.1950810              0.27765440             0.99587976             0.90243325       
He    D
      3.4000000              0.28055213            -0.95147161       
      1.3600000              0.56558317             0.18505878       
      0.5440000              0.30332967             0.69874000       
end
basis "Li_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
Li    S
   9497.9344000              0.0000747             -0.0000110              0.0000064             -0.0000401              0.0001553        
   1416.8112000              0.0005836             -0.0000857              0.0000489             -0.0003102              0.0012129        
    321.4599400              0.0030610             -0.0004507              0.0002658             -0.0016465              0.0063465        
     91.1241630              0.0126011             -0.0018630              0.0010685             -0.0066395              0.0259317        
     29.9998910              0.0423472             -0.0063575              0.0039771             -0.0226602              0.0853295        
     11.0176310              0.1147580             -0.0177673              0.0112030             -0.0582447              0.2196247        
      4.3728010              0.2393659             -0.0397968              0.0312189             -0.1222607              0.4038897        
      1.8312560              0.3575918             -0.0701282              0.0616508             -0.1352471              0.3648827        
      0.8022610              0.3033758             -0.1029469              0.1506502             -0.0542651             -0.5509683        
      0.3626480              0.0863793             -0.0937078              0.1874783              0.0832013             -1.3876100        
      0.1139950              0.0026439              0.2201288             -1.0941070              1.7479350              1.9839088        
      0.0512370              0.0012170              0.5933774             -0.2924223             -1.6463070             -0.7590298        
      0.0224680              0.0005620              0.2945275              0.8480944             -0.7408542             -0.6844426        
      0.0078600              0.0000197              0.0249503              0.4480009              1.3038650              0.6414520        
Li    P
     13.1195040              0.0014490             -0.0023268              0.0094825             -0.0105332        
      3.0774242              0.0079958             -0.0112242              0.0632078             -0.0734282        
      1.0988005              0.0213485             -0.0344626              0.1751466             -0.2410174        
      0.4357784              0.0501195             -0.0338775              0.5768939             -0.8859633        
      0.1802432              0.1954739             -0.4544520              0.5563516              1.6251780        
      0.0761333              0.4191119             -0.4963084             -1.2910820             -0.3335684        
      0.0325465              0.3481647              0.4885879              0.2070521             -1.2504850        
      0.0140182              0.1505975              0.5602339              0.4286728              0.9468121        
      0.0049064              0.0157033              0.0702807              0.0043312              0.2039821        
Li    D
      0.4500000              0.0223729             -0.0304618              0.1766793        
      0.1575000              0.3750879             -0.5734588              0.9944718        
      0.0551250              0.4689173             -0.2741871             -1.5526210        
      0.0192938              0.3653629              0.9562883              0.8786901        
Li    F
      0.2400000              0.3877783             -0.3795652        
      0.0960000              0.4016098             -0.6103086        
      0.0384000              0.4461499              1.0900688        
end
basis "Be_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
Be    S
  22628.5990000              0.0000533             -0.0000102              0.0000124             -0.0000163              0.0000203        
   3372.3181000              0.0004181             -0.0000804              0.0000976             -0.0001087              0.0001393        
    760.3504000              0.0022260             -0.0004281              0.0005167             -0.0007272              0.0008993        
    211.7404800              0.0095628             -0.0018487              0.0022526             -0.0023214              0.0030392        
     67.2234680              0.0348179             -0.0068008              0.0082282             -0.0124024              0.0155553        
     23.3721770              0.1059461             -0.0213719              0.0264413             -0.0250911              0.0369774        
      8.7213730              0.2456632             -0.0530352              0.0657897             -0.1164622              0.1584546        
      3.4680910              0.3860736             -0.1004577              0.1301064             -0.0631167              0.0835983        
      1.4521440              0.3103732             -0.1375139              0.1975492             -0.6700337              0.9577519        
      0.6086150              0.0638940             -0.0650704              0.0749265              1.2263580             -3.5277230        
      0.2576860             -0.0015314              0.3245732             -1.3887220              1.0746878              3.7533891        
      0.1041760              0.0011825              0.6181643              0.1545829             -2.9624550             -1.1940240        
      0.0424270             -0.0002521              0.2047675              1.0260181              1.5600035             -1.2477800        
      0.0148490              0.0000738              0.0043035              0.0257777              0.2818441              1.3591094        
Be    P
     33.7101840              0.0010378             -0.0012142              0.0025873             -0.0022873        
      8.0576495              0.0066087             -0.0056126              0.0208954             -0.0516249        
      2.8364714              0.0215590             -0.0254797              0.0573716             -0.0217907        
      1.0999657              0.0608778             -0.0114415              0.2642685             -1.0112180        
      0.4433964              0.2035573             -0.5138507              1.0647600              0.7352774        
      0.1822264              0.4579669             -0.4908092             -1.4363070              0.9156694        
      0.0757241              0.3685906              0.7221452             -0.0547326             -1.9316950        
      0.0316854              0.0630641              0.4307622              0.7770346              1.1633019        
      0.0110899              0.0021097              0.0022556             -0.0320504              0.2046835        
Be    D
      1.4000000              0.0066773             -0.0103868              0.1837287        
      0.4900000              0.2468134              0.8925807              0.8424700        
      0.1715000              0.6574463             -0.1507099             -1.4944970        
      0.0600250              0.2535191             -0.6812165              1.1174804        
Be    F
      0.5000000              0.3281297             -1.1039440        
      0.2000000              0.6598042              0.6502298        
      0.0800000              0.1628472              0.3520145        
end
basis "B_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
B    S
  33360.2170000              0.0000583             -0.0000121              0.0000121             -0.0000180              0.0000215        
   4972.0952000              0.0004565             -0.0000950              0.0000945             -0.0001292              0.0001376        
   1125.6417000              0.0024089             -0.0005028              0.0004997             -0.0007771              0.0009649        
    316.4913600              0.0101631             -0.0021264              0.0021192             -0.0027820              0.0028031        
    102.0072600              0.0360955             -0.0076744              0.0076519             -0.0125600              0.0165450        
     36.2958730              0.1059810             -0.0232179              0.0234045             -0.0301270              0.0306156        
     13.9714100              0.2395654             -0.0569468              0.0581156             -0.1113291              0.1680322        
      5.7411560              0.3737726             -0.1062577              0.1116739             -0.1047497              0.0264152        
      2.4942680              0.3081465             -0.1457694              0.1705623             -0.4598841              0.8205322        
      1.1142020              0.0776928             -0.0430285              0.0172676              0.6740179             -2.1545330        
      0.4215490              0.0014797              0.3719441             -0.9989044              1.5042519              1.0217582        
      0.1696330              0.0004991              0.5652090             -0.2265722             -2.4760430              1.7061016        
      0.0685350             -0.0000262              0.1921269              1.0294550              0.5776670             -3.0837640        
      0.0239870              0.0000236              0.0219128              0.2213786              0.7429993              1.8083378        
B    P
     55.0000000              0.0010186             -0.0007776              0.0007590             -0.0032210        
     13.3661010              0.0073958             -0.0057768              0.0059151             -0.0325794        
      4.1353940              0.0322514             -0.0226134              0.0136009             -0.1313091        
      1.4812560              0.0983464             -0.0696834              0.0320628             -0.6809573        
      0.6021360              0.2318024             -0.2551146              0.6295261             -0.3491983        
      0.2556360              0.3412436             -0.3607786              0.1732649              1.3937462        
      0.1111510              0.2932983              0.0612395             -0.8917853             -0.3529796        
      0.0476480              0.1695951              0.2959938             -0.3535550             -0.7747354        
      0.0166770              0.1507569              0.6629278              0.8469041              0.5768738        
B    D
      1.2000000              0.0803458             -0.1224628              0.5130462        
      0.4200000              0.4219358             -0.5604733              0.5097938        
      0.1470000              0.4639167             -0.0894260             -1.3189990        
      0.0514500              0.2855734              0.9015938              0.8663855        
B    F
      0.8500000              0.1825219             -0.4773313        
      0.3400000              0.3946453             -0.6578114        
      0.1360000              0.6104375              0.9513672        
end
basis "C_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
C    S
  50557.5010000              0.0000553             -0.0000120              0.0000119             -0.0000156              0.0000174        
   7524.7856000              0.0004343             -0.0000940              0.0000927             -0.0001140              0.0001232        
   1694.3276000              0.0023159             -0.0005028              0.0004989             -0.0006731              0.0007634        
    472.8227900              0.0098729             -0.0021476              0.0021180             -0.0025323              0.0027003        
    151.7107500              0.0352195             -0.0077942              0.0077784             -0.0109003              0.0126780        
     53.9187460              0.1041938             -0.0237634              0.0236328             -0.0277807              0.0302866        
     20.6593110              0.2412741             -0.0600235              0.0616306             -0.0958713              0.1201464        
      8.3839760              0.3840174             -0.1153985              0.1189680             -0.1247806              0.1242773        
      3.5770150              0.3082371             -0.1539009              0.1880621             -0.3932460              0.5530431        
      1.5471180              0.0683055             -0.0145946             -0.0540304              0.6796004             -1.6604970        
      0.6130130              0.0007782              0.3895849             -0.9814137              1.1978690              0.2197707        
      0.2460680              0.0009905              0.5397291             -0.1096758             -1.8979520              2.6568329        
      0.0990870             -0.0000893              0.1884060              0.8847356             -0.0044614             -3.5965560        
      0.0346800              0.0000471              0.0258575              0.2964983              1.0142148              1.8521129        
C    P
     83.3331550              0.0012241             -0.0011444              0.0014669             -0.0037213        
     19.5576110              0.0094389             -0.0089796              0.0144553             -0.0379844        
      6.0803650              0.0417744             -0.0378456              0.0466373             -0.1698042        
      2.1793170              0.1318330             -0.1292708              0.2366537             -0.8114152        
      0.8651500              0.2789119             -0.3784022              0.6088734              0.2421730        
      0.3619440              0.3668663             -0.2692137             -0.3917793              1.3030673        
      0.1547400              0.2790591              0.2917542             -0.8700229             -1.2001420        
      0.0654290              0.1380481              0.5436698              0.4200505             -0.0905452        
      0.0229000              0.0341950              0.2628308              0.5799497              0.5698009        
C    D
      1.9000000              0.0987312             -0.1455013              0.5637683        
      0.6650000              0.4529661             -0.5076809              0.4312592        
      0.2327500              0.4362457             -0.1015630             -1.2779980        
      0.0814630              0.2719250              0.9251922              0.8354205        
C    F
      1.2500000              0.3113650             -0.5041380        
      0.5000000              0.5159673             -0.4373719        
      0.2000000              0.3774231              1.0147246        
end
basis "N_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
N    S
  74761.7150000              0.0000502             -0.0000112              0.0000097             -0.0000121              0.0000187        
  11123.6540000              0.0003946             -0.0000878              0.0000765             -0.0000903              0.0001293        
   2512.6857000              0.0020885             -0.0004667              0.0004048             -0.0005179              0.0008218        
    703.7772900              0.0089079             -0.0019931              0.0017398             -0.0020046              0.0027758        
    225.4787900              0.0320884             -0.0073033              0.0063456             -0.0083600              0.0137694        
     79.6158100              0.0974474             -0.0228259              0.0201405             -0.0227440              0.0311642        
     30.2372830              0.2317895             -0.0592207              0.0524031             -0.0744866              0.1356368        
     12.2636220              0.3776911             -0.1156121              0.1066517             -0.1108600              0.1355762        
      5.2650860              0.3187917             -0.1565083              0.1583388             -0.2983389              0.6663341        
      2.3334710              0.0823782             -0.0231058             -0.0050051              0.3212822             -1.6249420        
      0.9018560              0.0027905              0.3756476             -0.8418720              1.1710298             -0.3859865        
      0.3583360              0.0002465              0.5457653             -0.1590563             -0.8649562              3.2306654        
      0.1410930             -0.0000289              0.2103543              0.5912026             -1.2237930             -3.5174500        
      0.0493830              0.0000097              0.0127895              0.5766053              1.4445805              1.5200656        
N    P
    126.6665700              0.0011423             -0.0009565              0.0014201             -0.0027058        
     29.8373890              0.0089591             -0.0075763              0.0125439             -0.0302621        
      9.3940380              0.0405375             -0.0336947              0.0509913             -0.1190992        
      3.4051040              0.1294901             -0.1133437              0.2057118             -0.6278549        
      1.3500000              0.2767808             -0.3055498              0.5452041             -0.2116148        
      0.5576960              0.3688889             -0.2733953             -0.1522542              1.4074630        
      0.2324490              0.2934619              0.2019252             -0.8377166             -0.6666649        
      0.0942640              0.1284683              0.4925344              0.0496595             -0.6807072        
      0.0329920              0.0390586              0.4098012              0.7459441              0.7498486        
N    D
      2.7500000              0.12053068            -0.1733321              0.61298904       
      0.9625000              0.50760685            -0.4739903              0.31696608       
      0.3368750              0.44539556             0.0367881             -1.21666300       
      0.1179060              0.15876917             0.89316126             0.87035573       
N    F
      1.8000000              0.33068755            -0.7670701        
      0.7200000              0.55560706            -0.0111511        
      0.2880000              0.30748869             0.80193318       
end
basis "O_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
O    S
 105374.9500000              0.0000459             -0.0000105              0.0000090             -0.0000109              0.0000181        
  15679.2400000              0.0003607             -0.0000825              0.0000705             -0.0000822              0.0001213        
   3534.5447000              0.0019198             -0.0004412              0.0003757             -0.0004675              0.0008093        
    987.3651600              0.0082067             -0.0018864              0.0016146             -0.0018465              0.0025770        
    315.9787500              0.0297257             -0.0069540              0.0059340             -0.0075585              0.0137794        
    111.6542800              0.0904558             -0.0217208              0.0187866             -0.0210868              0.0281112        
     42.6994510              0.2174054             -0.0568513              0.0494683             -0.0667511              0.1374754        
     17.3955960              0.3687657             -0.1139635              0.1030399             -0.1093673              0.1220690        
      7.4383090              0.3372798             -0.1620201              0.1620586             -0.2731431              0.7373493        
      3.2228620              0.0967505             -0.0333800              0.0009367              0.2097137             -1.7057510        
      1.2538770              0.0025674              0.3655068             -0.8224251              1.2034807             -0.3504060        
      0.4951550              0.0013746              0.5520031             -0.1017902             -0.6774694              3.1429946        
      0.1916650             -0.0001410              0.2236393              0.4253939             -1.4298840             -3.3474810        
      0.0670830              0.0000683              0.0065745              0.6877028              1.4891068              1.4012375        
O    P
    200.0000000              0.0008933             -0.0008384              0.0012618             -0.0019528        
     46.5333670              0.0073690             -0.0068491              0.0111628             -0.0243404        
     14.6218090              0.0349392             -0.0328505              0.0518316             -0.0944754        
      5.3130640              0.1152985             -0.1100060              0.1978845             -0.5489856        
      2.1025250              0.2583231             -0.3135263              0.5707652             -0.3495476        
      0.8502230              0.3696231             -0.3196011             -0.1789291              1.4659089        
      0.3375970              0.3238789              0.2217243             -0.8982077             -0.7571894        
      0.1288920              0.1467989              0.5622616              0.2666643             -0.5905673        
      0.0451120              0.0336127              0.3013251              0.6258994              0.7959321        
O    D
      3.7500000              0.1284934             -0.2182055              0.6242093        
      1.3125000              0.5211884             -0.4817695              0.2403063        
      0.4593750              0.4345784              0.1357595             -1.1836420        
      0.1607810              0.1457409              0.8297734              0.9208722        
O    F
      2.3500000              0.3634111             -0.8835406        
      0.9400000              0.5621555              0.2262408        
      0.3760000              0.2635279              0.6722325        
end
basis "F_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
F    S
 103109.4600000              0.0000637             -0.0000148              0.0000151             -0.0000154              0.0000245        
  15281.0070000              0.0005028             -0.0001172              0.0001187             -0.0001160              0.0001693        
   3441.5392000              0.0026677             -0.0006239              0.0006363             -0.0006596              0.0010891        
    967.0948300              0.0112003             -0.0026280              0.0026599             -0.0025500              0.0035621        
    314.0353400              0.0390980             -0.0093503              0.0096068             -0.0102361              0.0177703        
    113.4423000              0.1122657             -0.0278490              0.0284336             -0.0267629              0.0358282        
     44.6447270              0.2472042             -0.0676880              0.0719831             -0.0829345              0.1627494        
     18.9428740              0.3680345             -0.1230542              0.1310393             -0.1141649              0.1226370        
      8.5327430              0.2908617             -0.1522180              0.2031617             -0.3160866              0.8037417        
      3.9194010              0.0781024             -0.0075794             -0.0915990              0.4487239             -2.2316140        
      1.5681570              0.0035403              0.3759313             -1.0070250              1.1605351              0.6332833        
      0.6232900              0.0009157              0.5438482              0.0174627             -1.3695700              2.2900002        
      0.2408610              0.0000765              0.2127746              0.7490027             -0.6041401             -3.1231590        
      0.0843010              0.0000205              0.0066422              0.3447692              1.2967102              1.5381196        
F    P
    245.3302900              0.0009880             -0.0009793              0.0014003             -0.0021447        
     56.9190050              0.0082911             -0.0083410              0.0135623             -0.0279769        
     17.6045680              0.0407390             -0.0407457              0.0606052             -0.1126856        
      6.2749950              0.1353304             -0.1455266              0.2678220             -0.6847635        
      2.4470300              0.2809637             -0.3556275              0.5818369              0.0245360        
      0.9950600              0.3588351             -0.2537163             -0.4280396              1.3824370        
      0.4039730              0.3038112              0.2808700             -0.7991571             -1.1445170        
      0.1548100              0.1389379              0.5652035              0.4685214             -0.2020471        
      0.0541840              0.0258186              0.2323708              0.4862441              0.6854872        
F    D
      5.0000000              0.1303559             -0.2833655              0.6483531        
      1.7500000              0.5255055             -0.5329589              0.0852813        
      0.6125000              0.4421640              0.3393474             -1.0762450        
      0.2143750              0.1232747              0.6772189              1.0003287        
F    F
      3.2000000              0.3564982             -0.8994161        
      1.2800000              0.5841154              0.2624802        
      0.5120000              0.2404222              0.6517354        
end
basis "Ne_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (14s,9p,4d,3f) -> [5s,4p,3d,2f]
Ne    S
 166165.0800000              0.0000472             -0.0000111              0.0000138             -0.0000134              0.0000187        
  23107.5240000              0.0004007             -0.0000942              0.0001155             -0.0001015              0.0001378        
   5060.1539000              0.0021932             -0.0005180              0.0006492             -0.0006547              0.0009261        
   1384.6123000              0.0095876             -0.0022665              0.0027632             -0.0023205              0.0031060        
    436.5125800              0.0350734             -0.0084593              0.0107336             -0.0113825              0.0163981        
    153.4714800              0.1046517             -0.0260486              0.0318325             -0.0253425              0.0340752        
     59.3890870              0.2377123             -0.0653597              0.0871960             -0.1058383              0.1609211        
     24.8619670              0.3696061             -0.1222657              0.1529811             -0.0983722              0.1377601        
     11.0157040              0.3061609             -0.1585710              0.2847979             -0.5230270              0.8847408        
      4.9651750              0.0841985             -0.0060287             -0.1929549              1.1226234             -2.8322420        
      1.9365030              0.0037035              0.3828957             -1.3225880              0.4901401              2.1910109        
      0.7657280              0.0009654              0.5388649              0.4901279             -1.7379050              0.4452102        
      0.2955380              0.0000540              0.2114487              0.7546175              0.3977872             -2.2075830        
      0.1034380              0.0000268              0.0028049              0.0613671              0.8900413              1.5272555        
Ne    P
    234.9450000              0.0015826             -0.0022102              0.0033989             -0.0075907        
     55.0773850              0.0125767             -0.0185114              0.0363047             -0.0418546        
     17.3895490              0.0569865             -0.0815212              0.1439289             -0.4327586        
      6.3895370              0.1681230             -0.2923570              0.7336464             -0.7725174        
      2.5420820              0.3073860             -0.5403060             -0.1076693              2.1038154        
      1.0337640              0.3583112              0.0915155             -1.2143150             -1.5972860        
      0.4187880              0.2786938              0.6090880              0.6410833             -0.0026161        
      0.1646270              0.0952111              0.2435274              0.3568617              0.6386064        
      0.0576190              0.0021020              0.0071303              0.0189501             -0.0022546        
Ne    D
      6.4200000              0.1370856             -0.4204726              0.7415580        
      2.2470000              0.5447100             -0.5592957             -0.3478303        
      0.7864500              0.4497274              0.7000099             -0.6598257        
      0.2752575              0.0653709              0.3390023              1.0210673        
Ne    F
      4.1900000              0.3459704             -0.9362870        
      1.6760000              0.6148682              0.3366642        
      0.6704000              0.2083229              0.6035397        
end
basis "Na_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
Na    S
 138773.7200000              0.00007636            -0.00001870             0.00000255            -0.00000230             0.00000364            -0.00000170       
  20325.8990000              0.00052939            -0.00012910             0.00001760            -0.00001600             0.00002582            -0.00001000       
   5878.6049000              0.00183722            -0.00045110             0.00006160            -0.00005530             0.00008615            -0.00004890       
   2015.4373000              0.00653431            -0.00159820             0.00021769            -0.00019860             0.00032753            -0.00012770       
    739.6265800              0.02092231            -0.00521350             0.00071184            -0.00063400             0.00100249            -0.00077750       
    280.8211600              0.06426610            -0.01627270             0.00221369            -0.00199710             0.00347727            -0.00272200       
    108.7150100              0.17089923            -0.04645830             0.00632867            -0.00546590             0.00977528            -0.01681110       
     42.6015720              0.35610342            -0.11144450             0.01509121            -0.01276240             0.02880208            -0.07091840       
     16.8298170              0.40213461            -0.18537340             0.02530901            -0.01876960             0.05266945            -0.23941720       
      6.6864486              0.12746393            -0.06005440             0.00808949            -0.00747550             0.02852077            -0.06083470       
      2.6674877              0.00061064             0.35924086            -0.05305070             0.03897469            -0.18124290             0.78439608       
      1.0674621              0.00338457             0.57207971            -0.11164110             0.08327536            -0.14683560             0.84719710       
      0.4281891             -0.00132870             0.22321420            -0.13831340             0.20560497            -0.33984270            -2.0362530        
      0.1720801              0.00085748            -0.00502860            -0.02990100            -0.04683150             0.65955083            -0.24226820       
      0.0692588             -0.00047610             0.00595957             0.44900485            -0.79823140             1.8591377              2.3580377        
      0.0279092              0.00022186            -0.00253770             0.47484493            -0.57595290            -3.5576120             -2.2557800        
      0.0111633             -0.00006380             0.00078635             0.22905052             1.4408654              1.8865531              0.90445966       
Na    P
    383.7917200              0.00102867            -0.00011860             0.00015162            -0.00018580             0.00002038       
     94.3980720              0.00743093            -0.00086340             0.00110681            -0.00115460            -0.00049790       
     32.3615070              0.03273646            -0.00379970             0.00487773            -0.00606080             0.00196514       
     12.0543520              0.11687036            -0.01384260             0.01792042            -0.01828510            -0.00087320       
      4.6417186              0.27753763            -0.03315040             0.04350073            -0.05598100             0.05166830       
      1.8172876              0.39800015            -0.04899740             0.06554272            -0.05672000            -0.01024290       
      0.7182712              0.32331086            -0.04658270             0.07245938            -0.15067210             0.47624183       
      0.2855803              0.09433492            -0.03024570             0.09073829            -0.00335500            -0.88974630       
      0.1139947              0.00109373             0.22294313            -0.76763740             1.5488268             -0.26055090       
      0.0456292              0.00178158             0.50923252            -0.39771490            -1.8994640              1.9011944        
      0.0183010             -0.00069800             0.37196823             0.92303779             0.39892154            -2.6344810        
      0.0073204              0.00022539             0.04475107             0.17065606             0.64929030             1.6808822        
Na    D
      0.8626036              0.02177426            -0.01348600             0.02840092       
      0.3451418             -0.00721860            -0.00299870            -0.20618900       
      0.1380969              0.33517471            -0.46667530            -1.2158830        
      0.0552548              0.36379749            -0.62374900             1.8313353        
      0.0221019              0.49254995             1.1090949             -0.92087030       
Na    F
      0.3281449              0.01063271            -0.03833350       
      0.1573473             -0.49599110            -0.30098330       
      0.0754489             -0.26287320            -0.64602910       
      0.0301796             -0.47485960             1.1242100        
end
basis "Mg_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
Mg    S
 169973.8700000              0.00007417            -0.00001880             0.00000379            -0.00000440             0.00000684            -0.00000710       
  24699.0660000              0.00051736            -0.00013060             0.00002638            -0.00003080             0.00004631            -0.00004210       
   7175.4851000              0.00177276            -0.00045010             0.00009109            -0.00010460             0.00016849            -0.00019220       
   2478.7920000              0.00623864            -0.00157940             0.00031906            -0.00037490             0.00054725            -0.00044000       
    917.7325900              0.01976587            -0.00509070             0.00103163            -0.00118030             0.00193137            -0.00229800       
    351.7514000              0.06017463            -0.01575210             0.00318903            -0.00375480             0.00545737            -0.00428070       
    137.5155700              0.16016295            -0.04484030             0.00913931            -0.01046200             0.01729461            -0.02100840       
     54.4302860              0.33917581            -0.10853870             0.02227591            -0.02638960             0.03812473            -0.02842980       
     21.7225690              0.40883352            -0.18759800             0.03965557            -0.04506790             0.07914147            -0.10871400       
      8.7194484              0.15183413            -0.08683860             0.01868253            -0.02557030             0.01594961             0.06640619       
      3.5147166              0.00195927             0.33464216            -0.08001640             0.10765675            -0.13968240            -0.01738970       
      1.4212132              0.00418518             0.59813818            -0.18827570             0.21164824            -0.53435960             1.1451315        
      0.5760765             -0.00187660             0.23180428            -0.21162620             0.43129749            -0.28133200            -1.7763260        
      0.2339525              0.00120338            -0.00693860             0.14066560            -0.96823710             3.0868468             -0.12364070       
      0.0951560             -0.00067450             0.00680179             0.68477064            -0.97343960            -3.5376010              3.0022439        
      0.0387510              0.00031460            -0.00280300             0.34545022             1.4680586              1.0258502             -4.2293330        
      0.0155004             -0.00008880             0.00083003             0.00874972             0.09800990             0.56587909             2.4153747        
Mg    P
    557.1307800              0.00079833            -0.00016120             0.00013230            -0.00021600             0.00031544       
    135.4838800              0.00589231            -0.00119310             0.00094881            -0.00048420             0.00072367       
     47.2129580              0.02583591            -0.00524640             0.00431193            -0.00750940             0.01089367       
     18.0009550              0.09406296            -0.01931180             0.01513244            -0.00373040             0.00243732       
      7.1146607              0.24134480            -0.05049450             0.04187188            -0.07988840             0.12540044       
      2.8630240              0.38746464            -0.08296280             0.06595574             0.01126479             0.01067632       
      1.1640185              0.35595067            -0.08827490             0.09294055            -0.56057880             1.0932302        
      0.4763047              0.12288168            -0.03970790             0.05017503             0.66659154            -3.2229220        
      0.1957356              0.00380787             0.42165449            -0.75622220             1.2375291              3.6486214        
      0.0806783              0.00230283             0.58978450            -0.18127870            -2.3674500             -2.3911980        
      0.0333266             -0.00085890             0.10380275             1.0389702              1.2973603              0.71760597       
      0.0133306              0.00027579             0.00502440             0.09524704             0.07151495             0.17597721       
Mg    D
      1.0445644              0.01605667            -0.04289690             0.20912538       
      0.4857473              0.02264646             0.18907793            -0.90436520       
      0.2258841              0.46449386             0.77129122            -0.29454590       
      0.1050415              0.47219231            -0.32119970             1.5734652        
      0.0420166              0.16336646            -0.76069020            -1.1682750        
Mg    F
      0.4995238              0.00588707            -0.30407460       
      0.2838668             -0.51196050            -1.1139930        
      0.1613144             -0.46978720             1.1067098        
      0.0645258             -0.11745110             0.30597008       
end
basis "Al_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
Al    S
 208459.4900000              0.00007078            -0.00001840             0.00000432            -0.00000430             0.00000648            -0.00000780       
  29971.5980000              0.00049759            -0.00012920             0.00003029            -0.00003050             0.00004502            -0.00004730       
   8764.4565000              0.00167444            -0.00043710             0.00010265            -0.00010220             0.00015532            -0.00021000       
   3060.7073000              0.00580246            -0.00151200             0.00035421            -0.00035890             0.00052217            -0.00047560       
   1147.4963000              0.01811648            -0.00479430             0.00112743            -0.00111920             0.00171468            -0.00243970       
    445.7559500              0.05440537            -0.01462910             0.00343446            -0.00348670             0.00506469            -0.00446160       
    176.7064200              0.14492054            -0.04143990             0.00980341            -0.00974050             0.01501684            -0.02177380       
     70.9436200              0.31321200            -0.10118870             0.02408671            -0.02459030             0.03577722            -0.03013250       
     28.7240000              0.41334250            -0.18447700             0.04527494            -0.04498180             0.07132737            -0.11759120       
     11.6989230              0.19059653            -0.12273700             0.03095121            -0.03404100             0.04282415             0.04163135       
      4.7853697              0.00707487             0.27348316            -0.07575180             0.08910950            -0.13355890            -0.03258050       
      1.9637518              0.00484032             0.61530733            -0.22480450             0.22809994            -0.44484980             1.2270504        
      0.8078594             -0.00233010             0.28146024            -0.25485420             0.38525013            -0.52149340            -1.4506900        
      0.3329906              0.00153518            -0.00503600             0.20149503            -0.80088860             2.9480591             -1.2018800        
      0.1374693             -0.00086880             0.00796206             0.68310534            -0.99962600            -2.5769960              4.2755051        
      0.0568238              0.00040223            -0.00353640             0.30782923             1.1980110             -0.19367300            -4.7783590        
      0.0227295             -0.00011120             0.00100247             0.02408008             0.36451428             1.1061036              2.3292396        
Al    P
    677.7645800              0.00079717            -0.00013730             0.00015515            -0.00016860             0.00036347       
    164.8344200              0.00589941            -0.00101230             0.00113147            -0.00108570             0.00162437       
     57.6834240              0.02586307            -0.00449520             0.00508163            -0.00558830             0.01256209       
     22.1086740              0.09471373            -0.01657140             0.01841598            -0.01713210             0.02439129       
      8.7877514              0.24484796            -0.04414490             0.05014804            -0.05622460             0.13515491       
      3.5570874              0.39837993            -0.07248030             0.08138367            -0.07224890             0.06998835       
      1.4548780              0.35294610            -0.07465500             0.09799899            -0.16960580             0.56219989       
      0.5989363              0.10280005             0.01880214            -0.01844020             0.10547020            -1.5475220        
      0.2476373              0.00234580             0.27739515            -0.62774810             1.0958721              0.33806270       
      0.1026995              0.00175805             0.44207475            -0.24598520            -0.80230420             1.6903272        
      0.0426853             -0.00053410             0.29055057             0.35129892            -0.92384590            -2.2150650        
      0.0170741              0.00019528             0.16625332             0.65543563             1.1608148              1.1012016        
Al    D
      1.2673144              0.01856849            -0.00676530             0.15132202       
      0.5095130              0.11745821             0.20578256            -0.90596570       
      0.2048453              0.50149748             0.54053298            -0.04591540       
      0.0823563              0.37968233            -0.08920980             1.2672360        
      0.0329425              0.20021391            -0.87110670            -0.98171750       
Al    F
      0.5623111              0.08418120            -0.20789430       
      0.2707661              0.45945383            -0.40496500       
      0.1303803              0.38017523            -0.17522960       
      0.0521521              0.29286740             0.97536728       
end
basis "Si_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
Si    S
 250095.9700000              0.00006815            -0.00001820             0.00000470            -0.00000490             0.00000688            -0.00000870       
  35803.2000000              0.00048017            -0.00012780             0.00003305            -0.00003480             0.00004735            -0.00005180       
  10522.4830000              0.00159626            -0.00042650             0.00011064            -0.00011490             0.00016522            -0.00023760       
   3701.7745000              0.00547507            -0.00146180             0.00037778            -0.00040070             0.00053088            -0.00049020       
   1399.3933000              0.01693706            -0.00458450             0.00119120            -0.00123290             0.00179852            -0.00273600       
    548.3889500              0.05041784            -0.01387010             0.00359228            -0.00382010             0.00503523            -0.00444650       
    219.3626900              0.13450267            -0.03917820             0.01024273            -0.01061380             0.01559960            -0.02415990       
     88.8822590              0.29476401            -0.09635060             0.02530364            -0.02708780             0.03568620            -0.03015270       
     36.3233770              0.41279726            -0.18176200             0.04932521            -0.05122020             0.07863781            -0.13753650       
     14.9334630              0.21885760            -0.14523390             0.04049616            -0.04663010             0.04948931             0.04506541       
      6.1663485              0.01352631             0.22989807            -0.06985640             0.09190140            -0.11137450            -0.07232060       
      2.5545565              0.00478761             0.62379847            -0.25411200             0.26901327            -0.55229290             1.4944138        
      1.0609507             -0.00235090             0.31543582            -0.28611330             0.46077703            -0.38840900            -2.0022500        
      0.4415024              0.00157700            -0.00276260             0.24639415            -1.0562010              2.9534782             -0.5249362        
      0.1840168             -0.00091180             0.00903722             0.68019181            -0.78471120            -2.8556020              3.7709274        
      0.0767962              0.00041644            -0.00390620             0.28966706             1.2042630              0.09215286            -4.5574770        
      0.0307185             -0.00011400             0.00111144             0.02414823             0.29679859             1.0348260              2.2867174        
Si    P
    843.5338200              0.00074369            -0.00015740             0.00016602            -0.00019250             0.00040030       
    204.9072600              0.00552015            -0.00116560             0.00119789            -0.00115190             0.00205111       
     72.2487870              0.02411287            -0.00515290             0.00545750            -0.00647660             0.01387012       
     27.9613650              0.08883573            -0.01917230             0.01962832            -0.01827540             0.03298719       
     11.2322820              0.23494251            -0.05231320             0.05586579            -0.06800600             0.15230781       
      4.5969373              0.39732250            -0.09000870             0.09197956            -0.07758320             0.11866287       
      1.9014833              0.36181185            -0.09250120             0.11503921            -0.21432990             0.47363973       
      0.7917828              0.10524773             0.03870909            -0.06483660             0.25572048            -1.6830250        
      0.3311662              0.00256555             0.34152769            -0.68318220             1.0777334              0.83716261       
      0.1389423              0.00177329             0.46110561            -0.16360950            -1.2446840              1.1989226        
      0.0584257             -0.00045410             0.25855921             0.61750164            -0.38355030            -2.0733870        
      0.0233703              0.00017881             0.07566560             0.44097775             1.0225198              1.1887014        
Si    D
      2.0105333              0.02221051            -0.00195270             0.13166768       
      0.7910981              0.10356980             0.15356092            -0.66150530       
      0.3112787              0.50813164             0.48959332            -0.45910920       
      0.1224809              0.35117535             0.11387560             1.5443036        
      0.0489924              0.25071127            -0.98489900            -0.99944500       
Si    F
      0.7184925              0.11009981            -0.17967440       
      0.3474446              0.46295659            -0.23375030       
      0.1680153              0.32345259            -0.47263890       
      0.0672061              0.34355047             1.1086961        
end
basis "P_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
P    S
 296647.5500000              0.00006562            -0.00001780             0.00000495            -0.00000380             0.00000594            -0.00000860       
  42380.0300000              0.00046254            -0.00012560             0.00003483            -0.00002680             0.00004144            -0.00005490       
  12503.8560000              0.00152412            -0.00041530             0.00011560            -0.00008660             0.00013959            -0.00021710       
   4422.4937000              0.00518926            -0.00141400             0.00039175            -0.00030500             0.00046280            -0.00056060       
   1681.8478000              0.01595159            -0.00440030             0.00122727            -0.00091310             0.00148861            -0.00240580       
    663.2149000              0.04720087            -0.01323730             0.00367506            -0.00287280             0.00434089            -0.00514180       
    267.0058500              0.12619981            -0.03733840             0.01047976            -0.00779880             0.01277688            -0.02090760       
    108.8959200              0.27982529            -0.09244400             0.02602575            -0.02049300             0.03096216            -0.03617190       
     44.7973140              0.41030382            -0.17908160             0.05218594            -0.03865600             0.06543104            -0.11613130       
     18.5403120              0.24188220            -0.16174870             0.04842224            -0.04197400             0.05707014            -0.02312510       
      7.7070995              0.02071709             0.19399810            -0.06270700             0.06559604            -0.09386140             0.01864200       
      3.2143750              0.00443622             0.62785121            -0.27648210             0.19549449            -0.41005510             1.1215665        
      1.3440127             -0.00216870             0.34320722            -0.31132840             0.38636227            -0.48607910            -0.63232570       
      0.5630870              0.00148760            -0.00010200             0.27584791            -0.75348860             1.95041420            -2.9275670        
      0.2362870             -0.00087720             0.00993085             0.67745539            -0.54814350            -0.29309150             5.8115095        
      0.0992811              0.00039698            -0.00418080             0.28560830             0.26985002            -2.30754900            -5.0211630        
      0.0397124             -0.00010790             0.00119275             0.01675006             0.97010724             1.77847660             1.9270723        
P    P
   1018.4122000              0.00071159            -0.00016880             0.00015264            -0.00022110             0.00040331       
    247.3982000              0.00528387            -0.00125010             0.00110387            -0.00137890             0.00219003       
     87.7904820              0.02297828            -0.00550960             0.00500340            -0.00741670             0.01392847       
     34.2486000              0.08494327            -0.02057220             0.01814153            -0.02236340             0.03590870       
     13.8770140              0.22803285            -0.05717830             0.05241729            -0.07944690             0.15612489       
      5.7303098              0.39658377            -0.10153640             0.08911554            -0.10183150             0.14452546       
      2.3920068              0.36766734            -0.10487000             0.10677427            -0.22045860             0.41344622       
      1.0052767              0.10640781             0.05753445            -0.07211440             0.35066535            -1.6508330        
      0.4243929              0.00281028             0.37524649            -0.60909640             0.97783112             0.86123612       
      0.1797306              0.00165268             0.45668244            -0.16157330            -1.1218990              1.2175016        
      0.0762910             -0.00040110             0.22572156             0.54191860            -0.50591410            -2.1157790        
      0.0305164              0.00016315             0.06188888             0.53980064             1.0263412              1.1923436        
P    D
      2.7201853              0.02567866            -0.01281640             0.14954306       
      1.0722222              0.12037513             0.17873934            -0.66586430       
      0.4226405              0.55955359             0.50423470            -0.40061210       
      0.1665933              0.37100935            -0.11770020             1.5341916        
      0.0666373              0.12126366            -0.88859820            -1.0950090        
P    F
      0.8944019              0.17144038            -0.37580420       
      0.4408723              0.50049572            -0.39497070       
      0.2173166              0.37145759             0.26674267       
      0.0869266              0.13902900             0.76247795       
end
basis "S_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
S    S
 346348.2300000              0.00006370            -0.00001760             0.00000516            -0.00000380             0.00000585            -0.00000910       
  49391.1460000              0.00044935            -0.00012410             0.00003629            -0.00002730             0.00004096            -0.00005710       
  14610.9900000              0.00147142            -0.00040760             0.00011970            -0.00008760             0.00013668            -0.00023300       
   5187.2095000              0.00498429            -0.00138200             0.00040336            -0.00030730             0.00045296            -0.00056250       
   1980.9676000              0.01525241            -0.00427630             0.00125841            -0.00091510             0.00144216            -0.00257760       
    784.6313900              0.04494424            -0.01281620             0.00374805            -0.00286710             0.00420970            -0.00506850       
    317.3277900              0.12035338            -0.03610970             0.01069509            -0.00777990             0.01231522            -0.02231470       
    130.0197600              0.26908335            -0.08987260             0.02665475            -0.02053900             0.03016574            -0.03570240       
     53.7382080              0.40722490            -0.17728880             0.05454724            -0.03956760             0.06449660            -0.12800240       
     22.3458960              0.25831856            -0.17312010             0.05462756            -0.04600480             0.06268013            -0.02145890       
      9.3332512              0.02714669             0.16887115            -0.05692420             0.06098330            -0.08761680            -0.01890560       
      3.9111868              0.00400872             0.63115534            -0.29658550             0.20575809            -0.39434690             1.29060600       
      1.6432066             -0.00192710             0.36103178            -0.32932730             0.40570893            -0.55180690            -0.88556930       
      0.6917456              0.00134644             0.00184135             0.30470795            -0.81899290             1.99993610            -2.71487600       
      0.2916736             -0.00081150             0.01069710             0.67383630            -0.44471340            -0.27829840             5.68938710       
      0.1231441              0.00036382            -0.00432300             0.27748421             0.18735812            -2.35282500            -4.92890200       
      0.0492576             -0.00009870             0.00124248             0.01304772             1.00722580             1.79232710             1.86654110       
S    P
   1129.1269000              0.00077145            -0.00019700             0.00018333            -0.00028000             0.00043230       
    274.0351500              0.00572945            -0.00146240             0.00130515            -0.00172590             0.00288638       
     97.4025840              0.02477182            -0.00640040             0.00600239            -0.00940080             0.01459323       
     38.0855180              0.09109122            -0.02387630             0.02129088            -0.02797840             0.04821802       
     15.4710330              0.24064577            -0.06532010             0.06221627            -0.10067960             0.16282315       
      6.4056590              0.40976882            -0.11476930             0.09978781            -0.11767160             0.20594756       
      2.6812828              0.35226804            -0.10657020             0.11944864            -0.25665430             0.24014052       
      1.1300050              0.08382797             0.11048130            -0.15959890             0.68243796            -1.82669700       
      0.4783995              0.00271787             0.41795827            -0.67011450             0.66515564             1.80214550       
      0.2031805              0.00078655             0.42517813             0.01331064            -1.44513800             0.02939534       
      0.0864923              0.00011535             0.19228231             0.64871747             0.12745221            -1.46966500       
      0.0345969              0.00003404             0.04207771             0.37095119             0.77294449             1.12615110       
S    D
      3.0053679              0.03293922            -0.03191870             0.15012046       
      1.2172976              0.16386221             0.29392107            -0.82383320       
      0.4930556              0.58677406             0.46210890            -0.04964110       
      0.1997078              0.31916052            -0.32360540             1.32176930       
      0.0798831              0.08508563            -0.75561170            -1.11803800       
S    F
      1.1000988              0.20845644            -0.59442000       
      0.5272133              0.55071337            -0.33649890       
      0.2526627              0.33354097             0.71034940       
      0.1010651              0.06724721             0.35946202       
end
basis "Cl_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
Cl    S
 399432.4700000              0.00006215            -0.00001740             0.00000531            -0.00000470             0.00000595            -0.00000920       
  56908.8330000              0.00043838            -0.00012290             0.00003739            -0.00003370             0.00004122            -0.00005590       
  16874.7690000              0.00142781            -0.00040130             0.00012271            -0.00010830             0.00013955            -0.00024330       
   6010.0278000              0.00481620            -0.00135560             0.00041159            -0.00037410             0.00044686            -0.00051850       
   2303.2830000              0.01468157            -0.00417440             0.00127960            -0.00112330             0.00146844            -0.00270980       
    915.6599400              0.04311398            -0.01247260             0.00379416            -0.00346090             0.00411004            -0.00455620       
    371.7200900              0.11558388            -0.03510470             0.01083171            -0.00951860             0.01251189            -0.02342010       
    152.8910900              0.26016348            -0.08775020             0.02707379            -0.02486630             0.02954625            -0.03194480       
     63.4363030              0.40382380            -0.17564250             0.05631797            -0.04964540             0.06763368            -0.13915220       
     26.4817230              0.27179877            -0.18206990             0.05980454            -0.05901320             0.06396442            -0.00532620       
     11.1041120              0.03338125             0.14753370            -0.05113350             0.06729192            -0.07622940            -0.08114670       
      4.6716289              0.00356211             0.63295111            -0.31267210             0.26850578            -0.44555880             1.49579950       
      1.9704520             -0.00165600             0.37614178            -0.34374380             0.51536265            -0.53191500            -1.37186000       
      0.8327946              0.00117962             0.00380802             0.32577967            -1.11610500             2.38922930            -2.02018700       
      0.3525409             -0.00073110             0.01133746             0.66892575            -0.52914520            -1.29926400             5.24741420       
      0.1494341              0.00032425            -0.00444450             0.27170146             0.76655700            -1.50478700            -4.98513400       
      0.0597736             -0.00008790             0.00129047             0.01386816             0.59696595             1.65737770             2.06108180       
Cl    P
   1288.9716000              0.00078181            -0.00021070             0.00020575            -0.00031720             0.00045514       
    312.2443000              0.00581729            -0.00157040             0.00146090            -0.00194620             0.00362539       
    111.3463400              0.02503057            -0.00683040             0.00673436            -0.01067180             0.01501985       
     43.7360870              0.09188004            -0.02552010             0.02376316            -0.03157490             0.06149816       
     17.8565240              0.24258072            -0.06974890             0.07010553            -0.11574860             0.16963861       
      7.4327659              0.41394424            -0.12387560             0.11161894            -0.12908650             0.28532032       
      3.1282538              0.34789086            -0.10851620             0.12978530            -0.27649330             0.03758123       
      1.3257214              0.07717314             0.13894281            -0.23354130             0.89183689            -1.85478400       
      0.5644191              0.00312835             0.42954359            -0.67189630             0.41342424             2.43376840       
      0.2410741              0.00050049             0.40829131             0.10952051            -1.53837700            -0.94026680       
      0.1032089              0.00034786             0.18156256             0.66424757             0.46781029            -0.77329620       
      0.0412836             -0.00002380             0.03396053             0.30179468             0.59904463             0.92109142       
Cl    D
      3.6204561              0.03682298            -0.04843800             0.16746529       
      1.4775717              0.17638808             0.39297464            -0.94489600       
      0.6030230              0.59139283             0.47951806             0.27892621       
      0.2461043              0.30996037            -0.56212450             1.04819660       
      0.0984417              0.06672018            -0.56257760            -1.12710900       
Cl    F
      1.3568964              0.22438063            -0.68736230       
      0.6613646              0.56956395            -0.26104400       
      0.3223556              0.30148671             0.82343588       
      0.1289422              0.04940109             0.21671325       
end
basis "Ar_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (17s,12p,5d,4f) -> [6s,5p,3d,2f]
Ar    S
 455476.7700000              0.00006096            -0.00001730             0.00000544            -0.00000530             0.00000579            -0.00001010       
  64817.7430000              0.00043020            -0.00012220             0.00003829            -0.00003750             0.00003978            -0.00005880       
  19256.9870000              0.00139466            -0.00039690             0.00012513            -0.00012020             0.00013641            -0.00027260       
   6877.0073000              0.00468779            -0.00133670             0.00041795            -0.00041340             0.00042380            -0.00051080       
   2643.4877000              0.01424066            -0.00409860             0.00129572            -0.00123820             0.00143205            -0.00305700       
   1054.2375000              0.04169365            -0.01221340             0.00382578            -0.00379760             0.00386068            -0.00436370       
    429.3712200              0.11183053            -0.03433220             0.01092652            -0.01045540             0.01216691            -0.02637120       
    177.1885900              0.25298878            -0.08610070             0.02735689            -0.02735260             0.02778303            -0.03036920       
     73.7639450              0.40044790            -0.17427680             0.05765806            -0.05546770             0.06724781            -0.16095030       
     30.8970070              0.28245090            -0.18902660             0.06394978            -0.06865230             0.06200867             0.01248080       
     12.9994820              0.03906305             0.13009718            -0.04572820             0.07055596            -0.06041520            -0.15431860       
      5.4876793              0.00314565             0.63399171            -0.32577250             0.30115546            -0.46387010             1.83591150       
      2.3225716             -0.00139160             0.38815020            -0.35331040             0.61789886            -0.49311320            -2.05303400       
      0.9849807              0.00101034             0.00573222             0.33817566            -1.4337740              2.41394970            -1.20832800       
      0.4183973             -0.00064850             0.01193554             0.66223091            -0.27094710            -1.53597500             4.63521250       
      0.1779594              0.00028402            -0.00449410             0.27636906             0.77596409            -1.27729400            -4.69611700       
      0.0711838             -0.00007710             0.00131952             0.00949692             0.50334371             1.63788950             1.98829450       
Ar    P
   1462.4962000              0.00078756            -0.00022120             0.00029752            -0.00045430             0.00038932       
    354.0673100              0.00586048            -0.00165140             0.00201545            -0.00318150             0.00580901       
    126.6977900              0.02510137            -0.00713990             0.00979652            -0.01511580             0.01133247       
     49.9890950              0.09200774            -0.02671710             0.03265686            -0.05279920             0.10360929       
     20.5092950              0.24317197            -0.07307220             0.10366041            -0.17027200             0.13463887       
      8.5804641              0.41674542            -0.13132950             0.14799999            -0.23127500             0.54075660       
      3.6301049              0.34542045            -0.10964210             0.20744830            -0.20352810            -0.95625510       
      1.5465280              0.07305360             0.16048636            -0.50796850             1.7452925             -0.50691800       
      0.6619369              0.00294397             0.43595556            -0.80424020            -1.3963030              2.32780040       
      0.2842428             -0.00023940             0.40458441             0.69669502            -0.47271850            -2.63217100       
      0.1223463              0.00028995             0.17125106             0.46331690             0.89125570             1.09251950       
      0.0489385             -0.00009340             0.01351308             0.04908714             0.06889766             0.35266723       
Ar    D
      4.3288417              0.04003444            -0.05753400             0.16735357       
      1.7742302              0.18334334             0.42320227            -0.96674040       
      0.7271906              0.59072873             0.45075094             0.33376377       
      0.2980482              0.30437283            -0.56963190             1.0041472        
      0.1192193              0.06258812            -0.55102580            -1.1194440        
Ar    F
      1.6311740              0.23597497            -0.76592680       
      0.8203288              0.57618801            -0.17377420       
      0.4125491              0.27800823             0.84810472       
      0.1650196              0.04019225             0.16638315       
end
basis "Sc_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Sc    S
 2715278.0000000             0.0000090             -0.0000026              0.0000009             -0.0000002              0.0000003             -0.0000005              0.0000006             -0.0000001        
 406598.4000000              0.0000703             -0.0000206              0.0000073             -0.0000018              0.0000026             -0.0000038              0.0000051             -0.0000006        
  92530.0400000              0.0003694             -0.0001083              0.0000381             -0.0000094              0.0000134             -0.0000189              0.0000233             -0.0000032        
  26207.9200000              0.0015573             -0.0004572              0.0001611             -0.0000397              0.0000578             -0.0000858              0.0001174             -0.0000147        
   8549.4290000              0.0056382             -0.0016613              0.0005853             -0.0001442              0.0002037             -0.0002847              0.0003393             -0.0000471        
   3085.9750000              0.0180645             -0.0053748              0.0018971             -0.0004669              0.0006854             -0.0010311              0.0014477             -0.0001781        
   1203.1720000              0.0514455             -0.0156732              0.0055403             -0.0013666              0.0019141             -0.0026293              0.0029955             -0.0004298        
    498.4869000              0.1270708             -0.0408387              0.0145393             -0.0035806              0.0053127             -0.0081465              0.0118564             -0.0014226        
    216.7360000              0.2549055             -0.0918668              0.0330654             -0.0081804              0.0112847             -0.0150018              0.0155321             -0.0024011        
     97.8747600              0.3601745             -0.1648338              0.0611512             -0.0151200              0.0230985             -0.0371952              0.0587888             -0.0066727        
     45.2043300              0.2699414             -0.1809127              0.0702076             -0.0175994              0.0222344             -0.0235795              0.0052831             -0.0031433        
     20.2118700              0.0616375              0.0516540             -0.0211135              0.0055080              0.0001243             -0.0227982              0.0943456             -0.0060979        
      9.5747510             -0.0013701              0.5047500             -0.2706528              0.0700532             -0.1221890              0.2364863             -0.4657996              0.0462529        
      4.5403460              0.0020534              0.5045812             -0.4405492              0.1231272             -0.1477969              0.1308505              0.1041548              0.0173934        
      1.9956870             -0.0009541              0.0939370              0.0628539             -0.0280459             -0.0347018              0.2384111             -0.8841851              0.0482464        
      0.9422150              0.0004355             -0.0029708              0.7169126             -0.2441728              0.6462219             -1.7711660              4.0066269             -0.4068684        
      0.4178450             -0.0001870              0.0024825              0.4428795             -0.3251997              0.1555692              1.2977682             -4.9789490              0.4679794        
      0.0957610              0.0000967             -0.0008017              0.0233073              0.3583295             -2.2761670              3.2708298              7.8741989              0.6991548        
      0.0513510             -0.0000937              0.0007654             -0.0137221              0.6075220              1.1541231             -6.6504470             -9.8562820             -3.3040690        
      0.0238780              0.0000413             -0.0003371              0.0046301              0.2097175              0.7308993              4.2639247              5.3279198              4.8196833        
      0.0095510             -0.0000096              0.0000780             -0.0009669              0.0073593              0.1027599             -0.7124651             -1.3691380             -2.8589620        
Sc    P
   4609.8850000              0.0001918             -0.0000645              0.0000189             -0.0000241              0.0000314             -0.0000037              0.0000672        
   1092.1560000              0.0016801             -0.0005647              0.0001680             -0.0002160              0.0002819             -0.0000938              0.0003305        
    354.3368000              0.0092753             -0.0031416              0.0009226             -0.0011749              0.0015307             -0.0001810              0.0032736        
    134.8076000              0.0375290             -0.0128483              0.0038300             -0.0049286              0.0064337             -0.0021692              0.0073190        
     56.6025800              0.1149024             -0.0405378              0.0119347             -0.0152035              0.0198190             -0.0018707              0.0439947        
     25.3341000              0.2543925             -0.0928768              0.0279651             -0.0361671              0.0472648             -0.0184364              0.0413291        
     11.7403300              0.3799166             -0.1476504              0.0435437             -0.0555018              0.0728437              0.0051707              0.2160601        
      5.5692590              0.3095556             -0.1128068              0.0352851             -0.0466614              0.0644011             -0.0738196             -0.0475428        
      2.5949580              0.0871398              0.1576162             -0.0616862              0.0872214             -0.1191742              0.1428568              0.2380645        
      1.1963510              0.0025610              0.4713696             -0.1580190              0.2226945             -0.3825440             -0.0968099             -2.5585690        
      0.5350590              0.0012268              0.4300995             -0.2229972              0.3619737             -0.3938980              0.4540342              4.3170993        
      0.2207760             -0.0004759              0.1018083              0.1584348             -0.8883579              2.1980040             -1.4529900             -3.6818300        
      0.0883100              0.0002264             -0.0018422              0.7024475             -0.4095998             -2.3969200              2.6286388              2.2837762        
      0.0353240             -0.0001110              0.0029025              0.2812042              0.9190593              0.8963610             -3.1324930             -1.0737060        
      0.0141300              0.0000347             -0.0007827              0.0134820              0.2131487              0.3514869              1.9608482              0.2849510        
Sc    D
    110.2197000              0.0008259             -0.0007236              0.0008882             -0.0007975              0.0013188        
     32.8004100              0.0066811             -0.0058209              0.0072729             -0.0057483              0.0155258        
     12.3130000              0.0281594             -0.0247912              0.0305347             -0.0273494              0.0465941        
      5.0638190              0.0837259             -0.0737296              0.0926305             -0.0710894              0.2084908        
      2.2255470              0.1784011             -0.1578620              0.1989052             -0.1928455              0.2867545        
      0.9923430              0.2672948             -0.2208510              0.2656771             -0.1787391              0.5827251        
      0.4363610              0.3037322             -0.2096235              0.0901413             -0.0390972             -2.1646690        
      0.1857050              0.2950185              0.0538654             -0.6584846              1.3740417              2.1845099        
      0.0734410              0.1990362              0.4382646             -0.3970143             -1.9858830             -1.2561690        
      0.0293760              0.0988050              0.5100448              0.8953851              1.1614700              0.4427117        
Sc    F
      2.8415000              0.0345776             -0.0957320              0.1359995        
      1.1263000              0.0978527             -0.2169838              0.3321327        
      0.4464000              0.3495356             -0.5764450              0.4938045        
      0.1769000              0.5449483              0.1468281             -1.2477000        
      0.0701000              0.2305404              0.5750650              0.8152544        
      0.0278000              0.0309622              0.2099214              0.2046911        
Sc    G
      1.6071000             -0.0312478             -0.1712605        
      0.6317000             -0.1991247             -0.4022881        
      0.2483000             -0.4351061              0.0551703        
      0.0976000             -0.1645448              0.4427408        
end
basis "Ti_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Ti    S
 3014643.0000000             0.0000089             -0.0000026              0.0000009             -0.0000002              0.0000003             -0.0000007              0.0000007             -0.0000008        
 451432.9000000              0.0000693             -0.0000205              0.0000073             -0.0000018              0.0000026             -0.0000053              0.0000053             -0.0000053        
 102733.8000000              0.0003644             -0.0001077              0.0000385             -0.0000095              0.0000135             -0.0000263              0.0000292             -0.0000328        
  29098.1700000              0.0015364             -0.0004548              0.0001626             -0.0000401              0.0000587             -0.0001200              0.0001161             -0.0001114        
   9492.3300000              0.0055628             -0.0016529              0.0005909             -0.0001458              0.0002057             -0.0003962              0.0004557             -0.0005304        
   3426.3460000              0.0178286             -0.0053485              0.0019160             -0.0004727              0.0006977             -0.0014435              0.0013422             -0.0012205        
   1335.8960000              0.0508118             -0.0156089              0.0055992             -0.0013822              0.0019315             -0.0036579              0.0044136             -0.0053556        
    553.5026000              0.1257180             -0.0407222              0.0147171             -0.0036347              0.0054314             -0.0114497              0.0100605             -0.0083821        
    240.6925000              0.2529935             -0.0918764              0.0335677             -0.0083071              0.0114025             -0.0209347              0.0276626             -0.0360300        
    108.7293000              0.3595943             -0.1655028              0.0623753             -0.0154849              0.0239193             -0.0529136              0.0402696             -0.0248957        
     50.2645700              0.2724695             -0.1836009              0.0724054             -0.0181067              0.0224097             -0.0331418              0.0732413             -0.1229543        
     22.5800400              0.0635956              0.0477232             -0.0196954              0.0049579              0.0024417             -0.0357299             -0.0567999              0.1703617        
     10.7143200             -0.0012245              0.5057851             -0.2781485              0.0727455             -0.1299470              0.3473759             -0.1696599             -0.0254700        
      5.0935460              0.0020117              0.5066198             -0.4477923              0.1246226             -0.1441239              0.1962175             -0.7656318              1.4237522        
      2.2441830             -0.0009357              0.0946475              0.0757183             -0.0301251             -0.0426621              0.2160055              1.3773327             -3.6999680        
      1.0595700              0.0004205             -0.0028028              0.7218245             -0.2547207              0.6877107             -2.5428950              0.7186221              3.4250863        
      0.4688490             -0.0001776              0.0024413              0.4330537             -0.3112813              0.0897037              2.5344706             -2.5670770             -1.0095400        
      0.1061430              0.0000864             -0.0007298              0.0219039              0.3964178             -2.2007160              0.6548118              5.2087230             -2.3953330        
      0.0552620             -0.0000829              0.0006979             -0.0125651              0.5823944              1.1681766             -3.0783880             -5.9829570              5.6662256        
      0.0254650              0.0000376             -0.0003147              0.0045014              0.1989806              0.6824757              2.1852588              1.8991192             -5.7117110        
      0.0101860             -0.0000090              0.0000749             -0.0009663              0.0046510              0.0967020             -0.1213722              0.4757467              2.6957932        
Ti    P
   5181.1570000              0.0001872             -0.0000643              0.0000178             -0.0000246              0.0000372             -0.0000550              0.0000344        
   1227.4610000              0.0016414             -0.0005635              0.0001578             -0.0002160              0.0003035             -0.0004423              0.0007457        
    398.2712000              0.0090830             -0.0031425              0.0008699             -0.0012036              0.0018182             -0.0026841              0.0016752        
    151.5867000              0.0368951             -0.0129043              0.0036210             -0.0049522              0.0069432             -0.0100919              0.0173989        
     63.6963300              0.1135599             -0.0409507              0.0113629             -0.0157336              0.0239153             -0.0352776              0.0193675        
     28.5473300              0.2531790             -0.0946030              0.0267991             -0.0365861              0.0502972             -0.0726365              0.1481120        
     13.2612900              0.3801676             -0.1513956              0.0421416             -0.0594490              0.0959397             -0.1449412             -0.0041436        
      6.3103520              0.3102000             -0.1141409              0.0336818             -0.0467846              0.0578602             -0.1424794              0.6359246        
      2.9518750              0.0877741              0.1632057             -0.0589850              0.0794480             -0.0884661              0.3112594             -1.9129570        
      1.3653700              0.0029491              0.4732173             -0.1512272              0.2762838             -0.6566446              1.4389468              1.3110787        
      0.6114150              0.0013194              0.4245132             -0.2034795              0.2714219              0.1103128             -2.7808870              0.7177975        
      0.2525480             -0.0004215              0.1018377              0.1180617             -0.7924697              1.6148571              1.8524065             -2.2401480        
      0.1010190              0.0002198             -0.0016787              0.6938395             -0.4631748             -1.7484960             -0.0721023              2.9090753        
      0.0404080             -0.0001063              0.0028392              0.3145852              0.8432116              0.3163034             -1.1494250             -2.7064500        
      0.0161630              0.0000332             -0.0007664              0.0163869              0.2904509              0.6338804              0.9777475              1.4239416        
Ti    D
    134.3565000              0.0008295             -0.0006682              0.0010701             -0.0014503              0.0022858        
     40.0418900              0.0068672             -0.0054960              0.0090356             -0.0123965              0.0165219        
     15.1297600              0.0297829             -0.0241325              0.0392576             -0.0542237              0.0871351        
      6.2769900              0.0897360             -0.0729395              0.1244016             -0.1780062              0.2517754        
      2.7814100              0.1933983             -0.1579535              0.2501025             -0.3354542              0.5408700        
      1.2536020              0.2893468             -0.2164335              0.2800033             -0.1876683             -0.6428651        
      0.5574050              0.3179441             -0.1822406             -0.0889985              0.7838004             -0.8091268        
      0.2397590              0.2758861              0.1262455             -0.6260252              0.2236343              1.8533725        
      0.0952870              0.1593833              0.4480513             -0.2487541             -1.2876010             -1.6510520        
      0.0381150              0.0705435              0.4841333              0.8157396              0.9641309              0.7664389        
Ti    F
      4.2464000              0.0390840             -0.1220177              0.2385937        
      1.6831000              0.1338314             -0.3671189              0.5542357        
      0.6671000              0.3651079             -0.4991231             -0.1951449        
      0.2644000              0.4949678              0.2551840             -0.7351700        
      0.1048000              0.2514447              0.5221382              0.6567922        
      0.0415000              0.0383294              0.1120723              0.2690218        
Ti    G
      2.4017000              0.1052200             -0.3879583        
      0.9440000              0.3397169             -0.5519254        
      0.3710000              0.5641176              0.1803736        
      0.1458000              0.2853114              0.6041549        
end
basis "V_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
V    S
 3321857.0000000             0.0000088             -0.0000026              0.0000010             -0.0000002              0.0000004             -0.0000007              0.0000007             -0.0000010        
 497435.6000000              0.0000687             -0.0000204              0.0000074             -0.0000017              0.0000033             -0.0000054              0.0000052             -0.0000068        
 113202.7000000              0.0003610             -0.0001075              0.0000389             -0.0000092              0.0000166             -0.0000272              0.0000291             -0.0000415        
  32063.3300000              0.0015221             -0.0004539              0.0001642             -0.0000387              0.0000731             -0.0001222              0.0001132             -0.0001445        
  10459.6200000              0.0055116             -0.0016501              0.0005967             -0.0001408              0.0002521             -0.0004100              0.0004553             -0.0006669        
   3775.5060000              0.0176685             -0.0053400              0.0019353             -0.0004567              0.0008723             -0.0014655              0.0013015             -0.0016013        
   1472.0400000              0.0503829             -0.0155934              0.0056582             -0.0013356              0.0023584             -0.0038066              0.0044392             -0.0066923        
    609.9331000              0.1248088             -0.0407234              0.0148922             -0.0035183              0.0068381             -0.0115934              0.0096860             -0.0112466        
    265.2634000              0.2517261             -0.0920841              0.0340407             -0.0080547              0.0138569             -0.0220919              0.0282013             -0.0447482        
    119.8607000              0.3592265             -0.1663647              0.0634934             -0.0150827              0.0306954             -0.0533435              0.0380197             -0.0365416        
     55.4489100              0.2741645             -0.1858041              0.0742181             -0.0177395              0.0261509             -0.0382363              0.0785707             -0.1494322        
     24.9837200              0.0648633              0.0458546             -0.0190800              0.0045536              0.0087449             -0.0290722             -0.0683235              0.1911058        
     11.8805600             -0.0011662              0.5080706             -0.2857174              0.0716582             -0.1768010              0.3455982             -0.1473641              0.0690568        
      5.6603110              0.0019828              0.5069204             -0.4524590              0.1202978             -0.1591614              0.2579282             -0.8290211              1.6920091        
      2.4957030             -0.0009224              0.0943099              0.0900779             -0.0329731             -0.0836276              0.0217532              1.6312245             -4.9696740        
      1.1778660              0.0004099             -0.0027022              0.7250874             -0.2473306              1.0114782             -2.4028060              0.2319292              5.2939638        
      0.5200440             -0.0001702              0.0024007              0.4230042             -0.2854831             -0.2280242              2.7076750             -2.1521470             -2.3972030        
      0.1159650              0.0000789             -0.0006790              0.0204298              0.3533115             -2.2695010             -0.2510840              4.8952066             -0.6675687        
      0.0589380             -0.0000752              0.0006463             -0.0116477              0.5907965              1.6065987             -2.0254350             -5.9635710              3.3872267        
      0.0269460              0.0000349             -0.0002988              0.0043226              0.2222752              0.3016373              1.7930871              2.1703029             -4.3018660        
      0.0107780             -0.0000085              0.0000727             -0.0009541              0.0040419              0.1303343             -0.0337238              0.3787137              2.2468474        
V    P
   5777.3770000              0.0001836             -0.0000641              0.0000179             -0.0000293              0.0000376             -0.0000574              0.0000472        
   1368.6740000              0.0016111             -0.0005626              0.0001583             -0.0002555              0.0003106             -0.0004796              0.0007979        
    444.1233000              0.0089331             -0.0031441              0.0008760             -0.0014369              0.0018430             -0.0028100              0.0023232        
    169.0991000              0.0364077             -0.0129556              0.0036529             -0.0058937              0.0071563             -0.0110448              0.0187410        
     71.1019100              0.1125593             -0.0413180              0.0115437             -0.0189794              0.0244701             -0.0372458              0.0291005        
     31.9031100              0.2523889             -0.0961060              0.0273536             -0.0440556              0.0528094             -0.0816956              0.1583017        
     14.8510900              0.3804875             -0.1545839              0.0434320             -0.0731849              0.0989191             -0.1530986              0.0546206        
      7.0852270              0.3104782             -0.1148758              0.0338294             -0.0542949              0.0620169             -0.1586369              0.5486993        
      3.3244220              0.0880803              0.1682576             -0.0611490              0.1039268             -0.1279437              0.4488084             -2.0748220        
      1.5411640              0.0032000              0.4752220             -0.1559635              0.3508020             -0.6480029              1.2367060              1.8004150        
      0.6905200              0.0013680              0.4199565             -0.1942334              0.2145592              0.2664143             -2.6900400              0.1830578        
      0.2854240             -0.0003878              0.1007152              0.1212851             -0.9117910              1.3780078              1.9075451             -1.8887140        
      0.1141700              0.0002144             -0.0016510              0.6800287             -0.2994418             -1.6682250             -0.1590524              2.7107390        
      0.0456680             -0.0001028              0.0027748              0.3252677              0.7938386              0.3203251             -1.0926900             -2.5836200        
      0.0182670              0.0000321             -0.0007462              0.0164042              0.2405348              0.6871914              0.9569094              1.3604979        
V    D
    155.8527000              0.0008240             -0.0007370              0.0011148             -0.0016061              0.0023587        
     46.4977100              0.0069079             -0.0061568              0.0094982             -0.0138562              0.0183836        
     17.6299900              0.0304612             -0.0274669              0.0421737             -0.0622978              0.0940223        
      7.3546720              0.0923449             -0.0841448              0.1348554             -0.2093158              0.3078765        
      3.2740510              0.1985696             -0.1807083              0.2748253             -0.3859719              0.4964665        
      1.4824820              0.2942780             -0.2359404              0.2709970             -0.0411623             -0.9372764        
      0.6613510              0.3178236             -0.1545483             -0.1780122              0.9002036             -0.2635308        
      0.2848260              0.2736146              0.1934816             -0.6524956             -0.1729446              1.5113702        
      0.1128990              0.1545784              0.4609951             -0.0368649             -1.0012050             -1.6483540        
      0.0451600              0.0513788              0.4154791              0.7338086              0.9039410              0.8627922        
V    F
      5.9066000              0.0410317             -0.1107858              0.2409833        
      2.3412000              0.1605007             -0.3830492              0.5791615        
      0.9279000              0.3918668             -0.4698632             -0.2682171        
      0.3678000              0.4681741              0.2920987             -0.6823265        
      0.1458000              0.2329227              0.5179218              0.6413831        
      0.0578000              0.0387876              0.1150943              0.2628693        
V    G
      3.3406000              0.0933634             -0.3410268        
      1.3130000              0.3108378             -0.5179423        
      0.5161000              0.4744850              0.1916713        
      0.2028000              0.2390582              0.5527966        
end
basis "Cr_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Cr    S
 6177194.0000000             0.0000045             -0.0000014              0.0000005             -0.0000001              0.0000002             -0.0000004              0.0000006             -0.0000012        
 924929.5000000              0.0000352             -0.0000106              0.0000038             -0.0000009              0.0000016             -0.0000027              0.0000050             -0.0000057        
 210486.5000000              0.0001852             -0.0000555              0.0000201             -0.0000048              0.0000092             -0.0000147              0.0000220             -0.0000568        
  59620.0500000              0.0007817             -0.0002344              0.0000848             -0.0000200              0.0000357             -0.0000585              0.0001154             -0.0000907        
  19450.7600000              0.0028400             -0.0008546              0.0003098             -0.0000739              0.0001447             -0.0002294              0.0003176             -0.0010163        
   7022.0560000              0.0091912             -0.0027776              0.0010050             -0.0002366              0.0004123             -0.0006823              0.0014452             -0.0005727        
   2738.7630000              0.0268196             -0.0082331              0.0029926             -0.0007161              0.0014331             -0.0022555              0.0028196             -0.0115391        
   1135.8140000              0.0700666             -0.0221543              0.0080528             -0.0018906              0.0031937             -0.0053539              0.0124319              0.0008235        
    495.0923000              0.1580229             -0.0536442              0.0197404             -0.0047509              0.0098357             -0.0153230              0.0161504             -0.0944889        
    224.7487000              0.2846801             -0.1108446              0.0412384             -0.0096465              0.0152610             -0.0263623              0.0729922              0.0584811        
    105.3836000              0.3478419             -0.1798118              0.0698236             -0.0171280              0.0388736             -0.0591042              0.0328159             -0.5273241        
     50.1935900              0.2146960             -0.1532613              0.0619417             -0.0139696              0.0110289             -0.0275075              0.2042142              0.6649044        
     22.2495700              0.0363913              0.1570461             -0.0702821              0.0146851              0.0111926              0.0060714             -0.4066511             -1.9525110        
     10.9826500             -0.0023390              0.5579835             -0.3520653              0.0957589             -0.2755075              0.4188579             -0.0059639              7.6291413        
      5.3836650              0.0015758              0.4064273             -0.3830360              0.0929153             -0.0244757              0.1835805             -1.9348500            -11.9015400        
      2.3436850             -0.0007032              0.0548529              0.2666097             -0.0669435             -0.1402895             -0.3467947              6.1393726             10.9201510        
      1.1052020              0.0002840             -0.0018377              0.7072440             -0.3057681              1.3913639             -1.9822110             -6.5854110             -6.8143980        
      0.4878480             -0.0001028              0.0014536              0.3133199             -0.1700677             -0.9758837              2.8306916              2.8140449              2.2547552        
      0.0895990              0.0000244             -0.0000765              0.0078553              0.7452787             -1.4188350             -1.9394060             -0.0375438             -0.4055322        
      0.0334230             -0.0000169              0.0002354             -0.0036272              0.3968427              1.7184583              0.8905060             -1.1109460              0.0913183        
      0.0133690              0.0000060             -0.0000462              0.0010793              0.0052854             -0.1521812              0.3355072              1.0523679              0.0712628        
Cr    P
   6268.9210000              0.0001874             -0.0000656              0.0000211             -0.0000428              0.0000490             -0.0000511              0.0000653        
   1485.1180000              0.0016443             -0.0005756              0.0001861             -0.0003679              0.0004152             -0.0005176              0.0008809        
    481.9146000              0.0091208             -0.0032204              0.0010381             -0.0021020              0.0024043             -0.0025087              0.0032574        
    183.5142000              0.0371965             -0.0132776              0.0043020             -0.0085030              0.0096004             -0.0120257              0.0207472        
     77.1900500              0.1149261             -0.0423771              0.0137115             -0.0278731              0.0319684             -0.0329019              0.0425665        
     34.6517800              0.2569294             -0.0983383              0.0321288             -0.0633242              0.0714264             -0.0934099              0.1715203        
     16.1484600              0.3833594             -0.1569767              0.0514440             -0.1082859              0.1291633             -0.1241411              0.1445712        
      7.7109390              0.3047354             -0.1086111              0.0359673             -0.0706248              0.1006006             -0.2137930              0.3909267        
      3.6071540              0.0824344              0.1848507             -0.0764223              0.1767090             -0.3421204              0.8366523             -2.4203680        
      1.6673620              0.0027362              0.4759648             -0.1942220              0.5708496             -0.8354989              0.3460058              3.0695118        
      0.7390880              0.0014572              0.4067230             -0.1856082             -0.0357080              1.4164378             -2.1248310             -1.5957140        
      0.3013260             -0.0003291              0.1021274              0.2010582             -1.2560130             -0.0497432              2.4811644             -0.2690832        
      0.1205300              0.0002283             -0.0015565              0.6865246              0.4045846             -1.3359980             -1.4834690              1.5882811        
      0.0482120             -0.0001021              0.0027535              0.2606775              0.5870991              0.9781556             -0.1046105             -2.0707520        
      0.0192850              0.0000322             -0.0007733              0.0017175              0.0068897              0.2577832              0.8288056              1.2990116        
Cr    D
    150.8341000              0.00118076            -0.0007317              0.00147093            -0.0019819              0.00293042       
     44.9972300              0.00966118            -0.0059386              0.01221628            -0.0163386              0.02400180       
     16.9608800              0.04140729            -0.0258810              0.05281196            -0.0729836              0.11269289       
      7.0401540              0.12131664            -0.0761518              0.16199100            -0.2303703              0.37251217       
      3.1038780              0.24095388            -0.1505949              0.29357778            -0.3680624              0.35632893       
      1.3758960              0.32484954            -0.1687159              0.23847460             0.09367552            -0.9766277        
      0.5922820              0.32060330            -0.0719464             -0.23308910             0.77748431             0.00841508       
      0.2421380              0.23605297             0.1991270             -0.56415040            -0.1650367              1.2010561        
      0.0912840              0.09618844             0.30980514            -0.18723120            -0.9983717             -1.4641630        
      0.0365140              0.24331100             0.61183718             0.71568988             0.83634879             0.77260007       
Cr    F
      7.7139000              0.0390498             -0.0921689              0.2047374        
      3.0575000              0.1680515             -0.3609068              0.5745754        
      1.2119000              0.4050147             -0.4559056             -0.1714447        
      0.4803000              0.4507865              0.2474949             -0.6972531        
      0.1904000              0.2276147              0.5182729              0.4574673        
      0.0755000              0.0535853              0.1928989              0.4196485        
Cr    G
      4.3627000              0.0989929              0.2562285        
      1.7148000              0.3775771              0.4334279        
      0.6740000              0.5231325             -0.1214369        
      0.2649000              0.2998733             -0.4941415        
end
basis "Mn_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Mn    S
 3960805.0000000             0.0000087             -0.0000026              0.0000010             -0.0000002              0.0000004             -0.0000007              0.0000009             -0.0000010        
 593115.5000000              0.0000680             -0.0000205              0.0000075             -0.0000018              0.0000028             -0.0000058              0.0000063             -0.0000074        
 134976.8000000              0.0003574             -0.0001078              0.0000396             -0.0000094              0.0000142             -0.0000288              0.0000362             -0.0000425        
  38230.6700000              0.0015071             -0.0004553              0.0001675             -0.0000398              0.0000622             -0.0001299              0.0001344             -0.0001583        
  12471.5400000              0.0054576             -0.0016552              0.0006084             -0.0001445              0.0002166             -0.0004351              0.0005735             -0.0006729        
   4501.7430000              0.0174997             -0.0053576              0.0019744             -0.0004699              0.0007407             -0.0015590              0.0015221             -0.0017995        
   1755.2120000              0.0499351             -0.0156566              0.0057753             -0.0013712              0.0020337             -0.0040421              0.0056710             -0.0066425        
    727.3039000              0.1238807             -0.0409510              0.0152335             -0.0036322              0.0058033             -0.0123698              0.0110890             -0.0132033        
    316.3678000              0.2504969             -0.0928723              0.0349202             -0.0083049              0.0120735             -0.0235615              0.0370310             -0.0434664        
    143.0098000              0.3589592             -0.1684245              0.0654877             -0.0157294              0.0260455             -0.0574136              0.0408104             -0.0500572        
     66.2180500              0.2759017             -0.1891878              0.0770240             -0.0184252              0.0238516             -0.0411084              0.1135902             -0.1339672        
     29.9189600              0.0659604              0.0461651             -0.0195455              0.0043673              0.0048529             -0.0323033             -0.1239324              0.1360609        
     14.3031800             -0.0012372              0.5147184             -0.3005826              0.0769605             -0.1473013              0.3776811             -0.1093955              0.2718930        
      6.8394510              0.0019563              0.5041849             -0.4562535              0.1210388             -0.1459495              0.2609431             -1.2249610              1.4745861        
      3.0123740             -0.0009071              0.0918606              0.1202727             -0.0396616             -0.0354716             -0.0050120              2.7650131             -5.2458310        
      1.4188080              0.0003975             -0.0025870              0.7281293             -0.2631384              0.7785170             -2.4326520             -1.1481330              6.3171533        
      0.6236240             -0.0001593              0.0023080              0.4032453             -0.2629456             -0.0807084              2.7044847             -1.3280140             -3.5660270        
      0.1340980              0.0000683             -0.0005992              0.0177961              0.4329907             -2.0465300             -0.1886359              4.4658121              1.5693211        
      0.0655480             -0.0000647              0.0005684             -0.0101819              0.5464339              1.2305396             -1.9844750             -6.1545830              0.0507678        
      0.0295840              0.0000313             -0.0002737              0.0040037              0.1906748              0.5446708              1.8106923              3.0596419             -2.1748540        
      0.0118340             -0.0000079              0.0000689             -0.0009240             -0.0002215              0.0886842             -0.1521510             -0.1784082              1.7203416        
Mn    P
   7048.2710000              0.0001784             -0.0000639              0.0000176             -0.0000352              0.0000383             -0.0000547              0.0000540        
   1669.6780000              0.0015668             -0.0005610              0.0001560             -0.0003059              0.0003235             -0.0005149              0.0008003        
    541.8571000              0.0087154             -0.0031465              0.0008697             -0.0017361              0.0018862             -0.0026997              0.0026830        
    206.4295000              0.0357161             -0.0130398              0.0036328             -0.0071221              0.0075297             -0.0120236              0.0189338        
     86.8933400              0.1112153             -0.0419216              0.0116242             -0.0232595              0.0253564             -0.0360764              0.0348568        
     39.0630900              0.2516051             -0.0985734              0.0277021             -0.0541806              0.0569488             -0.0933107              0.1597768        
     18.2472500              0.3812308             -0.1596252              0.0447071             -0.0919950              0.1035302             -0.1416660              0.1021350        
      8.7412890              0.3102902             -0.1150729              0.0330480             -0.0671771              0.0787265             -0.2086819              0.5043990        
      4.1193320              0.0881207              0.1770515             -0.0626066              0.1377723             -0.1922694              0.6710510             -2.2679050        
      1.9148040              0.0035990              0.4773779             -0.1610873              0.4688822             -0.6913723              0.8461802              2.3112011        
      0.8578930              0.0014521              0.4126450             -0.1769052              0.1020817              0.6148777             -2.4352280             -0.3941252        
      0.3549500             -0.0003342              0.0994866              0.1209127             -1.0459610              0.9207736              1.9381038             -1.4844400        
      0.1419800              0.0002060             -0.0015978              0.6442919             -0.0694511             -1.5153770             -0.2709080              2.4865239        
      0.0567920             -0.0000973              0.0026783              0.3582730              0.6881997              0.3682492             -1.0654360             -2.4481300        
      0.0227170              0.0000303             -0.0007155              0.0197249              0.1821433              0.7016079              0.9985921              1.2827484        
Mn    D
    199.8357000              0.0008689             -0.0006141              0.0012453             -0.0014435              0.0022258        
     59.7217600              0.0074055             -0.0051723              0.0108402             -0.0124306              0.0189888        
     22.7477200              0.0334354             -0.0237547              0.0491838             -0.0580733              0.0923256        
      9.5650030              0.1022231             -0.0726328              0.1600817             -0.1953527              0.3320502        
      4.2854990              0.2176382             -0.1584041              0.3201419             -0.3745566              0.5002171        
      1.9509750              0.3138865             -0.2022489              0.2665074              0.0487524             -1.0197630        
      0.8727960              0.3226514             -0.1223759             -0.2815251              0.7802224             -0.1646050        
      0.3756210              0.2489774              0.1954530             -0.5757098             -0.1124107              1.4349364        
      0.1480090              0.1155548              0.3978832             -0.0703426             -1.1042480             -1.5662240        
      0.0592040              0.0397805              0.5143697              0.6737332              0.9709894              0.7879875        
Mn    F
      9.5413000              0.0349852             -0.0802442              0.1657279        
      3.7818000              0.1597661             -0.3483093              0.5743776        
      1.4990000              0.3964869             -0.4783902             -0.1019929        
      0.5941000              0.4551561              0.2256018             -0.7524029        
      0.2355000              0.2397760              0.5299708              0.4528616        
      0.0933000              0.0566387              0.1921441              0.4355518        
Mn    G
      5.3963000              0.0817002             -0.3031187        
      2.1210000              0.3454071             -0.6066715        
      0.8337000              0.5293068              0.1118580        
      0.3277000              0.3401254              0.6521647        
end
basis "Fe_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Fe    S
 4316265.0000000             0.0000087             -0.0000026              0.0000009             -0.0000002              0.0000004             -0.0000007              0.0000008             -0.0000010        
 646342.4000000              0.0000676             -0.0000202              0.0000066             -0.0000018              0.0000027             -0.0000057              0.0000059             -0.0000070        
 147089.7000000              0.0003551             -0.0001065              0.0000347             -0.0000094              0.0000140             -0.0000287              0.0000339             -0.0000407        
  41661.5200000              0.0014976             -0.0004495              0.0001467             -0.0000397              0.0000611             -0.0001281              0.0001263             -0.0001507        
  13590.7700000              0.0054237             -0.0016347              0.0005329             -0.0001438              0.0002133             -0.0004333              0.0005368             -0.0006437        
   4905.7500000              0.0173950             -0.0052934              0.0017304             -0.0004680              0.0007277             -0.0015352              0.0014320             -0.0017117        
   1912.7460000              0.0496629             -0.0154862              0.0050648             -0.0013658              0.0020047             -0.0040396              0.0053052             -0.0063667        
    792.6043000              0.1233557             -0.0405985              0.0133892             -0.0036226              0.0057061             -0.0121633              0.0104625             -0.0125269        
    344.8065000              0.2500229             -0.0925040              0.0308025             -0.0082964              0.0119517             -0.0237436              0.0346655             -0.0417984        
    155.8999000              0.3599037             -0.1690500              0.0582183             -0.0157706              0.0256976             -0.0563141              0.0388131             -0.0470446        
     72.2309100              0.2789928             -0.1922840              0.0693866             -0.0185872              0.0240385             -0.0434858              0.1064066             -0.1300846        
     32.7250600              0.0668486              0.0453208             -0.0166827              0.0041036              0.0046102             -0.0274669             -0.1142585              0.1353657        
     15.6676200             -0.0053045              0.5291912             -0.2807190              0.0775940             -0.1450720              0.3585423             -0.0805555              0.1662885        
      7.5034830             -0.0021942              0.5261370             -0.4350295              0.1205449             -0.1470185              0.2972373             -1.2213390              1.7057170        
      3.3122230             -0.0015672              0.0863404              0.1310265             -0.0409131             -0.0228404             -0.0556067              2.6254050             -5.3976890        
      1.5584710              0.0007006             -0.0366666              0.7287152             -0.2624671              0.7495812             -2.3578630             -0.9638793              6.1815820        
      0.6839140             -0.0000133             -0.0164420              0.3985276             -0.2576817             -0.0772963              2.6221971             -1.3981920             -3.2615050        
      0.1467570              0.0000758             -0.0013802              0.0173397              0.4333976             -1.9280090             -0.0969618              4.1494727              0.9003280        
      0.0705830             -0.0000682              0.0009867             -0.0096616              0.5466256              1.0656945             -1.9910490             -5.4097490              0.9972315        
      0.0314490              0.0000329             -0.0004385              0.0038520              0.1874711              0.6085632              1.7209050              2.3564495             -2.7522480        
      0.0125800             -0.0000084              0.0001090             -0.0009097              0.0027048              0.0919606             -0.1005195              0.1273023              1.8620910        
Fe    P
   7721.4890000              0.0001794             -0.0000553              0.0000183             -0.0000346              0.0000399             -0.0000545              0.0000625        
   1829.1260000              0.0015765             -0.0004858              0.0001614             -0.0003021              0.0003485             -0.0005660              0.0008057        
    593.6280000              0.0087821             -0.0027322              0.0009023             -0.0017071              0.0019716             -0.0026979              0.0030986        
    226.2054000              0.0360777             -0.0113692              0.0037727             -0.0070639              0.0081541             -0.0133077              0.0191580        
     95.2614500              0.1127293             -0.0368480              0.0121351             -0.0230082              0.0266173             -0.0360385              0.0413087        
     42.8592000              0.2560928             -0.0875078              0.0289886             -0.0542434              0.0626264             -0.1060966              0.1600455        
     20.0497100              0.3890943             -0.1433072              0.0470814             -0.0911168              0.1066534             -0.1308655              0.1456994        
      9.6208850              0.3151303             -0.0997609              0.0339563             -0.0677305              0.0933933             -0.2728610              0.4621261        
      4.5413710              0.0789275              0.1857857             -0.0672107              0.1481274             -0.2355891              0.8747656             -2.4652800        
      2.1135000             -0.0195952              0.4790901             -0.1728765              0.4603701             -0.6834363              0.5876422              2.8614131        
      0.9472010             -0.0183793              0.4081510             -0.1662075              0.0391571              0.6311456             -2.2942400             -1.0604460        
      0.3912430             -0.0050537              0.0975033              0.1458974             -0.9133288              0.8969611              1.9283610             -0.9677636        
      0.1564970              0.0002794             -0.0015518              0.6117855             -0.1569658             -1.3820600             -0.2812893              2.1615229        
      0.0625990             -0.0002231              0.0026314              0.3592589              0.6400545              0.1694495             -1.0387080             -2.2537740        
      0.0250400              0.0000638             -0.0007026              0.0407356              0.2835988              0.7656206              0.9387999              1.1863003        
Fe    D
    217.3688000              0.0009086             -0.0007237              0.0012589             -0.0016193              0.0020963        
     64.9997600              0.0077570             -0.0061290              0.0109211             -0.0139403              0.0198110        
     24.7731400              0.0350961             -0.0281316              0.0498014             -0.0654238              0.0876769        
     10.4361400              0.1069064             -0.0862305              0.1607749             -0.2210534              0.3534228        
      4.6796530              0.2235478             -0.1837914              0.3234614             -0.4183677              0.4656633        
      2.1256220              0.3148228             -0.2230041              0.2423199              0.1848733             -1.1841850        
      0.9452420              0.3170631             -0.0994840             -0.3448707              0.7868811              0.2228792        
      0.4026850              0.2453397              0.2425046             -0.5496404             -0.3431158              1.1216886        
      0.1566510              0.1198018              0.4217596              0.0368009             -0.8704182             -1.5111510        
      0.0626600              0.0424837              0.4358057              0.6510953              0.9015476              0.8488927        
Fe    F
     11.2749000              0.0325876             -0.0737873              0.1504848        
      4.4690000              0.1561285             -0.3571723              0.6175958        
      1.7713000              0.4009474             -0.4833309             -0.1524651        
      0.7021000              0.4532107              0.2397543             -0.7440038        
      0.2783000              0.2389983              0.5210098              0.5033181        
      0.1103000              0.0596616              0.1873248              0.3845365        
Fe    G
      6.3768000             -0.0718181             -0.2927576        
      2.5064000             -0.3567204             -0.6034929        
      0.9851000             -0.5171641              0.1617909        
      0.3872000             -0.2939848              0.6225390        
end
basis "Co_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Co    S
 4676708.0000000             0.0000086             -0.0000026              0.0000010             -0.0000002              0.0000004             -0.0000007              0.0000007             -0.0000010        
 700317.2000000              0.0000670             -0.0000204              0.0000076             -0.0000017              0.0000035             -0.0000055              0.0000050             -0.0000073        
 159373.0000000              0.0003524             -0.0001075              0.0000400             -0.0000089              0.0000177             -0.0000279              0.0000282             -0.0000422        
  45140.6700000              0.0014862             -0.0004538              0.0001692             -0.0000379              0.0000779             -0.0001222              0.0001073             -0.0001581        
  14725.7500000              0.0053825             -0.0016500              0.0006148             -0.0001373              0.0002689             -0.0004247              0.0004443             -0.0006660        
   5315.4480000              0.0172647             -0.0053419              0.0019959             -0.0004468              0.0009300             -0.0014568              0.0012261             -0.0018044        
   2072.4980000              0.0493040             -0.0156239              0.0058429             -0.0013053              0.0025209             -0.0039918              0.0043664             -0.0065650        
    858.8231000              0.1225355             -0.0409288              0.0154399             -0.0034624              0.0073269             -0.0114626              0.0090697             -0.0132991        
    373.6437000              0.2486038             -0.0931274              0.0355154             -0.0079487              0.0149812             -0.0238679              0.0282976             -0.0429058        
    168.9682000              0.3583791             -0.1696550              0.0669613             -0.0151248              0.0334211             -0.0522248              0.0349489             -0.0508896        
     78.3197100              0.2784106             -0.1924509              0.0796168             -0.0179403              0.0293121             -0.0483693              0.0840348             -0.1310410        
     35.5372400              0.0678588              0.0434714             -0.0187210              0.0039578              0.0099653             -0.0119317             -0.0820874              0.1301428        
     17.0473500             -0.0011575              0.5173704             -0.3104228              0.0747919             -0.1961004              0.3094635             -0.0853252              0.1408164        
      8.1755340              0.0019230              0.5046465             -0.4605415              0.1149008             -0.1762649              0.3905430             -0.9968384              1.9027016        
      3.6115780             -0.0008896              0.0920129              0.1358724             -0.0422338             -0.0386191             -0.2853214              2.0696525             -5.6643100        
      1.6974680              0.0003852             -0.0023455              0.7302026             -0.2468642              1.0841513             -2.0590340             -0.5272583              6.1328756        
      0.7436360             -0.0001514              0.0022423              0.3933001             -0.2419882             -0.4262671              2.5781278             -1.4183550             -2.8956170        
      0.1583250              0.0000613             -0.0005385              0.0167952              0.3722609             -1.9195620             -0.6181502              3.4922751             -0.0443428        
      0.0750090             -0.0000567              0.0005012             -0.0093016              0.5675956              1.3732252             -1.3076670             -4.0816200              2.3067771        
      0.0330930              0.0000278             -0.0002456              0.0037519              0.2173794              0.2776458              1.3226252              1.0653131             -3.4049790        
      0.0132370             -0.0000073              0.0000642             -0.0009060              0.0035247              0.1356901              0.1003355              0.7592251              1.8766262        
Co    P
   8421.8420000              0.0001749             -0.0000640              0.0000188             -0.0000383              0.0000399             -0.0000537              0.0000691        
   1995.0000000              0.0015377             -0.0005624              0.0001662             -0.0003362              0.0003581             -0.0005927              0.0007751        
    647.4855000              0.0085746             -0.0031626              0.0009316             -0.0018945              0.0019728             -0.0026636              0.0034388        
    246.7795000              0.0352897             -0.0131653              0.0038991             -0.0078932              0.0084177             -0.0140016              0.0184717        
    103.9689000              0.1104856             -0.0425877              0.0125983             -0.0256796              0.0267440             -0.0356191              0.0467461        
     46.8105200              0.2515627             -0.1009536              0.0301654             -0.0611228              0.0655127             -0.1134129              0.1513213        
     21.9270300              0.3820884             -0.1640955              0.0492289             -0.1020196              0.1057710             -0.1240218              0.1963007        
     10.5371500              0.3094567             -0.1146114              0.0347515             -0.0772885              0.1079408             -0.3189137              0.3861287        
      4.9806780              0.0875728              0.1858507             -0.0718809              0.1825778             -0.2925776              1.0561700             -2.5442090        
      2.3198240              0.0038266              0.4807124             -0.1828456              0.5178575             -0.6541275              0.3009816              3.2431707        
      1.0396090              0.0015123              0.4051311             -0.1534736             -0.0555423              0.7675423             -2.1218200             -1.6029170        
      0.4289210             -0.0002853              0.0965102              0.1559937             -0.9399717              0.6755047              1.9830532             -0.4972342        
      0.1715680              0.0002014             -0.0015578              0.5975206             -0.0557778             -1.3219740             -0.4347818              1.8487048        
      0.0686270             -0.0000928              0.0026127              0.3641942              0.6155397              0.2202244             -0.9317457             -2.0892250        
      0.0274510              0.0000289             -0.0006972              0.0401845              0.2359969              0.7602001              0.9173830              1.1324392        
Co    D
    237.5928000              0.0009270             -0.0008472              0.0012063             -0.0017141              0.0020516        
     71.0888100              0.0079387             -0.0072160              0.0104647             -0.0149083              0.0218297        
     27.1190300              0.0360641             -0.0332324              0.0480299             -0.0695053              0.0869779        
     11.4482600              0.1096816             -0.1023159              0.1545628             -0.2375036              0.3985729        
      5.1395420              0.2264578             -0.2139503              0.3106829             -0.4510802              0.4150750        
      2.3326940              0.3136776             -0.2429566              0.2090521              0.2600533             -1.3333530        
      1.0340300              0.3124355             -0.0662031             -0.3593479              0.8010824              0.5832683        
      0.4378990              0.2462833              0.2937819             -0.5128844             -0.4713708              0.7967890        
      0.1689630              0.1263317              0.4167302              0.0742974             -0.7172104             -1.3703940        
      0.0675850              0.0390034              0.3713092              0.6855019              0.8249891              0.8298717        
Co    F
     12.8403000              0.0323691             -0.0745389              0.1459166        
      5.0894000              0.1578875             -0.3766774              0.6332214        
      2.0172000              0.4107333             -0.4748131             -0.2037817        
      0.7996000              0.4517069              0.2764813             -0.7136340        
      0.3169000              0.2285547              0.5031531              0.5329550        
      0.1256000              0.0559753              0.1767600              0.3675116        
Co    G
      7.2621000             -0.0594147              0.3127987        
      2.8544000             -0.3498351              0.6295906        
      1.1219000             -0.5066564             -0.2105011        
      0.4410000             -0.2718922             -0.6000994        
end
basis "Ni_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Ni    S
 5048010.0000000             0.0000086             -0.0000026              0.0000010             -0.0000002              0.0000005             -0.0000007              0.0000009             -0.0000011        
 755918.1000000              0.0000668             -0.0000204              0.0000077             -0.0000017              0.0000036             -0.0000056              0.0000063             -0.0000090        
 172026.2000000              0.0003510             -0.0001076              0.0000403             -0.0000089              0.0000181             -0.0000290              0.0000364             -0.0000442        
  48724.5700000              0.0014802             -0.0004541              0.0001702             -0.0000375              0.0000796             -0.0001262              0.0001348             -0.0002033        
  15894.8900000              0.0053613             -0.0016512              0.0006185             -0.0001362              0.0002748             -0.0004421              0.0005770             -0.0006615        
   5737.4680000              0.0171985             -0.0053463              0.0020080             -0.0004432              0.0009496             -0.0015017              0.0015270             -0.0024644        
   2237.0510000              0.0491275             -0.0156411              0.0058797             -0.0012948              0.0025782             -0.0041660              0.0057149             -0.0061019        
    927.0302000              0.1221670             -0.0409988              0.0155488             -0.0034381              0.0074869             -0.0117984              0.0111504             -0.0198733        
    403.3461000              0.2481088             -0.0933929              0.0358090             -0.0079000              0.0153615             -0.0250661              0.0375778             -0.0355458        
    182.4282000              0.3582623             -0.1704003              0.0676485             -0.0150693              0.0342359             -0.0535867              0.0412961             -0.0966771        
     84.5891700              0.2791023             -0.1937400              0.0806548             -0.0179107              0.0303236             -0.0523617              0.1172759             -0.0583330        
     38.4229300              0.0683014              0.0435405             -0.0189262              0.0039219              0.0099202             -0.0078368             -0.1272878             -0.0934702        
     18.4687900             -0.0011835              0.5195027             -0.3154584              0.0750468             -0.2013734              0.3105100             -0.0582180              0.7591522        
      8.8681900              0.0019162              0.5037239             -0.4611078              0.1132425             -0.1830388              0.4404350             -1.4995820              1.3006597        
      3.9188700             -0.0008845              0.0913908              0.1448987             -0.0439357             -0.0217528             -0.3962250              3.4924071             -6.1242540        
      1.8398530              0.0003817             -0.0022736              0.7304487             -0.2443838              1.0974998             -2.0053650             -2.1907650              8.0238672        
      0.8046630             -0.0001483              0.0022082              0.3877855             -0.2348542             -0.4679771              2.6304708             -0.5455901             -5.0460320        
      0.1698460              0.0000585             -0.0005133              0.0162280              0.3686554             -1.8549820             -0.8055990              3.5960644              3.8279533        
      0.0793700             -0.0000537              0.0004748             -0.0089148              0.5724337              1.3222116             -1.1209270             -5.2375860             -3.8396240        
      0.0347000              0.0000266             -0.0002348              0.0036440              0.2159243              0.2973117              1.3686309              2.7668854              1.3803078        
      0.0138800             -0.0000071              0.0000624             -0.0008965              0.0002877              0.1157162             -0.0154283             -0.1683986              0.1371575        
Ni    P
   9148.7960000              0.0001736             -0.0000640              0.0000196             -0.0000429              0.0000447             -0.0000495              0.0000749        
   2167.1710000              0.0015266             -0.0005629              0.0001731             -0.0003784              0.0004210             -0.0005791              0.0007214        
    703.3857000              0.0085213             -0.0031692              0.0009722             -0.0021280              0.0022146             -0.0024593              0.0037275        
    268.1342000              0.0351341             -0.0132183              0.0040744             -0.0089146              0.0099401             -0.0137421              0.0172388        
    113.0078000              0.1102503             -0.0428710              0.0132102             -0.0289804              0.0300748             -0.0329468              0.0516092        
     50.9133900              0.2516806             -0.1019674              0.0317129             -0.0694999              0.0785153             -0.1129689              0.1378559        
     23.8774000              0.3825046             -0.1659257              0.0519237             -0.1156346              0.1165762             -0.1126527              0.2480738        
     11.4892400              0.3089367             -0.1141167              0.0360513             -0.0901824              0.1582313             -0.3393311              0.2639479        
      5.4368840              0.0872290              0.1896880             -0.0772532              0.2244235             -0.4693645              1.2317926             -2.4640590        
      2.5338370              0.0039206              0.4817172             -0.1941497              0.5942960             -0.6653167             -0.1771550              3.4121318        
      1.1353090              0.0015392              0.4020203             -0.1477233             -0.1622569              1.2479905             -1.7137840             -2.0114720        
      0.4678910             -0.0002655              0.0955193              0.1718753             -1.0340430              0.0608825              2.0981372             -0.0421967        
      0.1871560              0.0001994             -0.0015489              0.6042663              0.1500320             -1.2240160             -0.9419235              1.5201981        
      0.0748620             -0.0000909              0.0025883              0.3554410              0.6127340              0.5951147             -0.5823576             -1.9853170        
      0.0299450              0.0000284             -0.0006906              0.0212506              0.0948606              0.5080473              0.9511092              1.1789974        
Ni    D
    258.8667000              0.0009525             -0.0009261              0.0012366             -0.0017787              0.0020194        
     77.4960400              0.0081799             -0.0079244              0.0107482             -0.0157175              0.0233178        
     29.5897200              0.0373082             -0.0366267              0.0495894             -0.0727320              0.0872867        
     12.5152700              0.1132872             -0.1130537              0.1598774             -0.2541176              0.4366637        
      5.6244680              0.2314757             -0.2326325              0.3192322             -0.4630912              0.3374642        
      2.5513030              0.3161360             -0.2493503              0.1791901              0.3660276             -1.3921600        
      1.1280600              0.3108432             -0.0353269             -0.4130720              0.7561037              0.8432747        
      0.4753730              0.2421024              0.3269474             -0.4749400             -0.6047182              0.5259686        
      0.1821280              0.1229839              0.4196984              0.1711843             -0.5581049             -1.2586030        
      0.0728510              0.0351676              0.3181754              0.6397940              0.7818190              0.8375133        
Ni    F
     14.2156000              0.0344954             -0.0779649              0.1532766        
      5.6345000              0.1679319             -0.3935911              0.6445037        
      2.2333000              0.4235404             -0.4564942             -0.2641527        
      0.8852000              0.4432599              0.3114760             -0.6774664        
      0.3509000              0.2157909              0.4920107              0.5632829        
      0.1391000              0.0513622              0.1648255              0.3410204        
Ni    G
      8.0399000              0.0644167              0.2337494        
      3.1601000              0.3942264              0.4363882        
      1.2421000              0.5455206             -0.1801696        
      0.4882000              0.2687623             -0.4040997        
end
basis "Cu_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Cu    S
 9148883.0000000             0.0000045             -0.0000014              0.0000005             -0.0000001              0.0000002             -0.0000004              0.0000006             -0.0000004        
 1369956.0000000             0.0000347             -0.0000107              0.0000040             -0.0000008              0.0000017             -0.0000029              0.0000045             -0.0000023        
 311782.6000000              0.0001824             -0.0000561              0.0000210             -0.0000045              0.0000094             -0.0000154              0.0000231             -0.0000208        
  88318.8000000              0.0007700             -0.0002370              0.0000886             -0.0000187              0.0000365             -0.0000634              0.0001018             -0.0000403        
  28815.5300000              0.0027976             -0.0008638              0.0003236             -0.0000695              0.0001482             -0.0002388              0.0003513             -0.0003651        
  10403.4600000              0.0090560             -0.0028083              0.0010502             -0.0002203              0.0004226             -0.0007463              0.0012204             -0.0003145        
   4057.7910000              0.0264408             -0.0083298              0.0031294             -0.0006753              0.0014700             -0.0023287              0.0033544             -0.0040766        
   1682.9740000              0.0691804             -0.0224540              0.0084386             -0.0017612              0.0032832             -0.0059489              0.0099905             -0.0008187        
    733.7543000              0.1564799             -0.0545657              0.0207702             -0.0045222              0.0101489             -0.0156905              0.0219001             -0.0327459        
    333.2677000              0.2831880             -0.1133921              0.0436971             -0.0090430              0.0158848             -0.0304429              0.0540720              0.0131141        
    156.4338000              0.3483474             -0.1851260              0.0746019             -0.0167018              0.0406872             -0.0590770              0.0756341             -0.1783570        
     74.6972100              0.2172972             -0.1587381              0.0669604             -0.0128842              0.0119263             -0.0416723              0.1038940              0.2118313        
     33.3226200              0.0372395              0.1660091             -0.0794426              0.0133356              0.0102203              0.0368461             -0.1401680             -0.6562555        
     16.6223700             -0.0025807              0.5680884             -0.3848752              0.0979059             -0.2916877              0.3829534             -0.5126665              2.2531713        
      8.2082600              0.0015604              0.3950505             -0.3724662              0.0724974             -0.0233203              0.3638643             -1.3503980             -2.3652420        
      3.6094000             -0.0006799              0.0519344              0.3193858             -0.0605655             -0.0655306             -0.8379095              5.6933879             -0.0447763        
      1.6834490              0.0002619             -0.0010578              0.7043586             -0.2971844              1.3229446             -1.3327750             -6.4894760              2.0200703        
      0.7337570             -0.0000868              0.0012394              0.2799624             -0.1063761             -1.0559410              2.3585238              2.9509294             -1.7425540        
      0.1102070              0.0000177             -0.0001197              0.0057910              0.7953271             -1.2308780             -1.8284650             -0.3349516              1.8773472        
      0.0387860             -0.0000129              0.0000886             -0.0026652              0.3075825              1.6531394              1.2032456             -0.6736226             -3.2480540        
      0.0155140              0.0000049             -0.0000340              0.0009522              0.0148355             -0.2015516              0.0447791              0.8489410              2.2829914        
Cu    P
   9713.2530000              0.0001784             -0.0000658              0.0000226             -0.0000470              0.0000495             -0.0000495              0.0000852        
   2300.8890000              0.0015686             -0.0005782              0.0001982             -0.0004156              0.0004866             -0.0005750              0.0006669        
    746.7706000              0.0087543             -0.0032566              0.0011204             -0.0023277              0.0024554             -0.0024586              0.0042361        
    284.6806000              0.0360811             -0.0135780              0.0046657             -0.0097925              0.0115031             -0.0136626              0.0159196        
    119.9999000              0.1129915             -0.0439985              0.0152157             -0.0316589              0.0332154             -0.0329894              0.0594358        
     54.0738600              0.2566409             -0.1041809              0.0360811             -0.0759931              0.0910985             -0.1116608              0.1202889        
     25.3732100              0.3851875             -0.1676802              0.0592550             -0.1244749              0.1248290             -0.1175665              0.3208028        
     12.2096200              0.3028808             -0.1071443              0.0370993             -0.0955157              0.1963225             -0.3155263              0.0581344        
      5.7574210              0.0816448              0.2050046             -0.0933945              0.2789617             -0.6786917              1.3818450             -2.2496750        
      2.6734020              0.0033881              0.4829396             -0.2290024              0.6276759             -0.4986374             -0.7132927              3.4652132        
      1.1868350              0.0015770              0.3902233             -0.1232369             -0.3261519              1.4798113             -1.1090360             -2.3815320        
      0.4815930             -0.0002208              0.0943774              0.2311824             -1.0009900             -0.4634203              1.9212999              0.4528051        
      0.1926370              0.0002120             -0.0015448              0.6024109              0.3326714             -0.9305540             -1.2000030              1.1267670        
      0.0770550             -0.0000895              0.0026439              0.3065242              0.5440404              0.6921701             -0.3179660             -1.8121360        
      0.0308220              0.0000284             -0.0007274              0.0130776              0.0554239              0.3684572              0.9354899              1.1659415        
Cu    D
    249.3497000              0.0012640             -0.0015531              0.0018692             -0.0023354              0.0025041        
     74.6383700              0.0106389             -0.0131130              0.0161251             -0.0229071              0.0357945        
     28.3764100              0.0472095             -0.0589550              0.0724092             -0.0939470              0.1118229        
     11.9489300              0.1379366             -0.1778206              0.2362863             -0.3767594              0.6907369        
      5.3176460              0.2626675             -0.3271681              0.3829612             -0.3271353             -0.4708926        
      2.3644170              0.3324163             -0.2409974             -0.1679375              0.9500969             -0.9338754        
      1.0123860              0.3077990              0.1896065             -0.6824603             -0.0464879              1.6653446        
      0.4067730              0.2166410              0.5034045              0.0886993             -0.8856022             -1.1214400        
      0.1473310              0.0840772              0.3070359              0.6027864              0.5428285              0.0350511        
      0.0589320              0.0050438              0.0325397              0.1443810              0.3272240              0.5278036        
Cu    F
     15.4333000              0.0390182             -0.0843767              0.1616831        
      6.1172000              0.1875434             -0.4143733              0.6348261        
      2.4246000              0.4462125             -0.4172357             -0.3107576        
      0.9610000              0.4264741              0.3587680             -0.6318876        
      0.3809000              0.1915591              0.4777457              0.5673402        
      0.1510000              0.0416518              0.1542376              0.3500979        
Cu    G
      8.7286000              0.0694594             -0.3791541        
      3.4308000              0.4369875             -0.5966263        
      1.3485000              0.5414751              0.3613781        
      0.5300000              0.2174397              0.5126784        
end
basis "Zn_Roos_ANO_TZ" SPHERICAL
#BASIS SET: (21s,15p,10d,6f,4g) -> [8s,7p,5d,3f,2g]
Zn    S
 5820021.0000000             0.0000086             -0.0000026              0.0000010             -0.0000002              0.0000003             -0.0000007              0.0000009             -0.0000011        
 871523.4000000              0.0000665             -0.0000205              0.0000078             -0.0000017              0.0000027             -0.0000059              0.0000062             -0.0000087        
 198335.0000000              0.0003495             -0.0001080              0.0000408             -0.0000091              0.0000137             -0.0000301              0.0000355             -0.0000441        
  56176.3100000              0.0014738             -0.0004559              0.0001723             -0.0000386              0.0000598             -0.0001330              0.0001345             -0.0001963        
  18325.8200000              0.0053383             -0.0016578              0.0006259             -0.0001399              0.0002095             -0.0004566              0.0005591             -0.0006671        
   6614.9550000              0.0171271             -0.0053685              0.0020329             -0.0004559              0.0007112             -0.0015896              0.0015365             -0.0023574        
   2579.1990000              0.0489409             -0.0157124              0.0059546             -0.0013309              0.0019745             -0.0042814              0.0055053             -0.0062426        
   1068.8490000              0.1217934             -0.0412257              0.0157669             -0.0035427              0.0055909             -0.0125846              0.0113832             -0.0187991        
    465.1045000              0.2476589             -0.0940641              0.0363754             -0.0081430              0.0118924             -0.0255662              0.0359162             -0.0374100        
    210.4130000              0.3582432             -0.1719964              0.0689273             -0.0156132              0.0253915             -0.0582753              0.0441483             -0.0893121        
     97.6162900              0.2798170             -0.1958500              0.0823733             -0.0185358              0.0247517             -0.0503483              0.1081545             -0.0733922        
     44.3802000              0.0685758              0.0453244             -0.0200931              0.0041320              0.0031286             -0.0200286             -0.1056115             -0.0559832        
     21.4230800             -0.0013127              0.5244522             -0.3253008              0.0789884             -0.1455831              0.3614371             -0.1189922              0.6963994        
     10.3089100              0.0019163              0.5006010             -0.4602086              0.1141316             -0.1487271              0.3696434             -1.3055770              1.2777872        
      4.5536450             -0.0008791              0.0894769              0.1633908             -0.0486767              0.0323568             -0.2753528              3.0303774             -5.7953510        
      2.1328210              0.0003778             -0.0021743              0.7299936             -0.2515387              0.6651708             -2.0987060             -1.5662070              7.3501895        
      0.9296970             -0.0001433              0.0021375              0.3766747             -0.2337560             -0.0966651              2.4645301             -0.9562031             -4.3536210        
      0.1921470              0.0000541             -0.0004691              0.0150817              0.4380172             -1.6575130             -0.1095107              3.6013858              2.5356755        
      0.0875950             -0.0000491              0.0004303             -0.0082240              0.5521739              0.7510888             -1.7612880             -4.8829650             -1.7426520        
      0.0377020              0.0000247             -0.0002165              0.0034484              0.1698573              0.7349184              1.5307360              2.3698012             -0.3852316        
      0.0150810             -0.0000067              0.0000591             -0.0008762              0.0024973              0.0732319             -0.0774783             -0.0340590              0.8911217        
Zn    P
  10684.5800000              0.0001714             -0.0000641              0.0000168             -0.0000360              0.0000420             -0.0000534              0.0000728        
   2530.9030000              0.0015087             -0.0005638              0.0001482             -0.0003183              0.0003788             -0.0005555              0.0007303        
    821.4820000              0.0084368             -0.0031804              0.0008338             -0.0017874              0.0020876             -0.0026578              0.0036333        
    313.2522000              0.0348961             -0.0133103              0.0035065             -0.0075341              0.0089761             -0.0132177              0.0175155        
    132.1094000              0.1099359             -0.0433634              0.0114135             -0.0244969              0.0286258             -0.0362165              0.0504807        
     59.5875100              0.2520564             -0.1037319              0.0275640             -0.0593045              0.0708920             -0.1072132              0.1416367        
     28.0039900              0.3832784             -0.1690002              0.0451462             -0.0983075              0.1149481             -0.1368465              0.2380227        
     13.5042500              0.3078260             -0.1128672              0.0303909             -0.0757965              0.1174631             -0.2815020              0.2953867        
      6.4018810              0.0865115              0.1963898             -0.0664651              0.1881581             -0.3365914              1.0153917             -2.3891610        
      2.9857690              0.0040822              0.4829795             -0.1615315              0.4690391             -0.6406425              0.2591624              2.9777104        
      1.3369020              0.0015857              0.3967617             -0.1364279             -0.0399937              0.7452954             -1.9590820             -1.2389870        
      0.5499610             -0.0002323              0.0941104              0.1165787             -0.8182209              0.7015721              1.6931751             -0.8640304        
      0.2199840              0.0001958             -0.0015306              0.5468360             -0.2206737             -1.1502840             -0.0494415              2.1021802        
      0.0879940             -0.0000878              0.0025479              0.4149079              0.5382072             -0.0568782             -1.2351860             -2.1510650        
      0.0351980              0.0000274             -0.0006797              0.0795438              0.3628488              0.8428301              1.0061185              1.0853729        
Zn    D
    305.0115000              0.0010250             -0.0013860              0.0015239             -0.0017946              0.0017850        
     91.4000300              0.0088467             -0.0120163              0.0136362             -0.0175296              0.0261188        
     34.9582900              0.0406831             -0.0559640              0.0625750             -0.0760590              0.0832537        
     14.8369700              0.1232399             -0.1760541              0.2169856             -0.3077546              0.5297035        
      6.6807480              0.2479330             -0.3491389              0.4015913             -0.4047826             -0.0462489        
      3.0290260              0.3308668             -0.2730933             -0.1695897              0.8631571             -1.2273100        
      1.3348390              0.3173635              0.2110472             -0.7039918              0.1240994              1.4455574        
      0.5586080              0.2230148              0.5180431              0.1308419             -0.9362263             -0.4462594        
      0.2117430              0.0809221              0.2610813              0.5940125              0.3962795             -0.7216395        
      0.0846970              0.0035432              0.0202449              0.1801863              0.5183450              0.9250047        
Zn    F
     16.5744000              0.0455715             -0.0941222              0.1873342        
      6.5695000              0.2153603             -0.4366455              0.6545053        
      2.6039000              0.4696477             -0.3740533             -0.4433802        
      1.0321000              0.4040690              0.4286155             -0.5452492        
      0.4091000              0.1630365              0.4724145              0.6677663        
      0.1621000              0.0236161              0.0987123              0.2400460        
Zn    G
      9.3740000             -0.0925447              0.4204175        
      3.6844000             -0.4764832              0.5515246        
      1.4482000             -0.5052273             -0.4297044        
      0.5692000             -0.1957453             -0.4738866        
end