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#  m6-31G*  EMSL  Basis Set Exchange Library  3/15/13 10:18 AM
# Elements                             References
# --------                             ----------
# Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu : A.V. Mitin, J. Baker, P. Pulay, An improved 6-31G* basis set for first-row transition metals, J. Chem. Phys. 118, 7775 (2003).
# 



basis "Sc_m6-31G*" SPHERICAL
Sc    S
  39088.980000000            0.00180326       
   5869.792000000            0.01380769       
   1336.910000000            0.06800396       
    376.603100000            0.23470990       
    120.467900000            0.48156900       
     40.980320000            0.34456520       
Sc    SP
    786.285200000            0.00245186             0.00403953       
    186.887000000            0.03259579             0.03122570       
     60.009350000            0.12382420             0.13498330       
     22.258830000           -0.04359890             0.34247930       
      8.885149000           -0.61771810             0.46231130       
      3.609211000           -0.44328230             0.21775240       
Sc    SP
     29.843550000           -0.00258630            -0.00609665       
      9.542383000            0.07188424            -0.02628884       
      4.056790000            0.25032600             0.05091001       
      1.704703000           -0.29910030             0.37980970       
      0.706234000           -0.74468180             0.51708830       
      0.279536000           -0.17997760             0.18297720       
Sc    SP
      1.065609000            0.06482978            -0.29384400       
      0.425933000            0.32537560             0.09235323       
      0.076320000           -1.17080600             0.98479300       
Sc    SP
      0.029594000            1.00000000             1.00000000       
Sc    D
      9.2389253773           0.1013495998     
      2.3061823929           0.4074937059     
      0.6394887979           0.6965324203     
Sc    D
      0.1620099141           1.0000000        
Sc    F
      0.80000000             1.0000000        
end
basis "Ti_m6-31G*" SPHERICAL
Ti    S
  43152.950000000            0.00179187       
   6479.571000000            0.01372392       
   1475.675000000            0.06762830       
    415.699100000            0.23376420       
    133.000600000            0.48106960       
     45.272220000            0.34622800       
Ti    SP
    874.682600000            0.00243101             0.00401768       
    207.978500000            0.03233027             0.03113966       
     66.879180000            0.12425200             0.13490770       
     24.873470000           -0.03903905             0.34316720       
      9.968441000           -0.61717890             0.46257600       
      4.063826000           -0.44730970             0.21546030       
Ti    SP
     33.643630000           -0.00294036            -0.00631162       
     10.875650000            0.07163103            -0.02697638       
      4.628225000            0.25289150             0.05316847       
      1.950126000           -0.29664010             0.38455490       
      0.809452000           -0.74322150             0.51276620       
      0.320474000           -0.18535200             0.18111350       
Ti    SP
      1.224148000            0.06351465            -0.21120700       
      0.484263000            0.31514040             0.07771998       
      0.084096000           -1.16259500             0.98982140       
Ti    SP
      0.032036000            1.00000000             1.00000000       
Ti    D
     11.3802872735           0.1000655567     
      2.8785653801           0.4084975315     
      0.8146824263           0.6922977301     
Ti    D
      0.2106293041           1.0000000        
Ti    F
      0.80000000             1.0000000        
end
basis "V_m6-31G*" SPHERICAL
V    S
  47354.330000000            0.00178451       
   7110.787000000            0.01366754       
   1619.591000000            0.06736122       
    456.337900000            0.23305520       
    146.060600000            0.48063160       
     49.757910000            0.34748020       
V    SP
    968.148400000            0.00241060             0.00399500       
    230.282100000            0.03207243             0.03104061       
     74.145910000            0.12459420             0.13477470       
     27.641070000           -0.03482177             0.34372790       
     11.114750000           -0.61673740             0.46287590       
      4.543113000           -0.45098440             0.21355470       
V    SP
     37.640500000           -0.00323320            -0.00649406       
     12.282380000            0.07130744            -0.02753453       
      5.233366000            0.25438200             0.05516284       
      2.208950000           -0.29338870             0.38796720       
      0.917880000           -0.74156950             0.50902580       
      0.363412000           -0.19094100             0.18038400       
V    SP
      1.392781000            0.06139703            -0.18912650       
      0.543913000            0.30611300             0.08005453       
      0.091476000           -1.15489000             0.98773990       
V    SP
      0.034312000            1.00000000             1.00000000       
V    D
     13.3595274176           0.1006487662     
      3.4113944966           0.4115551152     
      0.9739061412           0.6875734800     
V    D
      0.2522224358           1.0000000        
V    F
      0.80000000             1.0000000        
end
basis "Cr_m6-31G*" SPHERICAL
Cr    S
  51789.810000000            0.00177618       
   7776.849000000            0.01360476       
   1771.385000000            0.06706925       
    499.158800000            0.23231040       
    159.798200000            0.48024100       
     54.470210000            0.34876530       
Cr    SP
   1064.328000000            0.00239967             0.00398700       
    253.213800000            0.03194886             0.03104662       
     81.609240000            0.12508680             0.13505180       
     30.481930000           -0.03221866             0.34488650       
     12.294390000           -0.61722840             0.46285710       
      5.037722000           -0.45259360             0.21104260       
Cr    SP
     41.562910000           -0.00345422            -0.00672250       
     13.676270000            0.07218428            -0.02806471       
      5.844390000            0.25448200             0.05820028       
      2.471609000           -0.29345340             0.39169880       
      1.028308000           -0.73854550             0.50478230       
      0.407250000           -0.19471570             0.17902900       
Cr    SP
      1.571464000            0.05892219            -0.19301000       
      0.605580000            0.29760550             0.09605620       
      0.098561000           -1.14750600             0.98176090       
Cr    SP
      0.036459000            1.00000000             1.00000000       
Cr    D
     13.5367472123           0.1119134766     
      3.4401597836           0.4307135301     
      0.9443297182           0.6725709357     
Cr    D
      0.2197057097           1.0000000        
Cr    F
      0.80000000             1.0000000        
end
basis "Mn_m6-31G*" SPHERICAL
Mn    S
  56347.140000000            0.00177158       
   8460.943000000            0.01357081       
   1927.325000000            0.06690605       
    543.234300000            0.23185410       
    173.990500000            0.47990460       
     59.360050000            0.34957370       
Mn    SP
   1165.412000000            0.00238875             0.00397732       
    277.327600000            0.03181708             0.03103112       
     89.472780000            0.12546700             0.13518940       
     33.482560000           -0.02955431             0.34573870       
     13.540370000           -0.61751600             0.46292050       
      5.557972000           -0.45444580             0.20905920       
Mn    SP
     45.835320000           -0.00366586            -0.00688758       
     15.187770000            0.07231971            -0.02846816       
      6.500710000            0.25444860             0.06031832       
      2.751583000           -0.29103800             0.39389610       
      1.145404000           -0.73598600             0.50137690       
      0.453687000           -0.19976170             0.17922640       
Mn    SP
      1.757999000            0.05628572            -0.50350240       
      0.667022000            0.28974910             0.23450110       
      0.105129000           -1.14065300             0.91412570       
Mn    SP
      0.038418000            1.00000000             1.00000000       
Mn    D
     17.4640356959           0.1021964953     
      4.5235533151           0.4169414088     
      1.3041931349           0.6799648276     
Mn    D
      0.3369193736           1.0000000        
Mn    F
      0.80000000             1.0000000        
end
basis "Fe_m6-31G*" SPHERICAL
Fe    S
  61132.620000000            0.00176611       
   9179.342000000            0.01353038       
   2090.857000000            0.06673128       
    589.247900000            0.23148230       
    188.754300000            0.47970580       
     64.446290000            0.35019760       
Fe    SP
   1259.980000000            0.00243801             0.00402802       
    299.876100000            0.03224048             0.03144647       
     96.849170000            0.12657240             0.13683170       
     36.310200000           -0.03139902             0.34872360       
     14.729960000           -0.62075930             0.46179310       
      6.066075000           -0.45029140             0.20430580       
Fe    SP
     50.434850000           -0.00387326            -0.00701713       
     16.839290000            0.07196598            -0.02877660       
      7.192086000            0.25565910             0.06181383       
      3.053420000           -0.28828370             0.39549460       
      1.273643000           -0.73428220             0.49890590       
      0.504091000           -0.20493530             0.17912510       
Fe    SP
      1.950316000            0.05694869            -0.45937960       
      0.736721000            0.28829150             0.28521390       
      0.114177000           -1.13815900             0.90764850       
Fe    SP
      0.041148000            1.00000000             1.00000000       
Fe    D
     19.2960488121           0.1050074059     
      5.0216501028           0.4228007951     
      1.4414455281           0.6740867843     
Fe    D
      0.3646837240           1.0000000        
Fe    F
      0.80000000             1.0000000        
end
basis "Co_m6-31G*" SPHERICAL
Co    S
  66148.990000000            0.00175979       
   9933.077000000            0.01348162       
   2262.816000000            0.06649342       
    637.915400000            0.23079390       
    204.412200000            0.47929190       
     69.825380000            0.35140970       
Co    SP
   1378.841000000            0.00237628             0.00397149       
    328.269400000            0.03167450             0.03108174       
    106.094600000            0.12628880             0.13574390       
     39.832750000           -0.02584552             0.34768270       
     16.186220000           -0.61834910             0.46263400       
      6.667788000           -0.45670080             0.20516320       
Co    SP
     54.523550000           -0.00399300            -0.00729077       
     18.297830000            0.07409663            -0.02926027       
      7.867348000            0.25420000             0.06564150       
      3.340534000           -0.29216570             0.40006520       
      1.393756000           -0.73187030             0.49502360       
      0.551326000           -0.20407840             0.17582400       
Co    SP
      2.151947000            0.05379843            -0.21654960       
      0.811063000            0.27599710             0.12404880       
      0.121017000           -1.12969200             0.97240640       
Co    SP
      0.043037000            1.00000000             1.00000000       
Co    D
     21.3342776067           0.1068275301     
      5.5768194304           0.4266878706     
      1.5985127182           0.6698677042     
Co    D
      0.3995329086           1.0000000        
Co    F
      0.80000000             1.0000000        
end
basis "Ni_m6-31G*" SPHERICAL
Ni    S
  71396.350000000            0.00175300       
  10720.840000000            0.01343122       
   2442.129000000            0.06627041       
    688.426500000            0.23025080       
    220.615300000            0.47901860       
     75.393730000            0.35234440       
Ni    SP
   1492.532000000            0.00237071             0.00396755       
    355.401300000            0.03160566             0.03109479       
    114.953400000            0.12663350             0.13595170       
     43.220430000           -0.02417037             0.34851360       
     17.597100000           -0.61877750             0.46254980       
      7.257765000           -0.45767700             0.20351860       
Ni    SP
     59.352610000           -0.00416200            -0.00742145       
     20.021810000            0.07425111            -0.02953410       
      8.614561000            0.25413600             0.06731852       
      3.660531000           -0.29034770             0.40166600       
      1.528111000           -0.73021210             0.49266230       
      0.604057000           -0.20760570             0.17568930       
Ni    SP
      2.379276000            0.05157888            -0.18876630       
      0.885839000            0.27076110             0.10151990       
      0.128529000           -1.12477000             0.97909060       
Ni    SP
      0.045195000            1.00000000             1.00000000       
Ni    D
     23.4797449981           0.1083435458     
      6.1618058722           0.4298776432     
      1.7645451103           0.6663191638     
Ni    D
      0.4366865521           1.0000000        
Ni    F
      0.80000000             1.0000000        
end
basis "Cu_m6-31G*" SPHERICAL
Cu    S
  76794.380000000            0.00174816       
  11530.700000000            0.01339602       
   2626.575000000            0.06610885       
    740.490300000            0.22982650       
    237.352800000            0.47876750       
     81.158180000            0.35307390       
Cu    SP
   1610.814000000            0.00236405             0.00396331       
    383.636700000            0.03153635             0.03110223       
    124.173300000            0.12694520             0.13613500       
     46.746780000           -0.02262840             0.34929140       
     19.065690000           -0.61920800             0.46247800       
      7.871567000           -0.45853930             0.20201020       
Cu    SP
     64.457320000           -0.00433108            -0.00752373       
     21.852120000            0.07412307            -0.02975687       
      9.405343000            0.25421080             0.06849654       
      3.999168000           -0.28748430             0.40271410       
      1.670297000           -0.72914360             0.49084900       
      0.659627000           -0.21139510             0.17592680       
Cu    SP
      2.600088000            0.05027577            -0.17029110       
      0.963094000            0.26500400             0.09310133       
      0.136161000           -1.12015500             0.98143360       
Cu    SP
      0.047332000            1.00000000             1.00000000       
Cu    D
     23.7507076365           0.1176454522     
      6.2001031538           0.4444063028     
      1.7193642175           0.6546667345     
Cu    D
      0.3881782772           1.0000000        
Cu    F
      0.80000000             1.0000000        
end