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#  cc-pwCVQZ-NR  EMSL  Basis Set Exchange Library  3/15/13 10:19 AM
# Elements                             References
# --------                             ----------
# Sc - Zn: N.B. Balabanov and K.A. Peterson, J. Chem. Phys., accepted (2005).
#   


basis "Sc_cc-pwCVQZ-NR" SPHERICAL
Sc    S
 8417909.0000000             1.981292E-06          -1.147926E-06           2.22196E-07           -5.350285E-08          -9.140993E-08          -1.445075E-07          -1.607992E-07     
 1260312.0000000             1.540697E-05          -8.929259E-06           1.729799E-06          -4.164419E-07          -7.270775E-07          -1.167681E-06          -1.216461E-06     
 286798.4000000              8.106065E-05          -4.696382E-05           9.088001E-06          -2.188499E-06          -3.702449E-06          -5.810201E-06          -6.659894E-06     
  81234.6900000              0.0003423943          -0.0001985315           3.848622E-05          -9.264628E-06          -1.633468E-05          -2.64162E-05           -2.670499E-05     
  26503.1100000              0.00124699            -0.0007230932           0.0001399997          -3.371711E-05          -5.64236E-05           -8.781407E-05          -0.0001039947     
   9568.7010000              0.004056425           -0.002358822            0.0004585975          -0.0001103886          -0.000196819           -0.0003207912          -0.0003133995     
   3732.4970000              0.01200596            -0.007008148            0.001364588           -0.0003287051          -0.0005428811          -0.000836375           -0.001029884      
   1548.4220000              0.03235944            -0.01912407             0.003773739           -0.000908425           -0.001642692           -0.00270364            -0.002530633      
    675.5420000              0.07819972            -0.04728922             0.009493887           -0.002288204           -0.003709752           -0.00563396            -0.007335917      
    307.2522000              0.1617396             -0.1032480              0.02174611            -0.005238462           -0.009699229           -0.01622651            -0.01414587       
    144.6672000              0.2618480             -0.1861960              0.04228528            -0.01021547            -0.0158935             -0.02336426            -0.03451496       
     70.0438700              0.2748284             -0.2480547              0.0654061             -0.01581707            -0.03149937            -0.05523292            -0.03859251       
     34.3225000              0.1419647             -0.1614781              0.04759732            -0.01162945            -0.0115392             -0.008807771           -0.05560506       
     15.6122400              0.07046176             0.1779183             -0.0816033              0.02013432             0.01426789            -0.0002060869           0.1025062        
      7.7437220              0.1288392              0.5324076             -0.3283980              0.08405086             0.1977719              0.3882857              0.2265527        
      3.8442600              0.09269352             0.3752830             -0.3654561              0.0984825              0.09493216             0.0974343              0.6017289        
      1.7197660              0.01229949             0.05198123             0.2102218             -0.06838523             0.0267895              0.006858569           -1.4029740        
      0.8325230             -0.0004588239          -0.004029053            0.6856793             -0.2353627             -0.9351082             -2.3215700             -0.8478364        
      0.3855640              0.0001722703           0.0003794092           0.3684308             -0.2776984              0.1820725              2.6665800              3.0947890        
      0.0967000             -5.410745E-05          -0.0004006692           0.02050798             0.2987423              2.0774230              0.1898281             -5.7927330        
      0.0477780              4.892875E-05           0.0003219248          -0.006410776            0.6193723             -1.1139440             -2.6840650              6.9441580        
Sc    S
      0.0223630              1.0000000        
Sc    S
      3.1343000              1.0000000        
Sc    S
      1.7369000              1.0000000        
Sc    P
  22640.9700000              0.0000120             -0.0000040              0.0000010              0.0000010              0.0000020             -0.0000020        
   5357.5450000              0.0001070             -0.0000350              0.0000090              0.0000100              0.0000200             -0.0000290        
   1740.3730000              0.0006250             -0.0002050              0.0000500              0.0000600              0.0001280             -0.0001300        
    666.6163000              0.0028300             -0.0009320              0.0002270              0.0002740              0.0005340             -0.0007520        
    283.6384000              0.0105300             -0.0034840              0.0008530              0.0010250              0.0021640             -0.0022120        
    129.7976000              0.0328810             -0.0110190              0.0026860              0.0032500              0.0063070             -0.0088930        
     62.6795600              0.0858840             -0.0294150              0.0072250              0.0086740              0.0183770             -0.0182620        
     31.5044100              0.1800300             -0.0637130              0.0155900              0.0188660              0.0360160             -0.0530410        
     16.2352500              0.2892240             -0.1060850              0.0263030              0.0314660              0.0694300             -0.0599390        
      8.5183240              0.3279100             -0.1286380              0.0317770              0.0386630              0.0719490             -0.1556420        
      4.5190050              0.2101980             -0.0530120              0.0124830              0.0149230              0.0577890              0.0095720        
      2.3665910              0.0546800              0.1740260             -0.0526270             -0.0596700             -0.1752840              0.0918980        
      1.2152350              0.0018530              0.3925500             -0.1140250             -0.1347060             -0.3373290              1.2567100        
      0.6143480             -0.0014170              0.3965140             -0.1463710             -0.1728090             -0.5644270             -1.0111150        
      0.3007450             -0.0009530              0.1765440             -0.0138630             -0.0806980              1.1633800             -1.3688360        
      0.1260040             -0.0000510              0.0191110              0.3524440              0.5542640              0.5658350              2.3777820        
      0.0548400             -0.0000210              0.0000750              0.5504540              0.5500070             -0.9715060             -1.1539840        
Sc    P
      0.0235570              1.0000000        
Sc    P
      4.0678000              1.0000000        
Sc    P
      0.9987000              1.0000000        
Sc    D
    145.4680000              0.0004940             -0.0005050             -0.0006670              0.0008360        
     43.4188000              0.0041980             -0.0042930             -0.0055930              0.0084950        
     16.5768000              0.0189670             -0.0194750             -0.0259900              0.0334810        
      6.9711100              0.0584080             -0.0606310             -0.0791400              0.1270110        
      3.1334700              0.1376050             -0.1436610             -0.1936220              0.2482810        
      1.4576800              0.2314700             -0.2292940             -0.2899810              0.4455630        
      0.6745380              0.2965300             -0.2619730             -0.1702510             -0.5406450        
      0.3051620              0.3052000             -0.0530060              0.6126870             -0.8783940        
      0.1341130              0.2380750              0.4119990              0.4817940              1.4431180        
      0.0572700              0.1073860              0.4831900             -0.6794480             -0.4690810        
Sc    D
      0.0233540              1.0000000        
Sc    D
      2.1374000              1.0000000        
Sc    D
      0.9795000              1.0000000        
Sc    F
      2.7750000              1.0000000        
Sc    F
      1.0597000              1.0000000        
Sc    F
      0.4046000              1.0000000        
Sc    F
      0.1125000              1.0000000        
Sc    G
      2.4928000              1.0000000        
Sc    G
      0.9149000              1.0000000        
Sc    G
      0.2573000              1.0000000        
Sc    H
      2.0516000              1.0000000        
Sc    H
      0.5016000              1.0000000        
end
basis "Ti_cc-pwCVQZ-NR" SPHERICAL
Ti    S
 9317034.0000000             1.967884E-06          -1.130007E-06           2.252735E-07          -5.318433E-08          -9.711872E-08          -1.533644E-07          -1.764526E-07     
 1394971.0000000             1.530198E-05          -8.789416E-06           1.753631E-06          -4.139855E-07          -7.73397E-07           -1.234295E-06          -1.314401E-06     
 317453.1000000              8.050403E-05          -4.622623E-05           9.213052E-06          -2.175153E-06          -3.931052E-06          -6.177188E-06          -7.355464E-06     
  89921.0000000              0.0003400302          -0.0001954047           3.901242E-05          -9.209567E-06          -1.738323E-05          -2.787253E-05          -2.863762E-05     
  29338.1600000              0.001238349           -0.0007117              0.0001419184          -3.350761E-05          -5.986536E-05          -9.355199E-05          -0.0001156551     
  10592.6600000              0.004028475           -0.002321755            0.0004648635          -0.0001097393          -0.0002095853          -0.0003378352          -0.0003330732     
   4132.0560000              0.01192508            -0.006899511            0.001383544           -0.0003267006          -0.0005756482          -0.0008935475          -0.001155156      
   1714.2350000              0.03215601            -0.01883765             0.003827354           -0.0009036567          -0.001751595           -0.002842353           -0.002659832      
    747.9151000              0.0777862             -0.04663976             0.009639191           -0.002277257           -0.00393512            -0.006052332           -0.008332036      
    340.1991000              0.1612030             -0.1020764              0.02211719            -0.005226756           -0.0103849             -0.0170469             -0.01462611       
    160.2060000              0.2618826             -0.1848693              0.04314954            -0.01021707            -0.0169110             -0.02549806            -0.0403089        
     77.5885100              0.2766541             -0.2479601              0.06703481            -0.01591468            -0.03410989            -0.05791149            -0.03745842       
     38.0448900              0.1442968             -0.1634863              0.04946424            -0.01182814            -0.01220437            -0.01271791            -0.07375959       
     17.3536200              0.06993131             0.1779147             -0.08333456             0.02011999             0.01397535             0.006260762            0.1443268        
      8.6420620              0.1259449              0.5351738             -0.3384435              0.08526584             0.2176212              0.4080306              0.2119031        
      4.3044040              0.0902583              0.3752822             -0.3674069              0.09693489             0.09532708             0.1284258              0.7474187        
      1.9377180              0.01200401             0.05217038             0.2247056             -0.07082672             0.01782524            -0.1231286             -2.0310800        
      0.9365940             -0.0003976168          -0.003863192            0.6878815             -0.2359740             -1.0163420             -2.2673310              0.1922693        
      0.4326240              0.0001425444           0.0002845374           0.3594435             -0.2629613              0.3107026              2.8075070              2.2877680        
      0.1073520             -4.196664E-05          -0.0003500414           0.01933695             0.3011214              1.9917860             -0.3028009             -5.1681350        
      0.0520340              4.824213E-05           0.0003192906          -0.005997819            0.6125074             -1.1429550             -2.0712270              6.4603230        
Ti    S
      0.0240380              1.0000000        
Ti    S
      4.0263000              1.0000000        
Ti    S
      1.0457000              1.0000000        
Ti    P
  25537.3300000              0.0000120             -0.0000040              0.0000010              0.0000010              0.0000020             -0.0000030        
   6042.2430000              0.0001040             -0.0000350              0.0000080              0.0000100              0.0000200             -0.0000280        
   1962.6530000              0.0006070             -0.0002030              0.0000490              0.0000610              0.0001260             -0.0001340        
    751.7338000              0.0027510             -0.0009250              0.0002210              0.0002750              0.0005260             -0.0007360        
    319.8833000              0.0102660             -0.0034700              0.0008360              0.0010340              0.0021510             -0.0022930        
    146.4300000              0.0321800             -0.0110200              0.0026410              0.0032830              0.0062570             -0.0087520        
     70.7486100              0.0844860             -0.0295770              0.0071510              0.0088290              0.0184550             -0.0192260        
     35.5908800              0.1783320             -0.0645740              0.0155300              0.0193080              0.0362470             -0.0525890        
     18.3689300              0.2885740             -0.1084580              0.0264790              0.0326120              0.0709200             -0.0658940        
      9.6586550              0.3287580             -0.1319100              0.0319800              0.0399770              0.0718270             -0.1481120        
      5.1367300              0.2115410             -0.0530890              0.0125610              0.0152990              0.0592010             -0.0241240        
      2.6988720              0.0555190              0.1781250             -0.0529940             -0.0626200             -0.1842720              0.1769790        
      1.3897030              0.0020200              0.3957010             -0.1130390             -0.1382880             -0.3296530              1.1584280        
      0.7031630             -0.0014290              0.3927280             -0.1436980             -0.1763480             -0.5457640             -0.9634580        
      0.3441230             -0.0009410              0.1744770             -0.0103360             -0.0554040              1.1454310             -1.3245080        
      0.1413610             -0.0000530              0.0189460              0.3547360              0.5592910              0.5526250              2.2913730        
      0.0608630             -0.0000170             -0.0003280              0.5481010              0.5331150             -0.9642600             -1.1129320        
Ti    P
      0.0259070              1.0000000        
Ti    P
      4.8140000              1.0000000        
Ti    P
      1.2166000              1.0000000        
Ti    D
    196.9490000              0.0003820             -0.0003880             -0.0006220             -0.0006960        
     58.8372000              0.0033680             -0.0034280             -0.0054930             -0.0070890        
     22.5654000              0.0162420             -0.0165980             -0.0269680             -0.0310130        
      9.5756600              0.0523770             -0.0541720             -0.0895330             -0.1200550        
      4.3185900              0.1299280             -0.1366600             -0.2283740             -0.2789100        
      2.0232700              0.2312330             -0.2294490             -0.3312580             -0.3789610        
      0.9467780              0.3035610             -0.2549950             -0.1063490              0.5737430        
      0.4338760              0.3092680             -0.0476610              0.6310360              0.7279500        
      0.1922740              0.2316440              0.3948800              0.3966210             -1.2976560        
      0.0815020              0.1015400              0.4964530             -0.6180090              0.3203760        
Ti    D
      0.0322850              1.0000000        
Ti    D
      2.7905000              1.0000000        
Ti    D
      1.3765000              1.0000000        
Ti    F
      3.7381000              1.0000000        
Ti    F
      1.4957000              1.0000000        
Ti    F
      0.5985000              1.0000000        
Ti    F
      0.1821000              1.0000000        
Ti    G
      3.2185000              1.0000000        
Ti    G
      1.2746000              1.0000000        
Ti    G
      0.4002000              1.0000000        
Ti    H
      2.7919000              1.0000000        
Ti    H
      0.8721000              1.0000000        
end
basis "V_cc-pwCVQZ-NR" SPHERICAL
V    S
 10251780.0000000            1.966291E-06          -1.100923E-06           2.278854E-07          -5.275948E-08          -1.003479E-07          -1.592148E-07          -1.885199E-07     
 1534920.0000000             1.528967E-05          -8.56325E-06            1.773942E-06          -4.107129E-07          -7.997061E-07          -1.278305E-06          -1.39455E-06      
 349300.9000000              8.043932E-05          -4.503678E-05           9.319992E-06          -2.157711E-06          -4.060397E-06          -6.420097E-06          -7.881519E-06     
  98942.0500000              0.0003397617          -0.0001903808           3.946449E-05          -9.13722E-06           -1.79807E-05           -2.883633E-05          -3.027981E-05     
  32281.3600000              0.001237405           -0.0006934284           0.000143572           -3.323885E-05          -6.18137E-05           -9.73589E-05           -0.000124316      
  11655.2700000              0.00402574            -0.002262429            0.0004702911          -0.0001088925          -0.0002168915          -0.0003491402          -0.0003507231     
   4546.5480000              0.01191912            -0.006724991            0.001399998           -0.0003241407          -0.0005942417          -0.0009316194          -0.00124644       
   1886.1850000              0.03215431            -0.01837325             0.003874111           -0.0008972319          -0.001814506           -0.002934959           -0.00278742       
    822.9417000              0.07785452            -0.0455526              0.009765942           -0.002262105           -0.004064807           -0.006333703           -0.009045618      
    374.3439000              0.1616367             -0.09996969             0.02244179            -0.005203068           -0.01079223            -0.01760698            -0.01522967       
    176.3069000              0.2634194             -0.1819111              0.04390091            -0.01019123            -0.01752264            -0.02696848            -0.04437496       
     85.4066100              0.2799986             -0.2458744              0.06843462            -0.0159482             -0.03573873            -0.05982079            -0.03793507       
     41.9043500              0.1473474             -0.1638089              0.0509650             -0.01193588            -0.01263079            -0.01545613            -0.08564216       
     19.1552500              0.06826405             0.1795843             -0.0853594              0.02018344             0.01393494             0.01103001             0.1715635        
      9.5716170              0.1194436              0.5389547             -0.3474804              0.08610071             0.2305046              0.4234006              0.2192374        
      4.7800860              0.08507582             0.3749098             -0.3672368              0.09487917             0.0936574              0.1454088              0.8190393        
      2.1618600              0.01125814             0.05200269             0.2385408             -0.07309753             0.00782896            -0.2197140             -2.4396980        
      1.0427110             -0.0003353521          -0.003775873            0.6888178             -0.2349632             -1.0538540             -2.1943290              0.9048685        
      0.4802820              0.0001070571           0.0001686888           0.3509919             -0.2500297              0.3865591              2.8574410              1.7069230        
      0.1176380             -2.979622E-05          -0.0003063802           0.01826144             0.3026096              1.9257830             -0.5832475             -4.6758140        
      0.0561740              4.672816E-05           0.0003238096          -0.005541134            0.6061635             -1.1464290             -1.6928450              6.0487340        
V    S
      0.0256610              1.0000000        
V    S
      4.4316000              1.0000000        
V    S
      1.2776000              1.0000000        
V    P
  28563.3200000              0.0000110             -0.0000040              0.0000010              0.0000010              0.0000020             -0.0000030        
   6757.1910000              0.0001010             -0.0000340              0.0000080              0.0000100              0.0000200             -0.0000290        
   2194.6520000              0.0005920             -0.0002020              0.0000490              0.0000600              0.0001290             -0.0001410        
    840.5257000              0.0026900             -0.0009200              0.0002210              0.0002750              0.0005360             -0.0007730        
    357.6666000              0.0100630             -0.0034590              0.0008380              0.0010330              0.0022030             -0.0024220        
    163.7534000              0.0316540             -0.0110250              0.0026560              0.0032960              0.0064280             -0.0092670        
     79.1446600              0.0834780             -0.0297320              0.0072330              0.0088960              0.0190710             -0.0205550        
     39.8385800              0.1772260             -0.0653490              0.0158080              0.0196130              0.0377120             -0.0564850        
     20.5853600              0.2883980             -0.1105270              0.0271720              0.0333180              0.0742670             -0.0714930        
     10.8430700              0.3294320             -0.1345370              0.0328010              0.0410090              0.0752600             -0.1577910        
      5.7779690              0.2121300             -0.0524370              0.0123380              0.0149590              0.0609980             -0.0215520        
      3.0431700              0.0558820              0.1822160             -0.0554180             -0.0642560             -0.2009760              0.2379500        
      1.5702390              0.0020970              0.3980180             -0.1156040             -0.1418170             -0.3453430              1.1318370        
      0.7949750             -0.0014710              0.3891530             -0.1390920             -0.1739660             -0.5018350             -1.0891800        
      0.3889800             -0.0009480              0.1727170              0.0006820             -0.0411320              1.1436310             -1.1257730        
      0.1573270             -0.0000550              0.0187460              0.3520090              0.5639950              0.5044870              2.1681890        
      0.0665660             -0.0000130             -0.0005940              0.5422050              0.5238960             -0.9441030             -1.1102630        
V    P
      0.0278610              1.0000000        
V    P
      5.6395000              1.0000000        
V    P
      1.4302000              1.0000000        
V    D
    238.0090000              0.0003500             -0.0003700             -0.0005750              0.0007340        
     71.1896000              0.0031300             -0.0033170             -0.0051570              0.0072580        
     27.3946000              0.0154780             -0.0164740             -0.0259290              0.0339580        
     11.7173000              0.0508290             -0.0548390             -0.0880590              0.1298550        
      5.3248000              0.1275480             -0.1408390             -0.2311790              0.3316480        
      2.5169800              0.2304470             -0.2395530             -0.3383520              0.3569830        
      1.1907500              0.3040580             -0.2519100             -0.0850300             -0.6934390        
      0.5518090              0.3083660             -0.0261060              0.6267990             -0.5768500        
      0.2469260              0.2290220              0.3877700              0.3834730              1.2280290        
      0.1051000              0.1013600              0.4867240             -0.6102620             -0.3167410        
V    D
      0.0413930              1.0000000        
V    D
      3.4512000              1.0000000        
V    D
      1.7775000              1.0000000        
V    F
      4.7261000              1.0000000        
V    F
      1.9376000              1.0000000        
V    F
      0.7944000              1.0000000        
V    F
      0.2550000              1.0000000        
V    G
      3.9825000              1.0000000        
V    G
      1.6478000              1.0000000        
V    G
      0.5645000              1.0000000        
V    H
      3.6783000              1.0000000        
V    H
      1.3165000              1.0000000        
end
basis "Cr_cc-pwCVQZ-NR" SPHERICAL
Cr    S
 11016640.0000000            2.002522E-06          -1.118844E-06           2.358227E-07          -5.343793E-08          -1.038573E-07          -1.671645E-07          -2.018526E-07     
 1649423.0000000             1.557145E-05          -8.70279E-06            1.83614E-06           -4.166295E-07          -8.291687E-07          -1.331951E-06          -1.476099E-06     
 375358.9000000              8.192146E-05          -4.576974E-05           9.643686E-06          -2.183977E-06          -4.198902E-06          -6.764614E-06          -8.479016E-06     
 106323.6000000              0.0003460132          -0.0001934803           4.085166E-05          -9.275174E-06          -1.865777E-05          -2.994507E-05          -3.186673E-05     
  34689.7600000              0.001260141           -0.0007046922           0.0001485404          -3.361788E-05          -6.386131E-05          -0.000102993           -0.0001344019     
  12524.8300000              0.004099273           -0.002299139            0.0004868639          -0.0001106225          -0.0002252576          -0.0003611865          -0.0003665342     
   4885.7520000              0.01213424            -0.006833193            0.001448156           -0.0003275214          -0.0006131653          -0.0009903414          -0.001355222      
   2026.9180000              0.03271636            -0.01866493             0.004010503           -0.0009122671          -0.001886356           -0.003022002           -0.002884635      
    884.3645000              0.07912296            -0.04624835             0.01009579            -0.002281936           -0.004185316           -0.006778242           -0.009908511      
    402.3170000              0.1638397             -0.1013820              0.02321493            -0.005294506           -0.01123172            -0.01798719            -0.01547488       
    189.5271000              0.2655107             -0.1839390              0.04524056            -0.01022548            -0.01791544            -0.02926094            -0.04925232       
     91.8609500              0.2789671             -0.2469356              0.07025001            -0.01618464            -0.03714198            -0.05950832            -0.03533906       
     45.1247600              0.1444466             -0.1597390              0.05032135            -0.01124211            -0.01126485            -0.02030054            -0.09963499       
     20.6251200              0.06941606             0.1940936             -0.09350992             0.02096236             0.01522975             0.02995049             0.2140183        
     10.3197300              0.1195153              0.5461479             -0.3650249              0.09050667             0.2458640              0.4202560              0.2137561        
      5.1577230              0.08084582             0.3610571             -0.3530889              0.08642079             0.07882802             0.1844826              0.8609798        
      2.3126280              0.009975024            0.04658647             0.2829720             -0.0785363             -0.01862956            -0.4526654             -2.9258430        
      1.1030790             -0.000286577           -0.003493969            0.7001955             -0.2526007             -1.0962620             -1.8921570              1.9665580        
      0.4980420              0.0001176051           0.0002600074           0.3067473             -0.2133579              0.5510966              2.8485940              0.7515651        
      0.1182470             -2.164013E-05          -0.00024401             0.01083139             0.3577908              1.8947270             -1.1247750             -4.1073970        
      0.0573560              5.032702E-05           0.0003266435          -0.001458427            0.5691145             -1.3157730             -0.9810669              5.7017810        
Cr    S
      0.0257600              1.0000000        
Cr    S
      4.7691000              1.0000000        
Cr    S
      1.4152000              1.0000000        
Cr    P
  31539.8900000              0.0000110             -0.0000040              0.0000010              0.0000010              0.0000030             -0.0000030        
   7460.2340000              0.0001000             -0.0000350              0.0000080              0.0000100              0.0000210             -0.0000310        
   2422.6220000              0.0005870             -0.0002030              0.0000480              0.0000610              0.0001340             -0.0001500        
    927.7547000              0.0026670             -0.0009260              0.0002180              0.0002770              0.0005590             -0.0008150        
    394.8041000              0.0099910             -0.0034870              0.0008270              0.0010410              0.0022970             -0.0025830        
    180.8027000              0.0314930             -0.0111410              0.0026260              0.0033380              0.0067270             -0.0098130        
     87.4239300              0.0832660             -0.0301280              0.0071720              0.0090130              0.0199900             -0.0221160        
     44.0342700              0.1773280             -0.0664840              0.0157380              0.0200130              0.0397890             -0.0602960        
     22.7770400              0.2892300             -0.1128540              0.0271540              0.0340000              0.0784260             -0.0781870        
     12.0154700              0.3296730             -0.1367850              0.0326310              0.0419930              0.0798820             -0.1674430        
      6.4117510              0.2108870             -0.0500570              0.0114930              0.0138040              0.0609720             -0.0135230        
      3.3811360              0.0551740              0.1884690             -0.0560770             -0.0662750             -0.2226880              0.3066960        
      1.7470540              0.0022300              0.4004550             -0.1142520             -0.1461070             -0.3668130              1.0907830        
      0.8850040             -0.0012840              0.3843320             -0.1337370             -0.1694750             -0.4471090             -1.2345450        
      0.4330280             -0.0008540              0.1695200              0.0034730             -0.0285870              1.1518010             -0.9015550        
      0.1734150             -0.0000460              0.0182570              0.3451660              0.5663070              0.4413050              2.0482660        
      0.0726080             -0.0000120             -0.0007430              0.5418440              0.5156880             -0.9140660             -1.1039840        
Cr    P
      0.0299150              1.0000000        
Cr    P
      6.4335000              1.0000000        
Cr    P
      1.6473000              1.0000000        
Cr    D
    268.0400000              0.0003600             -0.0004070             -0.0005820              0.0008280        
     80.2223000              0.0032360             -0.0036770             -0.0052760              0.0080720        
     30.8950000              0.0161530             -0.0184220             -0.0267230              0.0389600        
     13.2481000              0.0534180             -0.0620500             -0.0920120              0.1497060        
      6.0407700              0.1335240             -0.1589460             -0.2423410              0.3879330        
      2.8615900              0.2386370             -0.2629000             -0.3383560              0.2970340        
      1.3554500              0.3094550             -0.2438830             -0.0138860             -0.8758060        
      0.6282480              0.3056910              0.0377400              0.6731700             -0.2958520        
      0.2806230              0.2182890              0.4270640              0.2610890              1.2044240        
      0.1186680              0.0896930              0.4428120             -0.6613960             -0.5298930        
Cr    D
      0.0459310              1.0000000        
Cr    D
      4.0802000              1.0000000        
Cr    D
      2.1475000              1.0000000        
Cr    F
      5.6893000              1.0000000        
Cr    F
      2.3514000              1.0000000        
Cr    F
      0.9718000              1.0000000        
Cr    F
      0.3175000              1.0000000        
Cr    G
      4.6814000              1.0000000        
Cr    G
      1.9685000              1.0000000        
Cr    G
      0.6951000              1.0000000        
Cr    H
      4.4461000              1.0000000        
Cr    H
      1.6775000              1.0000000        
end
basis "Mn_cc-pwCVQZ-NR" SPHERICAL
Mn    S
 12210500.0000000            2.018537E-06          -9.633574E-07           2.316977E-07          -5.127786E-08          -1.017421E-07          -1.64232E-07           -2.001522E-07     
 1828157.0000000             1.569638E-05          -7.493672E-06           1.803633E-06          -3.991995E-07          -8.110718E-07          -1.314241E-06          -1.478765E-06     
 416030.3000000              8.257853E-05          -3.941004E-05           9.476176E-06          -2.097137E-06          -4.116344E-06          -6.63284E-06           -8.372432E-06     
 117843.6000000              0.0003488107          -0.0001666155           4.012553E-05          -8.881375E-06          -1.823899E-05          -2.96042E-05           -3.208892E-05     
  38448.1400000              0.001270414           -0.0006069041           0.000145987           -3.230705E-05          -6.265924E-05          -0.0001007673          -0.0001321413     
  13881.7100000              0.004133905           -0.001981108            0.0004782368          -0.0001058611          -0.0002200741          -0.0003579039          -0.0003714493     
   5415.0020000              0.01224366            -0.005893486            0.001424063           -0.0003151614          -0.0006024678          -0.0009666897          -0.001326456      
   2246.4600000              0.0330604             -0.01613849             0.003942807           -0.0008730066          -0.0018430             -0.003005179           -0.002951265      
    980.1463000              0.08019877            -0.04018929             0.009952411           -0.002203528           -0.004127938           -0.006605816           -0.009655762      
    445.8952000              0.1671550             -0.08903423             0.0229242             -0.005081761           -0.01100471            -0.0180382             -0.01616919       
    210.0558000              0.2743977             -0.1646993              0.04501638            -0.009988834           -0.0179012             -0.02853084            -0.04776647       
    101.8046000              0.2963690             -0.2288840              0.07048742            -0.01570961            -0.03676227            -0.06124413            -0.04049212       
     50.0112600              0.1592852             -0.1560684              0.05291064            -0.01183955            -0.01301427            -0.01893791            -0.09389925       
     22.9393900              0.05681818             0.1882585             -0.08983951             0.02031039             0.01478153             0.01888653             0.1920182        
     11.5226400              0.0827899              0.5512725             -0.3626155              0.08593055             0.2391713              0.4329357              0.2440487        
      5.7763380              0.05840628             0.3755111             -0.3621266              0.08897427             0.08964957             0.1661622              0.8589060        
      2.6259590              0.007343047            0.05061607             0.2656979             -0.07678891            -0.01299627            -0.3401427             -2.7931450        
      1.2603220             -0.0002934793          -0.004926193            0.6892091             -0.2261750             -1.0513300             -2.0393200              1.5640690        
      0.5771300             -4.562245E-05          -0.0006126838           0.3337072             -0.2271869              0.4478536              2.7946610              1.1184620        
      0.1365820             -9.934988E-06          -0.0002821975           0.01594677             0.3003127              1.8048060             -0.7303582             -4.0546640        
      0.0635350              2.391143E-05           0.0003009192          -0.004614546            0.5953419             -1.0710260             -1.4080030              5.4620540        
Mn    S
      0.0285210              1.0000000        
Mn    S
      5.2819000              1.0000000        
Mn    S
      1.5406000              1.0000000        
Mn    P
  35005.1200000              0.0000110             -0.0000040             -0.0000010              0.0000010              0.0000030             -0.0000030        
   8279.4620000              0.0000980             -0.0000340             -0.0000080              0.0000100              0.0000210             -0.0000320        
   2688.4650000              0.0005720             -0.0001990             -0.0000460              0.0000610              0.0001380             -0.0001650        
   1029.4900000              0.0026040             -0.0009070             -0.0002080              0.0002780              0.0005680             -0.0008520        
    438.0708000              0.0097790             -0.0034250             -0.0007920              0.0010520              0.0023680             -0.0028640        
    200.6153000              0.0309380             -0.0109850             -0.0025220              0.0033660              0.0068870             -0.0103380        
     97.0076900              0.0821940             -0.0298560             -0.0069280              0.0091930              0.0208050             -0.0249200        
     48.8705200              0.1761490             -0.0663660             -0.0152920              0.0204040              0.0412070             -0.0639080        
     25.2928100              0.2891330             -0.1135040             -0.0266110              0.0352770              0.0829490             -0.0917040        
     13.3538200              0.3309560             -0.1379910             -0.0319780              0.0429860              0.0823300             -0.1688330        
      7.1317860              0.2122180             -0.0493550             -0.0112220              0.0147830              0.0676490             -0.0457170        
      3.7643650              0.0552270              0.1912420              0.0549880             -0.0708510             -0.2505870              0.4475430        
      1.9462650              0.0012070              0.4023550              0.1104650             -0.1488630             -0.3787840              1.0445440        
      0.9854550             -0.0023550              0.3821160              0.1281620             -0.1726610             -0.3965170             -1.4857210        
      0.4818650             -0.0013200              0.1681990             -0.0029800             -0.0048570              1.1501120             -0.5306040        
      0.1892120             -0.0000940              0.0179050             -0.3368240              0.5718810              0.3830850              1.8217180        
      0.0779800             -0.0000070             -0.0009580             -0.5424410              0.5013280             -0.8923280             -1.0684500        
Mn    P
      0.0316850              1.0000000        
Mn    P
      7.3332000              1.0000000        
Mn    P
      1.9317000              1.0000000        
Mn    D
    301.4270000              0.0003610             -0.0003670             -0.0005810             -0.0007460        
     90.3288000              0.0032590             -0.0033310             -0.0053040             -0.0068580        
     34.8337000              0.0164190             -0.0168130             -0.0270190             -0.0350360        
     14.9770000              0.0547600             -0.0569290             -0.0940670             -0.1265920        
      6.8498300              0.1367270             -0.1457700             -0.2469380             -0.3598640        
      3.2521700              0.2424190             -0.2466730             -0.3420510             -0.3065310        
      1.5430900              0.3103760             -0.2342270             -0.0146210              0.7526320        
      0.7156410              0.3021700              0.0233200              0.6120700              0.4176590        
      0.3193230              0.2135730              0.3875770              0.3201120             -1.0728320        
      0.1344280              0.0890940              0.4676950             -0.5609790              0.2000430        
Mn    D
      0.0515700              1.0000000        
Mn    D
      4.6932000              1.0000000        
Mn    D
      2.4395000              1.0000000        
Mn    F
      6.6965000              1.0000000        
Mn    F
      2.7910000              1.0000000        
Mn    F
      1.1632000              1.0000000        
Mn    F
      0.3863000              1.0000000        
Mn    G
      5.4808000              1.0000000        
Mn    G
      2.3504000              1.0000000        
Mn    G
      0.8651000              1.0000000        
Mn    H
      5.1515000              1.0000000        
Mn    H
      2.0003000              1.0000000        
end
basis "Fe_cc-pwCVQZ-NR" SPHERICAL
Fe    S
      0.1327714E+08          1.976511E-06          -1.020185E-06           2.340322E-07          -5.062297E-08          -9.957952E-08          -1.678013E-07          -1.97919E-07      
 1987888.0000000             1.536912E-05          -7.935347E-06           1.821727E-06          -3.940586E-07          -7.925506E-07          -1.337004E-06          -1.454458E-06     
 452387.1000000              8.085571E-05          -4.173309E-05           9.571315E-06          -2.07034E-06           -4.031635E-06          -6.790249E-06          -8.296892E-06     
 128143.7000000              0.0003415253          -0.0001764249           4.052652E-05          -8.766406E-06          -1.780938E-05          -3.005871E-05          -3.147678E-05     
  41809.1700000              0.001243883           -0.0006426379           0.0001474531          -3.189537E-05          -6.14201E-05           -0.0001033899          -0.0001312505     
  15095.3300000              0.004047547           -0.00209744             0.0004830333          -0.0001044911          -0.00021473            -0.0003626365          -0.0003631851     
   5888.4380000              0.01198848            -0.00623875             0.001438609           -0.0003112113          -0.0005912544          -0.0009947359          -0.001321103      
   2442.8760000              0.03237358            -0.01707492             0.003983915           -0.0008620181          -0.001797193           -0.003038134           -0.002874345      
   1065.8570000              0.07854828            -0.0424857              0.01006355            -0.002178129           -0.004061089           -0.006831095           -0.009655667      
    484.9096000              0.1637396             -0.09392294             0.0232061             -0.00502697            -0.01073419            -0.01819172            -0.01565078       
    228.4585000              0.2687335             -0.1730554              0.0456678             -0.009908113           -0.01773464            -0.02987575            -0.0481821        
    110.7453000              0.2896317             -0.2386626              0.07169322            -0.01561357            -0.03586338            -0.06129076            -0.03801945       
     54.4311600              0.1554235             -0.1623971              0.05421018            -0.01187731            -0.01374002            -0.02302594            -0.09789664       
     25.0109600              0.06284331             0.1869345             -0.09163776             0.02031246             0.01645324             0.02701671             0.1990898        
     12.5926200              0.09927972             0.5495686             -0.3693219              0.08560291             0.2322749              0.4229967              0.2020013        
      6.3232020              0.06931444             0.3723118             -0.3616033              0.08702717             0.09256802             0.2153088              0.9776064        
      2.8833840              0.008885666            0.05057065             0.2734191             -0.07758197            -0.03322957            -0.4343164             -3.0035790        
      1.3828680             -0.00027762            -0.004072645            0.6889090             -0.2214919             -0.9860290             -1.9503480              1.8016620        
      0.6322010              1.27159E-06           -0.0002732199           0.3294179             -0.2196263              0.4046445              2.7202330              0.9747971        
      0.1492380             -1.537759E-05          -0.0002612296           0.01558687             0.2869893              1.6888890             -0.6123241             -3.8975570        
      0.0684940              2.552339E-05           0.0002547393          -0.004161049            0.5927434             -0.8479093             -1.4683290              5.2279090        
Fe    S
      0.0303810              1.0000000        
Fe    S
      5.6613000              1.0000000        
Fe    S
      1.6068000              1.0000000        
Fe    P
  38282.0500000              0.0000110             -0.0000040              0.0000010              0.0000010              0.0000030             -0.0000030        
   9061.5560000              0.0000970             -0.0000340              0.0000070              0.0000110              0.0000220             -0.0000330        
   2944.4500000              0.0005660             -0.0001990              0.0000440              0.0000660              0.0001470             -0.0001780        
   1128.1580000              0.0025750             -0.0009110              0.0001970              0.0002950              0.0005980             -0.0008800        
    480.3380000              0.0096760             -0.0034370              0.0007510              0.0011340              0.0025270             -0.0030750        
    220.1368000              0.0306440             -0.0110420              0.0023910              0.0035850              0.0072600             -0.0107140        
    106.5482000              0.0815530             -0.0300610              0.0065950              0.0099500              0.0223000             -0.0269530        
     53.7426200              0.1752450             -0.0670490              0.0145700              0.0218100              0.0435920             -0.0662790        
     27.8631800              0.2884650             -0.1150700              0.0255290              0.0386610              0.0898240             -0.1011440        
     14.7438200              0.3307340             -0.1399170              0.0304850              0.0456280              0.0863280             -0.1704670        
      7.8933510              0.2127700             -0.0494800              0.0108530              0.0179580              0.0797000             -0.0837750        
      4.1794970              0.0562030              0.1917090             -0.0523850             -0.0815930             -0.2943090              0.6056490        
      2.1656690              0.0018070              0.4030120             -0.1032710             -0.1581940             -0.4046430              0.9572390        
      1.0972400             -0.0019990              0.3807170             -0.1212410             -0.1890710             -0.3242020             -1.7348360        
      0.5360850             -0.0011550              0.1693050              0.0008400              0.0446210              1.1898370             -0.0978650        
      0.2023740             -0.0000790              0.0178720              0.3272880              0.6116920              0.2280980              1.5748130        
      0.0817420             -0.0000030             -0.0014330              0.5442260              0.4461700             -0.8474340             -1.0818170        
Fe    P
      0.0326620              1.0000000        
Fe    P
      8.3381000              1.0000000        
Fe    P
      2.2565000              1.0000000        
Fe    D
    338.5060000              0.0003560             -0.0003910             -0.0005650             -0.0008160        
    101.4920000              0.0032290             -0.0035760             -0.0051850             -0.0071240        
     39.1867000              0.0164140             -0.0181910             -0.0266110             -0.0385600        
     16.9034000              0.0551330             -0.0620900             -0.0930790             -0.1335670        
      7.7629600              0.1375020             -0.1592870             -0.2482970             -0.4152110        
      3.6988700              0.2425950             -0.2697760             -0.3498230             -0.2793690        
      1.7596300              0.3085230             -0.2389970              0.0369220              0.9276650        
      0.8166510              0.2998140              0.0619850              0.6494720              0.1855890        
      0.3638210              0.2150480              0.4136570              0.2342380             -1.0796160        
      0.1525410              0.0925770              0.4348780             -0.6097450              0.4197090        
Fe    D
      0.0579910              1.0000000        
Fe    D
      5.5048000              1.0000000        
Fe    D
      2.9128000              1.0000000        
Fe    F
      7.8340000              1.0000000        
Fe    F
      3.2859000              1.0000000        
Fe    F
      1.3782000              1.0000000        
Fe    F
      0.4624000              1.0000000        
Fe    G
      6.3980000              1.0000000        
Fe    G
      2.7936000              1.0000000        
Fe    G
      1.0668000              1.0000000        
Fe    H
      5.9288000              1.0000000        
Fe    H
      2.3842000              1.0000000        
end
basis "Co_cc-pwCVQZ-NR" SPHERICAL
Co    S
      0.1437022E+08          1.961579E-06          -1.032046E-06           2.357772E-07          -4.98388E-08           -9.633772E-08          -1.73362E-07           -1.968109E-07     
 2151540.0000000             1.525308E-05          -8.027614E-06           1.8353E-06            -3.879304E-07          -7.654083E-07          -1.376434E-06          -1.439789E-06     
 489625.7000000              8.024671E-05          -4.22193E-05            9.642951E-06          -2.038379E-06          -3.90364E-06           -7.026909E-06          -8.265947E-06     
 138690.3000000              0.0003389582          -0.0001784817           4.082978E-05          -8.630129E-06          -1.718665E-05          -3.089757E-05          -3.108989E-05     
  45249.8900000              0.001234551           -0.0006501411           0.000148563           -3.140519E-05          -5.95264E-05           -0.0001071929          -0.0001310184     
  16337.6200000              0.004017237           -0.002121909            0.0004866688          -0.0001028682          -0.0002070482          -0.0003721161          -0.0003577366     
   6373.0730000              0.01189936            -0.006311755            0.001449618           -0.0003064776          -0.0005737293          -0.001033758           -0.001321726      
   2643.9580000              0.03213721            -0.01727558             0.004015116           -0.0008488581          -0.001731567           -0.003111602           -0.00282163       
   1153.6140000              0.0779997             -0.04299353             0.0101482             -0.002146732           -0.003950029           -0.007127428           -0.009692646      
    524.8606000              0.1626825             -0.09507125             0.02342321            -0.004957499           -0.01033969            -0.01859372            -0.01528143       
    247.3069000              0.2671849             -0.1752212              0.0461722             -0.009792183           -0.01736027            -0.03148302            -0.04871094       
    119.9063000              0.2881411             -0.2416127              0.07262205            -0.01545065            -0.03449074            -0.06222078            -0.03611465       
     58.9642900              0.1548301             -0.1645933              0.0551247             -0.01181794            -0.0142204             -0.02684359            -0.1014559        
     27.1361600              0.06451896             0.1880060             -0.09356803             0.02031574             0.01816713             0.0349936              0.2059185        
     13.6891200              0.1030728              0.5505157             -0.3752066              0.08494754             0.2219044              0.4220093              0.1740209        
      6.8827710              0.07137991             0.3701682             -0.3595010              0.0845587              0.09496945             0.2573147              1.0618960        
      3.1446470              0.009131332            0.05007243             0.2821187             -0.07824438            -0.0535677             -0.5363089             -3.1875120        
      1.5062660             -0.0002919679          -0.003975686            0.6882851             -0.2161403             -0.9071045             -1.8561120              2.0527300        
      0.6872680             -5.581488E-06          -0.0002896409           0.3243680             -0.2120657              0.3491874              2.6514750              0.7962451        
      0.1609720             -1.732351E-05          -0.0002552515           0.01501498             0.2777048              1.5866890             -0.5228775             -3.7309490        
      0.0730170              2.132347E-05           0.0002182807          -0.003906005            0.5886342             -0.6425986             -1.4830860              5.0181100        
Co    S
      0.0320710              1.0000000        
Co    S
      6.0721000              1.0000000        
Co    S
      1.6842000              1.0000000        
Co    P
  41961.4000000              0.0000110             -0.0000040              0.0000010              0.0000010              0.0000030             -0.0000040        
   9928.3060000              0.0000950             -0.0000340              0.0000070              0.0000110              0.0000230             -0.0000330        
   3224.9710000              0.0005570             -0.0001980              0.0000440              0.0000690              0.0001500             -0.0001850        
   1235.2930000              0.0025380             -0.0009060              0.0001990              0.0003080              0.0006200             -0.0008870        
    525.8469000              0.0095540             -0.0034280              0.0007600              0.0011870              0.0025920             -0.0032040        
    240.9762000              0.0303350             -0.0110390              0.0024250              0.0037600              0.0075710             -0.0108490        
    116.6418000              0.0809840             -0.0301570              0.0067060              0.0104780              0.0230010             -0.0283310        
     58.8483400              0.1746920             -0.0675490              0.0148900              0.0230580              0.0459430             -0.0673690        
     30.5291000              0.2885440             -0.1164660              0.0261810              0.0410950              0.0929370             -0.1083230        
     16.1694300              0.3311360             -0.1414410              0.0313100              0.0485290              0.0934070             -0.1719860        
      8.6642360              0.2128970             -0.0487170              0.0108480              0.0188210              0.0801520             -0.1084480        
      4.5919430              0.0562950              0.1946550             -0.0538620             -0.0889830             -0.3177930              0.7416070        
      2.3810480              0.0018950              0.4041480             -0.1061120             -0.1710610             -0.4378130              0.8082640        
      1.2062460             -0.0019550              0.3789040             -0.1217750             -0.1897640             -0.2329460             -1.7802720        
      0.5888220             -0.0011260              0.1673060              0.0038630              0.0718740              1.1648970              0.0636530        
      0.2246580             -0.0000740              0.0177190              0.3271980              0.6049170              0.1731560              1.4742420        
      0.0904360             -0.0000030             -0.0012520              0.5419610              0.4357830             -0.8160710             -1.0385490        
Co    P
      0.0358480              1.0000000        
Co    P
      9.3655000              1.0000000        
Co    P
      2.5688000              1.0000000        
Co    D
    375.3200000              0.0003560             -0.0004110             -0.0005450             -0.0008270        
    112.6040000              0.0032390             -0.0037740             -0.0050280             -0.0070410        
     43.5190000              0.0165690             -0.0193160             -0.0259450             -0.0392680        
     18.8147000              0.0559830             -0.0664370             -0.0911040             -0.1333410        
      8.6649100              0.1394030             -0.1705420             -0.2453950             -0.4342300        
      4.1371100              0.2443780             -0.2854770             -0.3481600             -0.2565540        
      1.9708000              0.3081070             -0.2328840              0.0700830              0.9662400        
      0.9150070              0.2972660              0.0944710              0.6494450              0.1097980        
      0.4073700              0.2136850              0.4201780              0.1939420             -1.0470350        
      0.1704440              0.0934140              0.4094740             -0.6184680              0.4375990        
Co    D
      0.0643790              1.0000000        
Co    D
      6.2594000              1.0000000        
Co    D
      3.3241000              1.0000000        
Co    F
      9.0321000              1.0000000        
Co    F
      3.8111000              1.0000000        
Co    F
      1.6081000              1.0000000        
Co    F
      0.5442000              1.0000000        
Co    G
      7.3560000              1.0000000        
Co    G
      3.2498000              1.0000000        
Co    G
      1.2700000              1.0000000        
Co    H
      6.7510000              1.0000000        
Co    H
      2.7959000              1.0000000        
end
basis "Ni_cc-pwCVQZ-NR" SPHERICAL
Ni    S
 15503020.0000000            2.085023E-06          -7.298155E-07           2.453237E-07          -5.114261E-08          -9.762069E-08          -1.771733E-07          -1.988311E-07     
 2321071.0000000             1.621425E-05          -5.677768E-06           1.909637E-06          -3.980779E-07          -7.741142E-07          -1.397615E-06          -1.449716E-06     
 528180.2000000              8.530773E-05          -2.985922E-05           1.003489E-05          -2.092033E-06          -3.959746E-06          -7.203859E-06          -8.363444E-06     
 149604.0000000              0.0003603793          -0.0001262784           4.248835E-05          -8.856836E-06          -1.736914E-05          -3.128552E-05          -3.125532E-05     
  48809.0700000              0.001312632           -0.0004600252           0.0001546187          -3.223602E-05          -6.044953E-05          -0.0001102699          -0.0001327624     
  17622.3900000              0.004272395           -0.00150323             0.000506455           -0.0001055757          -0.0002090555          -0.0003755735          -0.0003589662     
   6874.2010000              0.01265994            -0.004479171            0.00150884            -0.0003146356          -0.0005834312          -0.0010679             -0.001341488      
   2851.8570000              0.03423065            -0.01232512             0.004178816           -0.0008714113          -0.001746713           -0.003128427           -0.002824018      
   1244.3340000              0.08326735            -0.03097639             0.01056668            -0.002205415           -0.004026784           -0.007410272           -0.009863607      
    566.1547000              0.1745758             -0.06998651             0.0243930             -0.005095517           -0.01042362            -0.01859501            -0.01523481       
    266.7873000              0.2898023             -0.1339256              0.04812101            -0.01008237            -0.01781172            -0.03322798            -0.04984489       
    129.3752000              0.3207323             -0.1966881              0.0756517             -0.0159207             -0.03466996            -0.0611844             -0.03522354       
     63.6516100              0.1778265             -0.1402258              0.05748534            -0.01222037            -0.01540945            -0.03286334            -0.1056424        
     29.3330200              0.03633007             0.1960730             -0.09783186             0.02115869             0.02086455             0.04844202             0.2138034        
     14.8221200              0.02089458             0.5564517             -0.3864536              0.08747304             0.2206820              0.3989880              0.1517675        
      7.4605130              0.01596954             0.3702167             -0.3606598              0.08511605             0.1073966              0.3379290              1.1804280        
      3.4135760              0.001730245            0.05396034             0.2888650             -0.08115683            -0.08310668            -0.7016224             -3.5264900        
      1.6328840              0.0004817365           0.004706492            0.6830917             -0.2166359             -0.8942999             -1.6944340              2.5508150        
      0.7435790              0.00012468             0.003736115            0.3206778             -0.2076958              0.3750141              2.5826800              0.4306461        
      0.1725920              2.340378E-05          -7.46805E-05            0.01651471             0.2699296              1.4967530             -0.5498758             -3.4500410        
      0.0774200             -1.348962E-05           9.575336E-05           0.0003124693           0.5842711             -0.5320390             -1.3945510              4.7403420        
Ni    S
      0.0337010              1.0000000        
Ni    S
      6.5001000              1.0000000        
Ni    S
      1.7599000              1.0000000        
Ni    P
  45066.6200000              0.0000110             -0.0000040              0.0000010              0.0000020              0.0000030              0.0000040        
  10662.6400000              0.0000960             -0.0000350              0.0000070              0.0000140              0.0000240              0.0000360        
   3463.4310000              0.0005640             -0.0002020              0.0000410              0.0000840              0.0001550              0.0001990        
   1326.6240000              0.0025700             -0.0009250              0.0001860              0.0003710              0.0006460              0.0009590        
    564.7414000              0.0096770             -0.0034990              0.0007120              0.0014600              0.0026890              0.0034630        
    258.8288000              0.0307420             -0.0112800              0.0022690              0.0045370              0.0078990              0.0117560        
    125.3115000              0.0820650             -0.0308190              0.0062910              0.0129220              0.0239120              0.0306900        
     63.2423300              0.1768450             -0.0690360              0.0139340              0.0277660              0.0480060              0.0730810        
     32.8240600              0.2911620             -0.1187330              0.0245310              0.0509560              0.0962130              0.1168270        
     17.3969200              0.3308160             -0.1424430              0.0287700              0.0567450              0.0975820              0.1911630        
      9.3243940              0.2088190             -0.0431070              0.0087810              0.0241190              0.0770220              0.1065430        
      4.9388390              0.0537390              0.2034990             -0.0517310             -0.1250870             -0.3601360             -0.9499240        
      2.5620250              0.0017090              0.4062280             -0.0959450             -0.2065410             -0.4455890             -0.5636050        
      1.2992940             -0.0017980              0.3709380             -0.1106750             -0.2149830             -0.1165380              1.9346110        
      0.6346780             -0.0010460              0.1643120              0.0027270              0.2078190              1.1705030             -0.5101770        
      0.2322620             -0.0000620              0.0172650              0.3150270              0.6385420             -0.0389310             -1.1722970        
      0.0915460              0.0000000             -0.0016820              0.5428100              0.3262840             -0.7688140              1.0158980        
Ni    P
      0.0356430              1.0000000        
Ni    P
     10.4165000              1.0000000        
Ni    P
      2.9093000              1.0000000        
Ni    D
    414.3427000              0.0003500             -0.0003620             -0.0005290             -0.0007870        
    124.3926000              0.0032000             -0.0033350             -0.0049280             -0.0067780        
     48.1154000              0.0164770             -0.0171760             -0.0253720             -0.0377260        
     20.8420000              0.0560010             -0.0592450             -0.0896540             -0.1291250        
      9.6221000              0.1392340             -0.1512320             -0.2387440             -0.4148090        
      4.6034000              0.2427760             -0.2544610             -0.3597210             -0.2839570        
      2.1963000              0.3040690             -0.2287180              0.0044440              0.8671940        
      1.0206000              0.2933190              0.0206160              0.5965470              0.2723270        
      0.4544000              0.2172590              0.3427530              0.3313020             -0.9868420        
      0.1900000              0.1046990              0.4738710             -0.5090090              0.1853600        
Ni    D
      0.0715000              1.0000000        
Ni    D
      6.9565000              1.0000000        
Ni    D
      3.6674000              1.0000000        
Ni    F
     10.3791000              1.0000000        
Ni    F
      4.4257000              1.0000000        
Ni    F
      1.8872000              1.0000000        
Ni    F
      0.6538000              1.0000000        
Ni    G
      8.5105000              1.0000000        
Ni    G
      3.8307000              1.0000000        
Ni    G
      1.5457000              1.0000000        
Ni    H
      7.7448000              1.0000000        
Ni    H
      3.3495000              1.0000000        
end
basis "Cu_cc-pwCVQZ-NR" SPHERICAL
Cu    S
 16665490.0000000            1.92221E-06           -1.082642E-06           2.389605E-07          -4.823436E-08          -8.876635E-08          -1.849356E-07          -1.980951E-07     
 2495213.0000000             1.494655E-05          -8.420869E-06           1.860009E-06          -3.753858E-07          -7.032135E-07          -1.461905E-06          -1.446191E-06     
 567850.7000000              7.863106E-05          -4.428625E-05           9.77258E-06           -1.972743E-06          -3.601366E-06          -7.510534E-06          -8.326308E-06     
 160853.1000000              0.0003321189          -0.0001872071           4.137619E-05          -8.349961E-06          -1.576871E-05          -3.274989E-05          -3.11938E-05      
  52481.8600000              0.001209649           -0.0006819265           0.0001505588          -3.039535E-05          -5.499726E-05          -0.0001148239          -0.0001320842     
  18948.8500000              0.003936231           -0.002225485            0.0004932175          -9.95301E-05           -0.0001897055          -0.0003935903          -0.0003585362     
   7391.6550000              0.01166031            -0.00661962             0.001469467           -0.0002967188          -0.0005311656          -0.001110617           -0.001333996      
   3066.5170000              0.03149512            -0.0181140              0.004071487           -0.0008217293          -0.001584593           -0.003284174           -0.002824728      
   1337.9940000              0.07646385            -0.04506622             0.01030091            -0.002081377           -0.003671316           -0.007697235           -0.009806333      
    608.7830000              0.1595162             -0.09955443             0.02381408            -0.004811149           -0.009458893           -0.01959013            -0.01529323       
    286.8980000              0.2618983             -0.1830558              0.04707008            -0.009537683           -0.01630134            -0.03444712            -0.04956573       
    139.1530000              0.2816708             -0.2510577              0.0742445             -0.01507351            -0.03145402            -0.06507176            -0.03583468       
     68.4945500              0.1509587             -0.1703417              0.05657657            -0.01161088            -0.01444712            -0.03269416            -0.1044906        
     31.6010800              0.07041955             0.1900077             -0.09760862             0.02032716             0.02037856             0.04738915             0.2105854        
     15.9915800              0.1180039              0.5507048             -0.3856399              0.08327403             0.1997307              0.4333712              0.1646732        
      8.0565100              0.08015187             0.3642532             -0.3540312              0.07953125             0.09475926             0.3189521              1.1505130        
      3.6903290              0.01020122             0.04868977             0.2983959             -0.07901524            -0.07935398            -0.7281955             -3.4837320        
      1.7629020             -0.0003720464          -0.003799993            0.6861809             -0.2054312             -0.7591353             -1.6631160              2.5166360        
      0.8012690             -2.206886E-05          -0.0003156308           0.3150989             -0.1985134              0.2365079              2.5132670              0.4429064        
      0.1842430             -2.401085E-05          -0.0002430411           0.01394564             0.2627133              1.4226040             -0.3736861             -3.4043100        
      0.0817930              1.529816E-05           0.0001553645          -0.00361164             0.5794031             -0.3066203             -1.4791020              4.6278500        
Cu    S
      0.0353030              1.0000000        
Cu    S
      7.2310000              1.0000000        
Cu    S
      1.9080000              1.0000000        
Cu    P
  48218.4100000              0.0000110             -0.0000040              0.0000010              0.0000020              0.0000030              0.0000040        
  11420.5500000              0.0000970             -0.0000350              0.0000070              0.0000130              0.0000250              0.0000370        
   3713.5690000              0.0005690             -0.0002060              0.0000400              0.0000790              0.0001630              0.0001900        
   1423.7620000              0.0025890             -0.0009410              0.0001820              0.0003490              0.0006760              0.0009780        
    606.6041000              0.0097420             -0.0035560              0.0006970              0.0013730              0.0028080              0.0033080        
    278.2564000              0.0309300             -0.0114610              0.0022200              0.0042610              0.0082550              0.0119800        
    134.8449000              0.0825300             -0.0313090              0.0061630              0.0121460              0.0249460              0.0292070        
     68.1225400              0.1777580             -0.0701390              0.0136310              0.0260640              0.0501600              0.0751220        
     35.4008800              0.2922250             -0.1205620              0.0240330              0.0479070              0.1002890              0.1078350        
     18.7902900              0.3303490             -0.1435520              0.0278620              0.0528290              0.1023190              0.2073790        
     10.0835600              0.2068630             -0.0403270              0.0079750              0.0215750              0.0772410              0.0604060        
      5.3461200              0.0527930              0.2084660             -0.0511330             -0.1177830             -0.3844490             -0.8949770        
      2.7752280              0.0017180              0.4087240             -0.0923050             -0.1883970             -0.4513540             -0.5584020        
      1.4075640             -0.0017010              0.3682010             -0.1064580             -0.2019160             -0.0947780              1.8997060        
      0.6872130             -0.0009760              0.1596530              0.0037380              0.1737430              1.1731180             -0.5022240        
      0.2468220             -0.0000540              0.0159550              0.3105410              0.6368480             -0.0541330             -1.1824130        
      0.0962200              0.0000000             -0.0016810              0.5419030              0.3515180             -0.7282440              1.0445070        
Cu    P
      0.0370370              1.0000000        
Cu    P
     11.9218000              1.0000000        
Cu    P
      3.2325000              1.0000000        
Cu    D
    527.8860000              0.0002560             -0.0003160              0.0003790             -0.0005930        
    158.7330000              0.0023780             -0.0029580              0.0035730             -0.0051060        
     61.5556000              0.0127220             -0.0158770              0.0192290             -0.0299220        
     26.8834000              0.0450120             -0.0568640              0.0699030             -0.1032930        
     12.5175000              0.1171960             -0.1535840              0.1993800             -0.3595680        
      6.0697700              0.2185550             -0.2811390              0.3488480             -0.4128070        
      2.9583190              0.2914480             -0.2685180              0.0513940              0.7476890        
      1.4141220              0.2971380              0.0231300             -0.5596790              0.5425150        
      0.6533290              0.2360920              0.3566200             -0.3845810             -0.9777060        
      0.2866920              0.1314440              0.4184700              0.4389250             -0.0886030        
Cu    D
      0.1150140              1.0000000        
Cu    D
      8.4804000              1.0000000        
Cu    D
      4.4553000              1.0000000        
Cu    F
     11.9463000              1.0000000        
Cu    F
      5.0345000              1.0000000        
Cu    F
      2.1217000              1.0000000        
Cu    F
      0.7391000              1.0000000        
Cu    G
      9.5934000              1.0000000        
Cu    G
      4.3083000              1.0000000        
Cu    G
      1.7760000              1.0000000        
Cu    H
      8.5704000              1.0000000        
Cu    H
      3.7909000              1.0000000        
end
basis "Zn_cc-pwCVQZ-NR" SPHERICAL
Zn    S
      0.1785293E+08          2.106603E-06          -6.503871E-07           2.455424E-07           4.916948E-08          -1.379282E-07          -1.951222E-07          -2.631275E-07     
 2673038.0000000             1.638051E-05          -5.059606E-06           1.911263E-06           3.829348E-07          -1.098688E-06          -1.513488E-06          -1.954514E-06     
 608324.4000000              8.617178E-05          -2.660362E-05           1.004137E-05           2.010287E-06          -5.581627E-06          -7.991991E-06          -1.098059E-05     
 172317.6000000              0.0003640028          -0.0001125168           4.25171E-05            8.520784E-06          -2.469757E-05          -3.361493E-05          -4.252529E-05     
  56222.6900000              0.001325778           -0.0004098844           0.0001546957           3.096268E-05          -8.4997E-05            -0.0001233416          -0.0001728905     
  20299.8500000              0.004315394           -0.001340085            0.0005068054           0.000101604           -0.000297955           -0.0004000292          -0.0004940605     
   7918.8710000              0.01278917            -0.003996271            0.001509742            0.0003021322          -0.0008180999          -0.001206705           -0.001731281      
   3285.3400000              0.03459541            -0.01102397             0.004183744            0.0008393851          -0.002498043           -0.003298144           -0.003952778      
   1433.5240000              0.08423468            -0.02783658             0.01058425             0.00211904            -0.005630866           -0.008503531           -0.01260194       
    652.2889000              0.1769497             -0.0635220              0.02447935             0.004923291           -0.01501607            -0.01932075            -0.02205362       
    307.4360000              0.2947718             -0.1235647              0.04837945             0.009713665           -0.02479935            -0.0395118             -0.06268701       
    149.1466000              0.3286054             -0.1860330              0.07630985             0.01549413            -0.05092472            -0.06074193            -0.05878225       
     73.4510800              0.1837326             -0.1345412              0.05798021             0.0117057             -0.01923797            -0.05154698            -0.1200370        
     33.9256200              0.0284564              0.2026370             -0.1010517             -0.02068558             0.0248084              0.0906352              0.2236128        
     17.1894700             -0.001562471            0.5627948             -0.3950702             -0.08652477             0.3402582              0.3930253              0.4980742        
      8.6665950              0.001057694            0.3687315             -0.3534286             -0.07840824             0.1317501              0.5283548              1.1915800        
      3.9725050             -0.0004832147           0.05055865             0.3070109              0.07950591            -0.2092734             -1.4626110             -5.6490630        
      1.8946650              0.0001795943          -0.00028561             0.6935144              0.2182560             -1.2899700             -0.8366769              6.8434890        
      0.8593850             -7.198366E-05           0.001213965            0.3040583              0.1957366              0.9898685              2.6151680             -3.3201000        
      0.1952560              2.200105E-05          -0.0001706895           0.01003318            -0.3195337              1.4779600             -2.2413220             -0.2249601        
      0.0858540             -1.56551E-05            0.0001266229          -0.004007622           -0.5833695             -1.2347640              0.7597394              1.9021540        
Zn    S
      0.0367810              1.0000000        
Zn    S
      8.3276000              1.0000000        
Zn    S
      3.4194000              1.0000000        
Zn    P
  52867.9300000              0.0000110             -0.0000040              0.0000010              0.0000010              0.0000030             -0.0000030        
  12511.7900000              0.0000940             -0.0000350              0.0000060              0.0000110              0.0000240             -0.0000360        
   4065.2860000              0.0005510             -0.0002060              0.0000380              0.0000670              0.0001590             -0.0001740        
   1557.5950000              0.0025110             -0.0009420              0.0001730              0.0002960              0.0006460             -0.0009530        
    663.2892000              0.0094700             -0.0035700              0.0006640              0.0011570              0.0027470             -0.0030470        
    304.1561000              0.0301690             -0.0115400              0.0021200              0.0036340              0.0079380             -0.0117360        
    147.3680000              0.0808550             -0.0316520              0.0059160              0.0103070              0.0246010             -0.0270160        
     74.4546900              0.1751390             -0.0712850              0.0131530              0.0224820              0.0485760             -0.0747980        
     38.7149300              0.2897160             -0.1232840              0.0233720              0.0410330              0.1006820             -0.0982370        
     20.5702200              0.3298490             -0.1476380              0.0272210              0.0464600              0.0984680             -0.2150840        
     11.0542500              0.2092940             -0.0444770              0.0083340              0.0181460              0.0862350             -0.0322140        
      5.8746610              0.0562590              0.2053650             -0.0488600             -0.0943640             -0.3793800              0.7563080        
      3.0529360              0.0050520              0.4100860             -0.0888940             -0.1601770             -0.4203930              0.7019320        
      1.5472250              0.0009970              0.3721450             -0.1036180             -0.1808950             -0.1825620             -1.8141870        
      0.7541510              0.0001870              0.1581180              0.0010510              0.0948260              1.1778870              0.2914540        
      0.2653490              0.0000510              0.0145400              0.3030640              0.6291530              0.0519740              1.2956230        
      0.1020670             -0.0000130             -0.0016080              0.5427240              0.4083180             -0.7444770             -1.0670890        
Zn    P
      0.0387550              1.0000000        
Zn    P
     12.5357000              1.0000000        
Zn    P
      3.4227000              1.0000000        
Zn    D
    639.7806000              0.0002080             -0.0002900             -0.0003170              0.0004520        
    192.6742000              0.0019540             -0.0027380             -0.0030560              0.0038790        
     74.8436800              0.0107110             -0.0151110             -0.0167530              0.0235700        
     32.8604800              0.0390570             -0.0556430             -0.0627120              0.0825260        
     15.3935300              0.1048480             -0.1558640             -0.1879800              0.2972800        
      7.5255120              0.2045690             -0.3034890             -0.3720840              0.4368320        
      3.7154290              0.2852080             -0.3062760             -0.0234390             -0.6042900        
      1.8064590              0.3014460              0.0333950              0.6054700             -0.6746050        
      0.8529730              0.2462280              0.4000750              0.3230630              0.9387020        
      0.3847800              0.1390160              0.3899720             -0.4713720              0.2779680        
Zn    D
      0.1593370              1.0000000        
Zn    D
      9.2094000              1.0000000        
Zn    D
      5.2262000              1.0000000        
Zn    F
     13.2355000              1.0000000        
Zn    F
      5.6706000              1.0000000        
Zn    F
      2.4295000              1.0000000        
Zn    F
      0.8530000              1.0000000        
Zn    G
     10.7902000              1.0000000        
Zn    G
      4.9368000              1.0000000        
Zn    G
      2.0693000              1.0000000        
Zn    H
      9.6086000              1.0000000        
Zn    H
      4.4136000              1.0000000        
end