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/usr/share/libreoffice/help/en/simpress.cfg is in libreoffice-help-en-us 1:3.5.2-2ubuntu1.

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Title=%PRODUCTNAME Impress

Language=en-US
Order=5
Start=text%2Fsimpress%2Fmain0000.xhp
Heading=headingheading
Program=IMPRESS