This file is indexed.

/etc/xdg/autostart/xfce4-volumed.desktop is in xfce4-volumed 0.2.0-0ubuntu2.

This file is owned by root:root, with mode 0o644.

The actual contents of the file can be viewed below.

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[Desktop Entry]
Type=Application
Terminal=false
Name=XFCE Volume Daemon (Pulseaudio)
Comment=Daemon managing the volume multimedia keys and displaying volume notifications for Pulseaudio
Exec=xfce4-volumed
OnlyShowIn=XFCE;