/usr/lib/systemd/user/xfce4-session.service is in xfce4-session 4.12.1-3ubuntu3.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
1 2 3 4 5 6 7 | [Unit]
Description=XFCE 4 Session Manager
PartOf=graphical-session.target
[Service]
ExecStart=/usr/bin/startxfce4
ExecStopPost=-/usr/bin/dbus-send --type=method_call --address=${UPSTART_SESSION} /com/ubuntu/Upstart com.ubuntu.Upstart0_6.EndSession
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