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/usr/share/xcrysden/examples/XYZ/mol1.xyz is in xcrysden-data 1.5.60-1build3.

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The actual contents of the file can be viewed below.

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XYZ Format Test #: 1
   C01    2.325243   -0.115261    0.031711
   H1     2.344577   -0.363301    1.077589
   F1     3.131708   -0.909527   -0.638930
   F2     2.736189    1.130568   -0.134093
   O1     1.079338   -0.265162   -0.526351
   C02    0.007719   -0.041269    0.244204
   F3     0.064656    1.154700    0.824420
   F4    -0.042641   -0.911850    1.255074
   O2    -1.071578   -0.152842   -0.539134
   C03   -2.310374    0.036537    0.022189
   H2    -2.267004    0.230694    1.077874
   F5    -2.890949    1.048938   -0.593940
   F6    -3.029540   -1.046542   -0.203665