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#! Tests RHF/ROHF/UHF SCF gradients

molecule h2o {
0 1
O
H 1 R
H 1 R 2 A

R = 1.0
A = 104.5
}

set {
   reference rhf
   basis cc-pvdz
   e_convergence 8
   d_convergence 8
}

analytic = gradient('scf')

set findif points 3
findif = gradient('scf', dertype=0)

compare_matrices(analytic, findif, 5, "RHF SCF finite-diff (3-pt) vs. analytic gradient to 10^-5") #TEST

set findif points 5
findif = gradient('scf', dertype=0)

compare_matrices(analytic, findif, 7, "RHF SCF finite-diff (5-pt) vs. analytic gradient to 10^-7") #TEST

molecule h2o {
0 3
O
H 1 R
H 1 R 2 A

R = 1.0
A = 104.5
}

set {
   reference rohf
   basis cc-pvdz
}

analytic = gradient('scf')

set findif points 3
findif = gradient('scf', dertype=0)

compare_matrices(analytic, findif, 5, "ROHF SCF finite-diff (3-pt) vs. analytic gradient to 10^-5") #TEST

set findif points 5
findif = gradient('scf', dertype=0)

compare_matrices(analytic, findif, 7, "ROHF SCF finite-diff (5-pt) vs. analytic gradient to 10^-7") #TEST

molecule h2o {
0 3
O
H 1 R
H 1 R 2 A

R = 1.0
A = 104.5
}

set {
   reference uhf
   basis cc-pvdz
}

analytic = gradient('scf')

set findif points 3
findif = gradient('scf', dertype=0)

compare_matrices(analytic, findif, 5, "UHF SCF finite-diff (3-pt) vs. analytic gradient to 10^-5") #TEST

set findif points 5
findif = gradient('scf', dertype=0)

compare_matrices(analytic, findif, 7, "UHF SCF finite-diff (5-pt) vs. analytic gradient to 10^-7") #TEST