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#! SAPT0 open-shell computation of H2O-HO2 interaction energy
#! First with cc-pVDZ and density fitted integrals with UHF
#! Then with 6-31g and direct integrals, except for dispersion 
#! that is computed with cc-pVDZ-ri density fitting with UHF.

memory 2 GB

molecule {
     0 1
     O 0.000000  0.000000  6.000000
     H 0.000000  1.431500  4.890600
     H 0.000000 -1.431500  4.890600
     --
     0 2
     O 0.000000  0.000000  0.000000
     O 0.000000  2.503900  0.000000
     H 0.000000 -0.424700 -1.839500
     units bohr
     symmetry c1
     no_reorient
     no_com
}

set {
reference     uhf
scf_type      df
guess         gwh
basis         cc-pVDZ
df_basis_scf  cc-pVDZ-jkfit
df_basis_sapt cc-pVDZ-ri
stability_analysis follow
}

energy('sapt0')

Eelst = psi4.get_variable("SAPT ELST ENERGY")
Eexch = psi4.get_variable("SAPT EXCH ENERGY")
Eind  = psi4.get_variable("SAPT IND ENERGY")
Edisp = psi4.get_variable("SAPT DISP ENERGY")
ET    = psi4.get_variable("SAPT ENERGY")



set {
guess gwh
basis 6-31g
df_basis_sapt cc-pVDZ-ri
scf_type direct
stability_analysis follow
}

energy('sapt0')

Eelst = psi4.get_variable("SAPT ELST ENERGY")
Eexch = psi4.get_variable("SAPT EXCH ENERGY")
Eind  = psi4.get_variable("SAPT IND ENERGY")
Edisp = psi4.get_variable("SAPT DISP ENERGY")
ET    = psi4.get_variable("SAPT ENERGY")