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#! SAPT2+3(CCD) aug-cc-pVDZ computation of the water dimer interaction energy, 
#! using the aug-cc-pVDZ-JKFIT DF basis for SCF and aug-cc-pVDZ-RI for SAPT.

memory 1 GB

molecule dimer {
0 1
O  -1.551007  -0.114520   0.000000
H  -1.934259   0.762503   0.000000
H  -0.599677   0.040712   0.000000
--
0 1
O   1.350625   0.111469   0.000000
H   1.680398  -0.373741  -0.758561
H   1.680398  -0.373741   0.758561
}

set {
basis aug-cc-pvdz
scf_type df
e_convergence 10
guess sad
freeze_core true
nat_orbs_t3 true
}

energy('sapt2+3(ccd)')


Labels = [
'SAPT Elst',
'SAPT Exch',
'SAPT Ind',
'SAPT Disp',
'SAPT0 Total',
'SAPT2 Total',
'SAPT2+ Total',
'SAPT2+(3) Total',
'SAPT2+3 Total',
'SAPT2+(CCD) Total',
'SAPT2+(3)(CCD) Total',
'SAPT2+3(CCD) Total']

Echeck = [];

Echeck.append(psi4.get_variable("SAPT ELST ENERGY"))
Echeck.append(psi4.get_variable("SAPT EXCH ENERGY"))
Echeck.append(psi4.get_variable("SAPT IND ENERGY"))
Echeck.append(psi4.get_variable("SAPT DISP ENERGY"))
Echeck.append(psi4.get_variable("SAPT0 TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2 TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2+ TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2+(3) TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2+3 TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2+(CCD) TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2+(3)(CCD) TOTAL ENERGY"))
Echeck.append(psi4.get_variable("SAPT2+3(CCD) TOTAL ENERGY"))