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#! Compute the IRC for HOOH torsional rotation at the RHF/DZP level of theory. 
# Print
# the path to a trajectory file for visualization
# in Jmol.
# grep '@IRC' on the output to see a nice printout
# of the progress of your IRC computation.

molecule h2o2 {
  H     0.0000000000   0.9803530335  -0.8498671785
  O     0.0000000000   0.6988545188   0.0536419016
  O     0.0000000000  -0.6988545188   0.0536419016
  H     0.0000000000  -0.9803530335  -0.8498671785
}

# g_convergence needs to be tight for IRCs:
set g_convergence gau_verytight

set {
  basis                      dzp
  opt_type                   irc
  geom_maxiter               50
  irc_direction              backward
}

frequencies('scf', dertype=1)

# Lower point group from C2v to C2
h2o2.reset_point_group('c2')

energy = optimize('scf')