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/usr/share/gromacs/top/gromos43a2.ff/aminoacids.r2b is in gromacs-data 2018.1-1.

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The actual contents of the file can be viewed below.

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; rtp residue to rtp building block table
;GMX   Force-field
CYS    CYSH
HISD   HISA
HISE   HISB
LYS    LYSH
LYSN   LYS
HEM    HEME