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/usr/share/avogadro/fragments/nitriles/isobutyronitrile.cml is in avogadro-data 1.2.0-3.

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The actual contents of the file can be viewed below.

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<?xml version="1.0" encoding="UTF-8"?>
<molecule xmlns="http://www.xml-cml.org/schema"
          xmlns:cml="http://www.xml-cml.org/dict/cml"
          xmlns:units="http://www.xml-cml.org/units/units"
          xmlns:xsd="http://www.w3c.org/2001/XMLSchema"
          xmlns:iupac="http://www.iupac.org"
          id="CS_2-methylpropanenitrile">
  <formula concise=" C 4 H 7 N 1 "/>
  <identifier convention="iupac:inchi" value="1/C4H7N/c1-4(2)3-5/h4H,1-2H3"/>
  <name convention="IUPAC">2-Methylpropanenitrile</name>
  <atomArray>
    <atom id="a1" elementType="C" x3="0.016662" y3="0.258849" z3="-0.389607"/>
    <atom id="a2" elementType="C" x3="-1.283232" y3="-0.388018" z3="0.068475"/>
    <atom id="a3" elementType="H" x3="0.021990" y3="0.331608" z3="-1.506019"/>
    <atom id="a4" elementType="C" x3="1.223245" y3="-0.547987" z3="0.069937"/>
    <atom id="a5" elementType="C" x3="0.103591" y3="1.621730" z3="0.118107"/>
    <atom id="a6" elementType="H" x3="-1.331370" y3="-0.477638" z3="1.161778"/>
    <atom id="a7" elementType="H" x3="-1.377354" y3="-1.399154" z3="-0.348786"/>
    <atom id="a8" elementType="H" x3="2.165249" y3="-0.090478" z3="-0.257643"/>
    <atom id="a9" elementType="H" x3="1.186317" y3="-1.564493" z3="-0.343238"/>
    <atom id="a10" elementType="H" x3="1.261137" y3="-0.638722" z3="1.163547"/>
    <atom id="a11" elementType="N" x3="0.172993" y3="2.706605" z3="0.519181"/>
    <atom id="a12" elementType="H" x3="-2.159227" y3="0.187699" z3="-0.255732"/>
  </atomArray>
  <bondArray>
    <bond atomRefs2="a1 a2" order="1"/>
    <bond atomRefs2="a1 a3" order="1"/>
    <bond atomRefs2="a1 a4" order="1"/>
    <bond atomRefs2="a1 a5" order="1"/>
    <bond atomRefs2="a2 a6" order="1"/>
    <bond atomRefs2="a2 a7" order="1"/>
    <bond atomRefs2="a4 a8" order="1"/>
    <bond atomRefs2="a4 a9" order="1"/>
    <bond atomRefs2="a4 a10" order="1"/>
    <bond atomRefs2="a5 a11" order="3"/>
    <bond atomRefs2="a2 a12" order="1"/>
  </bondArray>
  <propertyList>
    <property dictRef="cml:molwt" title="Molecular weight">
      <scalar dataType="xsd:double" dictRef="cml:molwt" units="units:g">69.1051</scalar>
    </property>
    <property dictRef="cml:monoisotopicwt" title="Monoisotopic weight">
      <scalar dataType="xsd:double" dictRef="cml:monoisotopicwt" units="units:g">69.0578492</scalar>
    </property>
    <property dictRef="cml:mp" title="Melting point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:mp" units="units:celsius">-72</scalar>
    </property>
    <property dictRef="cml:bp" title="Boiling point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:bp" units="units:celsius">107</scalar>
    </property>
  </propertyList>
</molecule>