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/usr/share/avogadro/fragments/heteroaromatics/thiophene.cml is in avogadro-data 1.2.0-3.

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The actual contents of the file can be viewed below.

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<?xml version="1.0" encoding="UTF-8"?>
<molecule xmlns="http://www.xml-cml.org/schema"
          xmlns:cml="http://www.xml-cml.org/dict/cml"
          xmlns:units="http://www.xml-cml.org/units/units"
          xmlns:xsd="http://www.w3c.org/2001/XMLSchema"
          xmlns:iupac="http://www.iupac.org"
          id="CS_thiophene">
  <formula concise=" C 4 H 4 S 1 "/>
  <identifier convention="iupac:inchi" value="1/C4H4S/c1-2-4-5-3-1/h1-4H"/>
  <name convention="IUPAC">Thiophene</name>
  <atomArray>
    <atom id="a1" elementType="C" x3="1.126214" y3="0.765886" z3="0.000000"/>
    <atom id="a2" elementType="C" x3="0.819345" y3="-0.564955" z3="0.000000"/>
    <atom id="a3" elementType="C" x3="-0.598383" y3="-0.795127" z3="0.000000"/>
    <atom id="a4" elementType="C" x3="-1.310706" y3="0.370165" z3="0.000000"/>
    <atom id="a5" elementType="S" x3="-0.285330" y3="1.757144" z3="0.000000"/>
    <atom id="a6" elementType="H" x3="2.130424" y3="1.185837" z3="0.000000"/>
    <atom id="a7" elementType="H" x3="1.548377" y3="-1.375303" z3="0.000000"/>
    <atom id="a8" elementType="H" x3="-1.033768" y3="-1.794407" z3="0.000000"/>
    <atom id="a9" elementType="H" x3="-2.396173" y3="0.450760" z3="0.000000"/>
  </atomArray>
  <bondArray>
    <bond atomRefs2="a1 a2" order="2"/>
    <bond atomRefs2="a2 a3" order="1"/>
    <bond atomRefs2="a3 a4" order="2"/>
    <bond atomRefs2="a4 a5" order="1"/>
    <bond atomRefs2="a5 a1" order="1"/>
    <bond atomRefs2="a1 a6" order="1"/>
    <bond atomRefs2="a2 a7" order="1"/>
    <bond atomRefs2="a3 a8" order="1"/>
    <bond atomRefs2="a4 a9" order="1"/>
  </bondArray>
  <propertyList>
    <property dictRef="cml:molwt" title="Molecular weight">
      <scalar dataType="xsd:double" dictRef="cml:molwt" units="units:g">84.1396</scalar>
    </property>
    <property dictRef="cml:monoisotopicwt" title="Monoisotopic weight">
      <scalar dataType="xsd:double" dictRef="cml:monoisotopicwt" units="units:g">84.0033711</scalar>
    </property>
    <property dictRef="cml:mp" title="Melting point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:mp" units="units:celsius">-38</scalar>
    </property>
    <property dictRef="cml:bp" title="Boiling point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:bp" units="units:celsius">84</scalar>
    </property>
  </propertyList>
</molecule>