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/usr/share/avogadro/fragments/alkenes/E-oct-3-ene.cml is in avogadro-data 1.2.0-3.

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The actual contents of the file can be viewed below.

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<?xml version="1.0" encoding="UTF-8"?>
<molecule xmlns="http://www.xml-cml.org/schema"
          xmlns:cml="http://www.xml-cml.org/dict/cml"
          xmlns:units="http://www.xml-cml.org/units/units"
          xmlns:xsd="http://www.w3c.org/2001/XMLSchema"
          xmlns:iupac="http://www.iupac.org"
          id="CS_E-oct-3-ene">
  <formula concise=" C 8 H 16 "/>
  <identifier convention="iupac:inchi" value="1/C8H16/c1-3-5-7-8-6-4-2/h5,7H,3-4,6,8H2,1-2H3/b7-5+"/>
  <name convention="IUPAC">(E)-Oct-3-ene</name>
  <atomArray>
    <atom id="a1" elementType="C" x3="4.119180" y3="0.044284" z3="1.358298"/>
    <atom id="a2" elementType="C" x3="2.693002" y3="-0.289323" z3="1.740594"/>
    <atom id="a3" elementType="C" x3="1.810242" y3="-0.333389" z3="0.543590"/>
    <atom id="a4" elementType="C" x3="0.659125" y3="0.335521" z3="0.466538"/>
    <atom id="a5" elementType="C" x3="-0.218834" y3="0.295030" z3="-0.733685"/>
    <atom id="a6" elementType="C" x3="-1.672539" y3="0.069540" z3="-0.344405"/>
    <atom id="a7" elementType="C" x3="-2.576464" y3="0.060923" z3="-1.566869"/>
    <atom id="a8" elementType="C" x3="-4.023867" y3="-0.149053" z3="-1.183557"/>
    <atom id="a9" elementType="H" x3="4.529350" y3="-0.682922" z3="0.645022"/>
    <atom id="a10" elementType="H" x3="4.775228" y3="0.048162" z3="2.238054"/>
    <atom id="a11" elementType="H" x3="4.190241" y3="1.034728" z3="0.890556"/>
    <atom id="a12" elementType="H" x3="2.320143" y3="0.439790" z3="2.487679"/>
    <atom id="a13" elementType="H" x3="2.652122" y3="-1.278034" z3="2.240588"/>
    <atom id="a14" elementType="H" x3="2.161402" y3="-0.958206" z3="-0.287726"/>
    <atom id="a15" elementType="H" x3="0.309427" y3="0.961488" z3="1.297771"/>
    <atom id="a16" elementType="H" x3="0.109043" y3="-0.489240" z3="-1.445896"/>
    <atom id="a17" elementType="H" x3="-0.113502" y3="1.256211" z3="-1.277392"/>
    <atom id="a18" elementType="H" x3="-2.003432" y3="0.855545" z3="0.364128"/>
    <atom id="a19" elementType="H" x3="-1.771668" y3="-0.886916" z3="0.206232"/>
    <atom id="a20" elementType="H" x3="-2.252305" y3="-0.732307" z3="-2.269665"/>
    <atom id="a21" elementType="H" x3="-2.466662" y3="1.013040" z3="-2.123453"/>
    <atom id="a22" elementType="H" x3="-4.384827" y3="0.643274" z3="-0.514226"/>
    <atom id="a23" elementType="H" x3="-4.170607" y3="-1.105541" z3="-0.664388"/>
    <atom id="a24" elementType="H" x3="-4.673796" y3="-0.152606" z3="-2.067791"/>
  </atomArray>
  <bondArray>
    <bond atomRefs2="a1 a2" order="1"/>
    <bond atomRefs2="a2 a3" order="1"/>
    <bond atomRefs2="a3 a4" order="2"/>
    <bond atomRefs2="a4 a5" order="1"/>
    <bond atomRefs2="a5 a6" order="1"/>
    <bond atomRefs2="a6 a7" order="1"/>
    <bond atomRefs2="a7 a8" order="1"/>
    <bond atomRefs2="a1 a9" order="1"/>
    <bond atomRefs2="a1 a10" order="1"/>
    <bond atomRefs2="a1 a11" order="1"/>
    <bond atomRefs2="a2 a12" order="1"/>
    <bond atomRefs2="a2 a13" order="1"/>
    <bond atomRefs2="a3 a14" order="1"/>
    <bond atomRefs2="a4 a15" order="1"/>
    <bond atomRefs2="a5 a16" order="1"/>
    <bond atomRefs2="a5 a17" order="1"/>
    <bond atomRefs2="a6 a18" order="1"/>
    <bond atomRefs2="a6 a19" order="1"/>
    <bond atomRefs2="a7 a20" order="1"/>
    <bond atomRefs2="a7 a21" order="1"/>
    <bond atomRefs2="a8 a22" order="1"/>
    <bond atomRefs2="a8 a23" order="1"/>
    <bond atomRefs2="a8 a24" order="1"/>
  </bondArray>
  <propertyList>
    <property dictRef="cml:molwt" title="Molecular weight">
      <scalar dataType="xsd:double" dictRef="cml:molwt" units="units:g">112.2126</scalar>
    </property>
    <property dictRef="cml:monoisotopicwt" title="Monoisotopic weight">
      <scalar dataType="xsd:double" dictRef="cml:monoisotopicwt" units="units:g">112.1252005</scalar>
    </property>
    <property dictRef="cml:bp" title="Boiling point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:bp" units="units:celsius">122</scalar>
    </property>
  </propertyList>
</molecule>