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/usr/share/avogadro/fragments/alkanes/2-methylpropane.cml is in avogadro-data 1.2.0-3.

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The actual contents of the file can be viewed below.

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<?xml version="1.0" encoding="UTF-8"?>
<molecule xmlns="http://www.xml-cml.org/schema"
          xmlns:cml="http://www.xml-cml.org/dict/cml"
          xmlns:units="http://www.xml-cml.org/units/units"
          xmlns:xsd="http://www.w3c.org/2001/XMLSchema"
          xmlns:iupac="http://www.iupac.org"
          id="CS_2-methylpropane">
  <formula concise=" C 4 H 10 "/>
  <identifier convention="iupac:inchi" value="1/C4H10/c1-4(2)3/h4H,1-3H3"/>
  <name convention="IUPAC">2-Methylpropane</name>
  <atomArray>
    <atom id="a1" elementType="H" x3="2.023313" y3="-0.365417" z3="0.755709"/>
    <atom id="a2" elementType="C" x3="1.412552" y3="-0.255752" z3="-0.149765"/>
    <atom id="a3" elementType="H" x3="1.655894" y3="0.718785" z3="-0.594222"/>
    <atom id="a4" elementType="H" x3="1.731698" y3="-1.029360" z3="-0.860146"/>
    <atom id="a5" elementType="C" x3="-0.069418" y3="-0.371904" z3="0.165322"/>
    <atom id="a6" elementType="H" x3="-0.257277" y3="-1.378489" z3="0.612506"/>
    <atom id="a7" elementType="C" x3="-0.483849" y3="0.686446" z3="1.173871"/>
    <atom id="a8" elementType="H" x3="0.088302" y3="0.595567" z3="2.106290"/>
    <atom id="a9" elementType="H" x3="-0.319920" y3="1.700652" z3="0.785305"/>
    <atom id="a10" elementType="H" x3="-1.548119" y3="0.600503" z3="1.428681"/>
    <atom id="a11" elementType="C" x3="-0.894849" y3="-0.249347" z3="-1.104543"/>
    <atom id="a12" elementType="H" x3="-0.748201" y3="0.725349" z3="-1.589249"/>
    <atom id="a13" elementType="H" x3="-0.622710" y3="-1.023011" z3="-1.834159"/>
    <atom id="a14" elementType="H" x3="-1.967418" y3="-0.354023" z3="-0.895598"/>
  </atomArray>
  <bondArray>
    <bond atomRefs2="a1 a2" order="1"/>
    <bond atomRefs2="a2 a3" order="1"/>
    <bond atomRefs2="a2 a4" order="1"/>
    <bond atomRefs2="a2 a5" order="1"/>
    <bond atomRefs2="a5 a6" order="1"/>
    <bond atomRefs2="a5 a7" order="1"/>
    <bond atomRefs2="a5 a11" order="1"/>
    <bond atomRefs2="a7 a8" order="1"/>
    <bond atomRefs2="a7 a9" order="1"/>
    <bond atomRefs2="a7 a10" order="1"/>
    <bond atomRefs2="a11 a12" order="1"/>
    <bond atomRefs2="a11 a13" order="1"/>
    <bond atomRefs2="a11 a14" order="1"/>
  </bondArray>
  <propertyList>
    <property dictRef="cml:molwt" title="Molecular weight">
      <scalar dataType="xsd:double" dictRef="cml:molwt" units="units:g">58.1222</scalar>
    </property>
    <property dictRef="cml:monoisotopicwt" title="Monoisotopic weight">
      <scalar dataType="xsd:double" dictRef="cml:monoisotopicwt" units="units:g">58.0782503</scalar>
    </property>
    <property dictRef="cml:mp" title="Melting point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:mp" units="units:celsius">-160</scalar>
    </property>
    <property dictRef="cml:bp" title="Boiling point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:bp" units="units:celsius">-12</scalar>
    </property>
  </propertyList>
</molecule>