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/usr/share/avogadro/crystals/other/LaAlO3.cif is in avogadro-data 1.2.0-3.

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The actual contents of the file can be viewed below.

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data_5910090
loop_
_publ_author_name
'Wyckoff, R. W. G.'
_publ_section_title
;
Page 274 from the second edition of Structure of Crystals by Wyckoff
R W G. Published by The Chemical Catalog Company, INC, New York in 1931
http://jcrystal.com/steffenweber/gallery/StructureTypes/st4.html
;
_journal_name_full               'The second edition of Structure of Crystals'
_journal_page_first              274
_journal_page_last               274
_journal_year                    1931
_chemical_formula_structural     LaAlO3
_chemical_formula_sum            'Al La O3'
_chemical_name_systematic        LaAlO3
_space_group_IT_number           221
_symmetry_cell_setting           cubic
_symmetry_Int_Tables_number      221
_symmetry_space_group_name_Hall  '-P 4 2 3'
_symmetry_space_group_name_H-M   'P m -3 m'
_audit_creation_date             2005-04-11
_audit_creation_method
;
Page 274 from the second edition of Structure of Crystals by Wyckoff
R W G. Published by The Chemical Catalog Company, INC, New York in 1931
http://jcrystal.com/steffenweber/gallery/StructureTypes/st4.html
;
_audit_update_record
'created by Girish Upreti, Portland State University'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   3.78
_cell_length_b                   3.78
_cell_length_c                   3.78
_cell_volume                     54.010
_[local]_cod_chemical_formula_sum_orig 'La Al O3'
_cod_database_code               5910090
loop_
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loop_
_atom_site_fract_x
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_atom_site_label
0.00000 0.00000 0.00000 La
0.50000 0.50000 0.50000 Al
0.50000 0.50000 0.00000 O