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#------------------------------------------------------------------------------
#$Date: 2010-01-30 13:59:17 +0000 (Sat, 30 Jan 2010) $
#$Revision: 966 $
#$URL: svn://cod.ibt.lt/cod/cif/1/1001248.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1001248
_chemical_name_systematic          'Silicon nitride - $-beta'
_chemical_formula_structural       'Si3 N4'
_chemical_formula_sum              'N4 Si3'
_publ_section_title
;
Modifications structurales du nitrure de silicium en fonction de la
temperature
;
loop_
_publ_author_name
  'Billy, M'
  'Labbe, J C'
  'Selvaraj, A'
  'Roult, G'
_journal_name_full                 'Materials Research Bulletin'
_journal_coden_ASTM                MRBUAC
_journal_volume                    18
_journal_year                      1983
_journal_page_first                921
_journal_page_last                 934
_cell_length_a                     7.6322(6)
_cell_length_b                     7.6322(6)
_cell_length_c                     2.9191(4)
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  120
_cell_volume                       147.3
_cell_formula_units_Z              2
_symmetry_space_group_name_H-M     'P 63/m'
_symmetry_Int_Tables_number        176
_symmetry_cell_setting             hexagonal
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-y,x-y,z'
  'y-x,-x,z'
  '-x,-y,1/2+z'
  'y,y-x,1/2+z'
  'x-y,x,1/2+z'
  '-x,-y,-z'
  'y,y-x,-z'
  'x-y,x,-z'
  'x,y,1/2-z'
  '-y,x-y,1/2-z'
  'y-x,-x,1/2-z'
loop_
_atom_type_symbol
_atom_type_oxidation_number
  N3-   -3.000
  Si4+   4.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_attached_hydrogens
_atom_site_calc_flag
  N1    N3-    2 c 0.3333 0.6667 0.25 1.  0 d
  N2    N3-    6 h 0.3394 0.0362 0.25 1.  0 d
  Si1   Si4+   6 h 0.1952 0.7656 0.25 1.  0 d
_cod_database_code 1001248