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data_global
_chemical_name_mineral 'Nacrite'
loop_
_publ_author_name
'Zhukhlistov A P'
_journal_name_full 'Crystallography Reports'
_journal_volume 53 
_journal_year 2008
_journal_page_first 76
_journal_page_last 82
_publ_section_title
;
 Crystal structure of nacrite from the electron diffraction data
;
_database_code_amcsd 0012394
_chemical_formula_sum 'Al2 Si2 O9 H4'
_cell_length_a 8.910
_cell_length_b 5.144
_cell_length_c 14.593
_cell_angle_alpha 90
_cell_angle_beta 100.50
_cell_angle_gamma 90
_cell_volume 657.642
_exptl_crystal_density_diffrn      2.607
_symmetry_space_group_name_H-M 'C 1 c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Al1   0.32750  -0.07030  -0.00020
Al2   0.16280   0.42450   0.00040
Si1   0.06320   0.27960   0.18970
Si2   0.23420  -0.23440   0.19070
O1   0.13490   0.00110   0.22150
O2   0.18090   0.50270   0.23620
O3   0.41190  -0.19250   0.23710
O4   0.02140   0.31110   0.07880
O5   0.21430  -0.26200   0.07940
O-h1   0.32710   0.23790   0.07480
O-h2   0.16400   0.11530  -0.06600
O-h3   0.28530  -0.37930  -0.06500
O-h4   0.47720   0.04320  -0.06510
H1   0.42600   0.31800   0.09600
H2   0.59900   0.41000   0.37800
H3   0.30000   0.34600   0.38000
H4   0.49900  -0.11400   0.38000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Al1 0.00817 0.00643 0.00939 -0.00114 0.00064 0.00075
Al2 0.00778 0.00630 0.00834 -0.00068 0.00064 0.00150
Si1 0.00778 0.00617 0.01043 -0.00183 0.00446 -0.00075
Si2 0.00817 0.00885 0.00834 -0.00091 0.00255 0.00037
O1 0.01011 0.00858 0.01565 -0.00023 0.00764 -0.00112
O2 0.00933 0.00858 0.01043 0.00183 0.00127 -0.00224
O3 0.01166 0.01019 0.01565 0.00411 0.00637 0.00037
O4 0.01089 0.00871 0.01043 -0.00479 0.00446 -0.00112
O5 0.01089 0.01099 0.00939 0.00320 0.00318 0.00523
O-h1 0.01011 0.00818 0.01147 0.00023 0.00637 0.00187
O-h2 0.01283 0.01059 0.01460 -0.00297 0.00573 -0.00486
O-h3 0.00855 0.00938 0.01252 0.00114 0.00446 -0.00075
O-h4 0.01089 0.01206 0.01460 0.00068 0.00573 0.00000
H1 0.04899 0.03928 0.04589 0.01027 0.03057 0.02580
H2 0.03849 0.04424 0.04381 -0.02146 -0.00255 0.01533
H3 0.03577 0.03820 0.03442 0.02009 0.01401 -0.01421
H4 0.03499 0.03740 0.04172 0.02762 0.03184 0.00897