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/usr/share/gromacs/top/gmx.ff/decane.itp is in gromacs-data 4.5.5-2.

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The actual contents of the file can be viewed below.

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[ moleculetype ]
; Name	nrexcl
C10	3

[ atoms ] 
; nr    type   	resnr  	residu  atom  	cgnr	charge
1	CP3	1	C10	C1	1	0.0
2	CP2	1	C10	C2	2	0.0
3	CP2	1	C10	C3	3	0.0
4	CP2	1	C10	C4	4	0.0
5	CP2	1	C10	C5	5	0.0
6	CP2	1	C10	C6	6	0.0
7	CP2	1	C10	C7	7	0.0
8	CP2	1	C10	C8	8	0.0
9	CP2	1	C10	C9	9	0.0
10	CP3	1	C10	C10	10	0.0

[ bonds ]
; i	j
1	2
2	3
3	4
4	5
5	6
6	7
7	8
8	9
9	10

[ angles ]
; i	j	k
1	2	3
2	3	4
3	4	5
4	5	6
5	6	7
6	7	8
7	8	9
8	9	10

[ dihedrals ]
; i	j	k 	l	type
1 	2	3	4	3
2	3	4	5	3
3	4	5	6	3
4	5	6	7	3
5	6	7	8	3
6	7	8	9	3
7	8	9	10	3