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/usr/share/gromacs/top/amber99sb.ff/dna.arn is in gromacs-data 4.5.5-2.

This file is owned by root:root, with mode 0o644.

The actual contents of the file can be viewed below.

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DNA  OP1  O1P
DNA  OP2  O2P
DNA  H2'  H2'1
DNA  H2'' H2'2
DNA  H5'  H5'1
DNA  H5'' H5'2
DNA  HO5' H5T
DNA  HO3' H3T