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/usr/share/avogadro/fragments/alkynes/propyne.cml is in avogadro-data 1.0.3-5.

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The actual contents of the file can be viewed below.

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<?xml version="1.0" encoding="UTF-8"?>
<molecule xmlns="http://www.xml-cml.org/schema"
          xmlns:cml="http://www.xml-cml.org/dict/cml"
          xmlns:units="http://www.xml-cml.org/units/units"
          xmlns:xsd="http://www.w3c.org/2001/XMLSchema"
          xmlns:iupac="http://www.iupac.org"
          id="CS_propyne">
  <formula concise=" C 3 H 4 "/>
  <identifier convention="iupac:inchi" value="1/C3H4/c1-3-2/h1H,2H3"/>
  <name convention="IUPAC">Propyne</name>
  <atomArray>
    <atom id="a1" elementType="C" x3="-0.479166" y3="-0.001224" z3="-0.113245"/>
    <atom id="a2" elementType="C" x3="-1.638781" y3="-0.004287" z3="-0.386990"/>
    <atom id="a3" elementType="C" x3="0.915058" y3="0.002412" z3="0.216097"/>
    <atom id="a4" elementType="H" x3="-2.674224" y3="-0.007012" z3="-0.631428"/>
    <atom id="a5" elementType="H" x3="1.063845" y3="0.271382" z3="1.270112"/>
    <atom id="a6" elementType="H" x3="1.457897" y3="0.728104" z3="-0.403679"/>
    <atom id="a7" elementType="H" x3="1.355372" y3="-0.989376" z3="0.049132"/>
  </atomArray>
  <bondArray>
    <bond atomRefs2="a1 a2" order="3"/>
    <bond atomRefs2="a1 a3" order="1"/>
    <bond atomRefs2="a2 a4" order="1"/>
    <bond atomRefs2="a3 a5" order="1"/>
    <bond atomRefs2="a3 a6" order="1"/>
    <bond atomRefs2="a3 a7" order="1"/>
  </bondArray>
  <propertyList>
    <property dictRef="cml:molwt" title="Molecular weight">
      <scalar dataType="xsd:double" dictRef="cml:molwt" units="units:g">40.0639</scalar>
    </property>
    <property dictRef="cml:monoisotopicwt" title="Monoisotopic weight">
      <scalar dataType="xsd:double" dictRef="cml:monoisotopicwt" units="units:g">40.0313001</scalar>
    </property>
    <property dictRef="cml:mp" title="Melting point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:mp" units="units:celsius">-102</scalar>
    </property>
    <property dictRef="cml:bp" title="Boiling point">
      <scalar dataType="xsd:double" errorValue="1.0" dictRef="cml:bp" units="units:celsius">-23</scalar>
    </property>
  </propertyList>
</molecule>