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***************************************************
                    Input file
***************************************************

#
# File Name
#

System.CurrrentDir    ./             # default=./
System.Name           V_CA13
Log.print             off            # ON|OFF

System.UseRestartfile  yes           # NO|YES, default=NO
System.Restartfile     V_CA13      # default=null

#
# Calculation type
#

eq.type               dirac          # sch|sdirac|dirac 
calc.type             VPS            # ALL|VPS|PAO
xc.type               LDA            # LDA|GGA

#
# Atom
#

AtomSpecies             23
max.occupied.N           4
total.electron        23.0
valence.electron      13.0 
<occupied.electrons 
 1   2.0
 2   2.0  6.0
 3   2.0  6.0  3.0
 4   2.0  0.0  0.0  0.0
occupied.electrons>

#
# parameters for solving 1D-differential equations
#

grid.xmin             -8.0           # default=-7.0 rmin(a.u.)=exp(grid.xmin)
grid.xmax              3.2           # default= 2.5 rmax(a.u.)=exp(grid.xmax)
grid.num             12000           # default=4000
grid.num.output        500           # default=2000

#
# SCF
#

scf.maxIter             60           # default=40            
scf.Mixing.Type       simple         # Simple|GR-Pulay 
scf.Init.Mixing.Weight 0.10          # default=0.300 
scf.Min.Mixing.Weight  0.001         # default=0.001 
scf.Max.Mixing.Weight  0.800         # default=0.800 
scf.Mixing.History      7            # default=5
scf.Mixing.StartPulay   7            # default=6
scf.criterion         1.0e-14        # default=1.0e-9

#
# Pseudo potetial, cutoff (A.U.)
#

vps.type               MBK           # BHS|TM        
number.vps              7
<pseudo.NandL
 0  3  0  1.10  0.0 
 1  3  1  1.70  0.0 
 2  3  2  1.45  0.0  
 3  4  0  2.30  0.0
 4  4  1  2.40  0.0
 5  4  2  2.90  0.7
 6  4  3  1.20  0.0
pseudo.NandL> 
Blochl.projector.num    4            # default=1 which means KB-form
local.type           Polynomial      # Simple|Polynomial
local.part.vps          1            # default=0
local.cutoff           1.40          # default=smallest_cutoff_vps
local.origin.ratio     2.20          # default=3.0
log.deri.RadF.calc      on           # ON|OFF
log.deri.MinE          -2.0          # default=-3.0 (Hartree)
log.deri.MaxE           2.0          # default= 2.0 (Hartree) 
log.deri.num            100          # default=50
<log.deri.R
 0  2.9 2.9
 1  2.9 2.9
 2  2.9 2.9
 3  2.9 2.9
log.deri.R>
ghost.check             off          # ON|OFF

 
#
# Core electron density for partial core correction
#   pcc.ratio=rho_core/rho_V,
#   pcc.ratio.origin = rho_core(orgin)/rho_core(ip)
#

charge.pcc.calc         on           # ON|OFF
pcc.ratio              0.06          # default=1.0     
pcc.ratio.origin      12.0           # default=6.0     

#
# Pseudo atomic orbitals
#

maxL.pao                3            # default=2
num.pao                15            # default=7 
radial.cutoff.pao      6.0           # default=5.0 (Bohr)
height.of.wall    20000.0            # default=4000.0 (Hartree)
rising.edge            0.2           # default=0.5(Bohr),r1=rc-rising.edge
search.LowerE       -3.000           # default=-3.000 (Hartree)
search.UpperE       60.000           # default=20.000 (Hartree)
num.of.partition      2200           # default=300
matching.point.ratio  0.67           # default=0.67

*****************************************************
    SCF history in all electron calculations      
*****************************************************

 SCF=   1  Eeigen=-568.7357073073828 (Hartree)  NormRD=  2.1787759276045
 SCF=   2  Eeigen=-568.0479527770622 (Hartree)  NormRD=  2.0242413389908
 SCF=   3  Eeigen=-567.9304873886174 (Hartree)  NormRD=  1.9635133660665
 SCF=   4  Eeigen=-565.8560639874627 (Hartree)  NormRD=  0.4310282019933
 SCF=   5  Eeigen=-565.0706520267515 (Hartree)  NormRD=  0.1327226367309
 SCF=   6  Eeigen=-563.5690511986670 (Hartree)  NormRD=  0.0032481268698
 SCF=   7  Eeigen=-564.4542504319146 (Hartree)  NormRD=  0.0010291486698
 SCF=   8  Eeigen=-563.5073589629927 (Hartree)  NormRD=  0.0009890002145
 SCF=   9  Eeigen=-564.5019398658436 (Hartree)  NormRD=  0.0010927136622
 SCF=  10  Eeigen=-564.0059959091973 (Hartree)  NormRD=  0.0000011505321
 SCF=  11  Eeigen=-563.9884550145641 (Hartree)  NormRD=  0.0000000207162
 SCF=  12  Eeigen=-563.9880281249161 (Hartree)  NormRD=  0.0000000076271
 SCF=  13  Eeigen=-563.9880480356258 (Hartree)  NormRD=  0.0000000009556
 SCF=  14  Eeigen=-563.9880606111024 (Hartree)  NormRD=  0.0000000000787
 SCF=  15  Eeigen=-563.9880616197044 (Hartree)  NormRD=  0.0000000000080
 SCF=  16  Eeigen=-563.9880618976824 (Hartree)  NormRD=  0.0000000000071
 SCF=  17  Eeigen=-563.9880619024606 (Hartree)  NormRD=  0.0000000000071
 SCF=  18  Eeigen=-563.9880619072285 (Hartree)  NormRD=  0.0000000000071
 SCF=  19  Eeigen=-563.9880619119908 (Hartree)  NormRD=  0.0000000000071
 SCF=  20  Eeigen=-563.9880619167419 (Hartree)  NormRD=  0.0000000000071
 SCF=  21  Eeigen=-563.9880619214844 (Hartree)  NormRD=  0.0000000000071
 SCF=  22  Eeigen=-563.9880619262196 (Hartree)  NormRD=  0.0000000000070
 SCF=  23  Eeigen=-563.9880619309473 (Hartree)  NormRD=  0.0000000000070
 SCF=  24  Eeigen=-563.9880619356665 (Hartree)  NormRD=  0.0000000000070
 SCF=  25  Eeigen=-563.9880619403773 (Hartree)  NormRD=  0.0000000000070
 SCF=  26  Eeigen=-563.9880619450788 (Hartree)  NormRD=  0.0000000000070
 SCF=  27  Eeigen=-563.9880619497733 (Hartree)  NormRD=  0.0000000000070
 SCF=  28  Eeigen=-563.9880619544589 (Hartree)  NormRD=  0.0000000000070
 SCF=  29  Eeigen=-563.9880619591390 (Hartree)  NormRD=  0.0000000000069
 SCF=  30  Eeigen=-563.9880619638061 (Hartree)  NormRD=  0.0000000000069
 SCF=  31  Eeigen=-563.9880619684677 (Hartree)  NormRD=  0.0000000000069
 SCF=  32  Eeigen=-563.9880619731207 (Hartree)  NormRD=  0.0000000000069
 SCF=  33  Eeigen=-563.9880619777656 (Hartree)  NormRD=  0.0000000000069
 SCF=  34  Eeigen=-563.9880619824052 (Hartree)  NormRD=  0.0000000000069
 SCF=  35  Eeigen=-563.9880619870341 (Hartree)  NormRD=  0.0000000000069
 SCF=  36  Eeigen=-563.9880619916545 (Hartree)  NormRD=  0.0000000000068
 SCF=  37  Eeigen=-563.9880619962665 (Hartree)  NormRD=  0.0000000000068
 SCF=  38  Eeigen=-563.9880620008732 (Hartree)  NormRD=  0.0000000000068
 SCF=  39  Eeigen=-563.9880620054709 (Hartree)  NormRD=  0.0000000000068
 SCF=  40  Eeigen=-563.9880620100588 (Hartree)  NormRD=  0.0000000000068
 SCF=  41  Eeigen=-563.9880620146412 (Hartree)  NormRD=  0.0000000000068
 SCF=  42  Eeigen=-563.9880620192156 (Hartree)  NormRD=  0.0000000000068
 SCF=  43  Eeigen=-563.9880620237803 (Hartree)  NormRD=  0.0000000000067
 SCF=  44  Eeigen=-563.9880620283374 (Hartree)  NormRD=  0.0000000000067
 SCF=  45  Eeigen=-563.9880620328869 (Hartree)  NormRD=  0.0000000000067
 SCF=  46  Eeigen=-563.9880620374291 (Hartree)  NormRD=  0.0000000000067
 SCF=  47  Eeigen=-563.9880620419618 (Hartree)  NormRD=  0.0000000000067
 SCF=  48  Eeigen=-563.9880620464910 (Hartree)  NormRD=  0.0000000000067
 SCF=  49  Eeigen=-563.9880620510080 (Hartree)  NormRD=  0.0000000000067
 SCF=  50  Eeigen=-563.9880620555190 (Hartree)  NormRD=  0.0000000000066
 SCF=  51  Eeigen=-563.9880620600211 (Hartree)  NormRD=  0.0000000000066
 SCF=  52  Eeigen=-563.9880620645168 (Hartree)  NormRD=  0.0000000000066
 SCF=  53  Eeigen=-563.9880620690027 (Hartree)  NormRD=  0.0000000000066
 SCF=  54  Eeigen=-563.9880620734818 (Hartree)  NormRD=  0.0000000000066
 SCF=  55  Eeigen=-563.9880620779546 (Hartree)  NormRD=  0.0000000000066
 SCF=  56  Eeigen=-563.9880620824176 (Hartree)  NormRD=  0.0000000000066
 SCF=  57  Eeigen=-563.9880620868747 (Hartree)  NormRD=  0.0000000000066
 SCF=  58  Eeigen=-563.9880620913241 (Hartree)  NormRD=  0.0000000000065
 SCF=  59  Eeigen=-563.9880620957659 (Hartree)  NormRD=  0.0000000000065
 SCF=  60  Eeigen=-563.9880621001979 (Hartree)  NormRD=  0.0000000000000

*****************************************************
 Eigenvalues (Hartree) in the all electron calculation
*****************************************************

                         j=l+1/2                j=l-1/2
 n=  1  l=  0      -196.5261997848718     -196.5261997848718
 n=  2  l=  0       -22.0680475181952      -22.0680475181952
 n=  2  l=  1       -18.3723467150902      -18.6322937514404
 n=  3  l=  0        -2.5632549996754       -2.5632549996754
 n=  3  l=  1        -1.6029874106754       -1.6338310096939
 n=  3  l=  2        -0.1961406370672       -0.1985676097077
 n=  4  l=  0        -0.1783092319255       -0.1783092319255


*****************************************************
 Energies (Hartree) in the all electron calculation 
*****************************************************

 Eeigen =     -563.9880621001979
 Ekin   =      957.2398638909700
 EHart  =      397.2336138872300
 Exc    =      -43.1723046688482
 Eec    =    -2258.5628848862707
 Etot   = Ekin + EHart + Exc + Eec
 Etot   =     -947.2617117769188


***********************************************************
** DATA for factorized norm conserving pseudo potentials **
***********************************************************

j.dependent.pseudo.potentials   on

<VPS> L=0, dif of log deris for all electrons =    4.9490085516    4.9490085516
<VPS> L=0, dif of log deris for semi local    =  983.9119790048  983.9119790048
<VPS> L=1, dif of log deris for all electrons =    0.1260817005    0.2957205990
<VPS> L=1, dif of log deris for semi local    =   66.3163842702 204828.4446661940
<VPS> L=2, dif of log deris for all electrons =    3.4933957250    2.3095953751
<VPS> L=2, dif of log deris for semi local    = 1452.3359018523 1523.1376649284
<VPS> L=3, dif of log deris for all electrons =    0.0000505810    0.0130730468
<VPS> L=3, dif of log deris for semi local    =    0.3130436590    0.3287923216

<project.energies
10
 0    1.00000000000000e+00   1.00000000000000e+00
 0    1.00000000000000e+00   1.00000000000000e+00
 1   -1.00000000000000e+00  -1.00000000000000e+00
 1    1.00000000000000e+00   1.00000000000000e+00
 2   -1.00000000000000e+00  -1.00000000000000e+00
 2   -1.00000000000000e+00  -1.00000000000000e+00
 3   -1.00000000000000e+00  -1.00000000000000e+00
 3   -1.00000000000000e+00  -1.00000000000000e+00
 3    1.00000000000000e+00   1.00000000000000e+00
 3   -1.00000000000000e+00  -1.00000000000000e+00
project.energies>

<Pseudo.Potentials
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3.13167134268537e+00 2.29122417665718e+01  -5.67382281203975e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
3.15411422845691e+00 2.34322722563841e+01  -5.54790412928123e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
3.17655711422846e+00 2.39641056816355e+01  -5.42477994945224e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
3.19900000000000e+00 2.45080099290896e+01  -5.30438825437636e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
Pseudo.Potentials>


***********************************************************
**            Core electron densities for PCC            **
***********************************************************
<density.PCC
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1.35868336673347e+00 3.89106681967025e+00  1.60101417547382e-08
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1.40356913827655e+00 4.06969939610736e+00  1.28164656554426e-08
1.42601202404810e+00 4.16206782482367e+00  1.14350389471954e-08
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1.96464128256513e+00 7.13235363161504e+00  2.48881970687718e-10
1.98708416833667e+00 7.29423396573296e+00  2.00106778118282e-10
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2.03196993987976e+00 7.62910043470414e+00  1.27223231769076e-10
2.05441282565130e+00 7.80225524322553e+00  1.00583464386117e-10
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2.09929859719439e+00 8.16044414634886e+00  6.17834825798175e-11
2.12174148296593e+00 8.34565866222845e+00  4.79934170102330e-11
2.14418436873747e+00 8.53507692195792e+00  3.70564697528862e-11
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2.25639879759519e+00 9.54864058839247e+00  9.25772826764882e-12
2.27884168336673e+00 9.76536247413426e+00  6.88015336662634e-12
2.30128456913828e+00 9.98700321458890e+00  5.07906848114860e-12
2.32372745490982e+00 1.02136744511423e+01  3.72408366179584e-12
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2.36861322645291e+00 1.06825677050114e+01  1.96092972225455e-12
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2.43594188376753e+00 1.14265761530398e+01  7.10172607003072e-13
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2.61548496993988e+00 1.36738461744950e+01  3.37952597039175e-14
2.63792785571142e+00 1.39841962919643e+01  2.22612819867146e-14
2.66037074148297e+00 1.43015903087275e+01  1.45370632166428e-14
2.68281362725451e+00 1.46261880975040e+01  9.40946091540818e-15
2.70525651302605e+00 1.49581531595840e+01  6.03588983990211e-15
2.72769939879759e+00 1.52976527071845e+01  3.83646074136051e-15
2.75014228456914e+00 1.56448577476753e+01  2.41576616016805e-15
2.77258517034068e+00 1.59999431697153e+01  1.50672097957714e-15
2.79502805611222e+00 1.63630878313457e+01  9.30638452431513e-16
2.81747094188377e+00 1.67344746500808e+01  5.69132015169990e-16
2.83991382765531e+00 1.71142906950446e+01  3.44540086187282e-16
2.86235671342685e+00 1.75027272811982e+01  2.06428298522220e-16
2.88479959919840e+00 1.78999800657063e+01  1.22378911477242e-16
2.90724248496994e+00 1.83062491464900e+01  7.17718365519340e-17
2.92968537074148e+00 1.87217391630175e+01  4.16304363938665e-17
2.95212825651303e+00 1.91466593993816e+01  2.38766639789210e-17
2.97457114228457e+00 1.95812238897169e+01  1.35374066036218e-17
2.99701402805611e+00 2.00256515260100e+01  7.58554496289142e-18
3.01945691382766e+00 2.04801661683561e+01  4.19966733502042e-18
3.04189979959920e+00 2.09449967577184e+01  2.29669862746113e-18
3.06434268537074e+00 2.14203774312466e+01  1.24032433915413e-18
3.08678557114228e+00 2.19065476402127e+01  6.61281876247961e-19
3.10922845691383e+00 2.24037522706237e+01  3.47962807236465e-19
3.13167134268537e+00 2.29122417665718e+01  1.80653066223147e-19
3.15411422845691e+00 2.34322722563841e+01  9.25107422652508e-20
3.17655711422846e+00 2.39641056816355e+01  4.67130211727994e-20
3.19900000000000e+00 2.45080099290896e+01  2.32515913306715e-20
density.PCC>