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***************************************************
                    Input file
***************************************************

#
# File Name
#

System.CurrrentDir    ./             # default=./
System.Name            O_CA13
Log.print              OFF           # ON|OFF

System.UseRestartfile  yes           # NO|YES, default=NO
System.Restartfile     O_CA13       # default=null

#
# Calculation type
#

eq.type                dirac         # sch|sdirac|dirac 
calc.type              vps           # ALL|VPS|PAO
xc.type                LDA           # LDA|GGA

#
# Atom
#

AtomSpecies             8
max.ocupied.N           2
total.electron         8.0
valence.electron       6.0 
<ocupied.electrons 
 1   2.0
 2   2.0  4.0
ocupied.electrons>

#
# parameters for solving 1D-differential equations
#

grid.xmin             -7.8           # default=-7.0 rmin(a.u.)=exp(grid.xmin)
grid.xmax              3.0           # default= 2.5 rmax(a.u.)=exp(grid.xmax)
grid.num             10000           # default=4000
grid.num.output        500           # default=2000

#
# SCF
#

scf.maxIter             60           # default=40            
scf.Mixing.Type        simple        # Simple|GR-Pulay 
scf.Init.Mixing.Weight 0.10          # default=0.300 
scf.Min.Mixing.Weight  0.001         # default=0.001 
scf.Max.Mixing.Weight  0.200         # default=0.800 
scf.Mixing.History      7            # default=5
scf.Mixing.StartPulay   6            # default=6
scf.criterion         1.0e-13        # default=1.0e-9

#
# Pseudo potetial, cutoff (A.U.)
#

vps.type               MBK            # BHS|TM|MBK        
number.vps              5
<pseudo.NandL
 0  2  0  0.70  0.0
 1  2  1  1.20  0.0
 2  3  0  1.10  0.0
 3  3  1  1.20  0.3
 4  3  2  0.90  0.0
pseudo.NandL> 

Blochl.projector.num    3            # default=1 which means KB-form
local.type            polynomial     # Simple|Polynomial
local.part.vps          1            # default=0
local.cutoff           1.10          # default=smallest_cutoff_vps
local.origin.ratio     3.30          # default=3.0
log.deri.RadF.calc      on           # ON|OFF
log.deri.MinE          -2.0          # default=-3.0 (Hartree)
log.deri.MaxE           2.0          # default= 2.0 (Hartree) 
log.deri.num             80          # default=50
<log.deri.R
 0  1.9 1.9
 1  1.9 1.9
 2  1.9 1.9
log.deri.R>
ghost.check             off          # ON|OFF
 
#
# Core electron density for partial core correction
#   pcc.ratio=rho_core/rho_V,
#   pcc.ratio.origin = rho_core(orgin)/rho_core(ip)
#

charge.pcc.calc         on           # ON|OFF
pcc.ratio              0.15          # default=1.0     
pcc.ratio.origin       7.00          # default=6.0     

#
# Pseudo atomic orbitals
#

maxL.pao                4            # default=2
num.pao                20            # default=7 
radial.cutoff.pao      6.0           # default=5.0 (Bohr)
height.of.wall    20000.0            # default=4000.0 (Hartree)
rising.edge           0.2            # default=0.5(Bohr),r1=rc-rising.edge
search.LowerE       -3.000           # default=-3.000 (Hartree)
search.UpperE       75.000           # default=20.000 (Hartree)
num.of.partition      2000           # default=300
matching.point.ratio  0.67           # default=0.67









*****************************************************
    SCF history in all electron calculations      
*****************************************************


*****************************************************
 Eigenvalues (Hartree) in the all electron calculation
*****************************************************

                         j=l+1/2                j=l-1/2
 n=  1  l=  0       -18.7733800005400      -18.7733800005400
 n=  2  l=  0        -0.8727186080804       -0.8727186080804
 n=  2  l=  1        -0.3374246231442       -0.3387772905943


*****************************************************
 Energies (Hartree) in the all electron calculation 
*****************************************************

 Eeigen =      -40.6446010447178
 Ekin   =       74.2781505203160
 EHart  =       36.3524208539454
 Exc    =       -7.7716274494606
 Eec    =     -177.3841733771505
 Etot   = Ekin + EHart + Exc + Eec
 Etot   =      -74.5252294523497


***********************************************************
** DATA for factorized norm conserving pseudo potentials **
***********************************************************

j.dependent.pseudo.potentials   on

<VPS> L=0, dif of log deris for all electrons =    1.2217018693    1.2217018693
<VPS> L=0, dif of log deris for semi local    =    0.9029865642    0.9029865642
<VPS> L=1, dif of log deris for all electrons =   10.9930386002    2.7838935586
<VPS> L=1, dif of log deris for semi local    =  243.3120550099   50.3377782361
<VPS> L=2, dif of log deris for all electrons =    0.0000128638    0.0000116788
<VPS> L=2, dif of log deris for semi local    =    0.0000162723    0.0000162984

<project.energies
 7
 0    1.00000000000000e+00   1.00000000000000e+00
 0    1.00000000000000e+00   1.00000000000000e+00
 1   -1.00000000000000e+00  -1.00000000000000e+00
 1    1.00000000000000e+00   1.00000000000000e+00
 2    1.00000000000000e+00   1.00000000000000e+00
 2    1.00000000000000e+00   1.00000000000000e+00
 2    1.00000000000000e+00   1.00000000000000e+00
project.energies>

<Pseudo.Potentials
-7.80000000000000e+00 4.09734978979787e-04  -1.79949718776807e+01   -3.04431912060074e+01 -3.04431912060074e+01  1.63433875429500e+01 1.63433875429500e+01  9.22450901173645e-02 9.22423748934419e-02  3.84243247390023e-02 3.85271180679705e-02  1.24350378235932e-06 1.24280025458052e-06  -7.38222334167415e-07 -7.37409263905683e-07  -1.47498718294513e-06 -1.47467966448290e-06
-7.77835871743487e+00 4.18698814035733e-04  -1.79949718776807e+01   -3.04431757812816e+01 -3.04431757812816e+01  1.63433872535843e+01 1.63433872535843e+01  9.42631374236799e-02 9.42603628245656e-02  3.92649347622532e-02 3.93699769060932e-02  1.29850760078347e-06 1.29777295395612e-06  -7.70876008858960e-07 -7.70026974039379e-07  -1.54023023930713e-06 -1.53990911845797e-06
-7.75671743486974e+00 4.27858752287726e-04  -1.79949718776807e+01   -3.04431596744298e+01 -3.04431596744298e+01  1.63433869515368e+01 1.63433869515368e+01  9.63253330091071e-02 9.63224977375992e-02  4.01239346166309e-02 4.02312747723045e-02  1.35594440045992e-06 1.35517725810127e-06  -8.04974045822618e-07 -8.04087455619298e-07  -1.60835919330904e-06 -1.60802386840467e-06
-7.73507615230461e+00 4.37219083915501e-04  -1.79949718776807e+01   -3.04431428552774e+01 -3.04431428552774e+01  1.63433866362437e+01 1.63433866362437e+01  9.84326426551980e-02 9.84297453858330e-02  4.10017265975996e-02 4.11114150383107e-02  1.41592179942454e-06 1.41512072416633e-06  -8.40580332956214e-07 -8.39654526175584e-07  -1.67950169726145e-06 -1.67915154002052e-06
-7.71343486973948e+00 4.46784192955712e-04  -1.79949718776807e+01   -3.04431252923155e+01 -3.04431252923155e+01  1.63433863071172e+01 1.63433863071172e+01  1.00586053268223e-01 1.00583092646666e-01  4.18987218002479e-02 4.20108098989843e-02  1.47855217598908e-06 1.47771566688441e-06  -8.77761584063996e-07 -8.76794826032218e-07  -1.75379104996721e-06 -1.75342540431811e-06
-7.69179358717435e+00 4.56558559355259e-04  -1.79949718776807e+01   -3.04431069526416e+01 -3.04431069526416e+01  1.63433859635426e+01 1.63433859635426e+01  1.02786573341064e-01 1.02783547983485e-01  4.28153403117017e-02 4.29298805652922e-02  1.54395287930350e-06 1.54307936901459e-06  -9.16587463851077e-07 -9.15577943163661e-07  -1.83136644648734e-06 -1.83098462733910e-06
-7.67015230460922e+00 4.66546761069526e-04  -1.79949718776807e+01   -3.04430878018977e+01 -3.04430878018977e+01  1.63433856048787e+01 1.63433856048787e+01  1.05035233425192e-01 1.05032141917632e-01  4.37520114077408e-02 4.38690574614377e-02  1.61224644923223e-06 1.61133430109381e-06  -9.57130718446199e-07 -9.56076543573945e-07  -1.91237323895560e-06 -1.91197453091420e-06
-7.64851102204409e+00 4.76753476206530e-04  -1.79949718776807e+01   -3.04430678042062e+01 -3.04430678042062e+01  1.63433852304559e+01 1.63433852304559e+01  1.07333086612956e-01 1.07329927510673e-01  4.47091737537086e-02 4.48287804263081e-02  1.68356084595638e-06 1.68260835090918e-06  -9.99467311697630e-07 -9.98366507442334e-07  -1.99696320892998e-06 -1.99654686495818e-06
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2.93407615230461e+00 1.88041229624418e+01  -3.19078960088615e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
2.95571743486974e+00 1.92155036481396e+01  -3.12247865570150e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
2.97735871743487e+00 1.96358841722719e+01  -3.05563016521434e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
2.99900000000000e+00 2.00654614256862e+01  -2.99021282000600e-01   0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00  0.00000000000000e+00 0.00000000000000e+00
Pseudo.Potentials>


***********************************************************
**            Core electron densities for PCC            **
***********************************************************
<density.PCC
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1.80872945891784e+00 6.10268878761963e+00  3.13082042478088e-11
1.83037074148297e+00 6.23619824738360e+00  2.38181445083416e-11
1.85201202404810e+00 6.37262851410117e+00  1.80362382727096e-11
1.87365330661323e+00 6.51204348671457e+00  1.35932056995281e-11
1.89529458917836e+00 6.65450846209305e+00  1.01949395608732e-11
1.91693587174349e+00 6.80009016561547e+00  7.60820456386179e-12
1.93857715430862e+00 6.94885678242205e+00  5.64887475996595e-12
1.96021843687375e+00 7.10087798934981e+00  4.17225728876649e-12
1.98185971943888e+00 7.25622498756660e+00  3.06517804835771e-12
2.00350100200401e+00 7.41497053591918e+00  2.23955234303459e-12
2.02514228456914e+00 7.57718898501078e+00  1.62716751701486e-12
2.04678356713427e+00 7.74295631202418e+00  1.17547319041430e-12
2.06842484969940e+00 7.91235015630664e+00  8.44200622366855e-13
2.09006613226453e+00 8.08544985573338e+00  6.02661284826727e-13
2.11170741482966e+00 8.26233648386647e+00  4.27599226633128e-13
2.13334869739479e+00 8.44309288792676e+00  3.01492752786771e-13
2.15498997995992e+00 8.62780372759648e+00  2.11218785375634e-13
2.17663126252505e+00 8.81655551467069e+00  1.47008412965095e-13
2.19827254509018e+00 9.00943665357634e+00  1.01634928855038e-13
2.21991382765531e+00 9.20653748277754e+00  6.97864199260092e-14
2.24155511022044e+00 9.40795031708689e+00  4.75839757007891e-14
2.26319639278557e+00 9.61376949090233e+00  3.22140879050527e-14
2.28483767535070e+00 9.82409140238986e+00  2.16500214130502e-14
2.30647895791583e+00 1.00390145586330e+01  1.44420497375240e-14
2.32812024048096e+00 1.02586396217699e+01  9.56062990990511e-15
2.34976152304609e+00 1.04830694561397e+01  6.27998985582585e-15
2.37140280561122e+00 1.07124091764605e+01  4.09234402907491e-15
2.39304408817635e+00 1.09467661970612e+01  2.64515073379448e-15
2.41468537074148e+00 1.11862502821905e+01  1.69557271302996e-15
2.43632665330661e+00 1.14309735974265e+01  1.07768279935090e-15
2.45796793587174e+00 1.16810507622108e+01  6.79036361789163e-16
2.47960921843687e+00 1.19365989035321e+01  4.24072186888787e-16
2.50125050100200e+00 1.21977377107842e+01  2.62449913562991e-16
2.52289178356713e+00 1.24645894918242e+01  1.60925992737847e-16
2.54453306613226e+00 1.27372792302571e+01  9.77440415743225e-17
2.56617434869739e+00 1.30159346439731e+01  5.87960120977488e-17
2.58781563126252e+00 1.33006862449667e+01  3.50191799823711e-17
2.60945691382766e+00 1.35916674004629e+01  2.06475956350232e-17
2.63109819639279e+00 1.38890143953824e+01  1.20487253518039e-17
2.65273947895792e+00 1.41928664961717e+01  6.95698839413556e-18
2.67438076152305e+00 1.45033660160309e+01  3.97381982210977e-18
2.69602204408818e+00 1.48206583815678e+01  2.24490314819465e-18
2.71766332665331e+00 1.51448922009105e+01  1.25395808638441e-18
2.73930460921844e+00 1.54762193333097e+01  6.92397306171570e-19
2.76094589178357e+00 1.58147949602646e+01  3.77835758174071e-19
2.78258717434870e+00 1.61607776582037e+01  2.03709730785728e-19
2.80422845691383e+00 1.65143294727562e+01  1.08483644503725e-19
2.82586973947896e+00 1.68756159946488e+01  5.70482459531083e-20
2.84751102204409e+00 1.72448064372617e+01  2.96159772385957e-20
2.86915230460922e+00 1.76220737158822e+01  1.51735903383715e-20
2.89079358717435e+00 1.80075945286920e+01  7.67002416965335e-21
2.91243486973948e+00 1.84015494395260e+01  3.82393960426077e-21
2.93407615230461e+00 1.88041229624418e+01  1.87965394548398e-21
2.95571743486974e+00 1.92155036481396e+01  9.10582910947626e-22
2.97735871743487e+00 1.96358841722719e+01  4.34519241367009e-22
2.99900000000000e+00 2.00654614256862e+01  2.04089540481458e-22
density.PCC>