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/usr/share/gromacs/top/charmm27.ff/aminoacids.r2b is in gromacs-data 5.0.2-1.

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; rtp residue to rtp building block table
;GMX   Force-field
HISD	HSD
HIS1	HSD
HISE	HSE
HISH	HSP
LYSN	LSN
ASPH	ASPP
GLUH	GLUP
HEM	HEME