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/usr/share/avogadro/fragments/coordination/5-square-pyramidal.cml is in avogadro-data 1.0.3-10.1.

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The actual contents of the file can be viewed below.

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<molecule>
 <atomArray>
  <atom id="a1" elementType="S" x3="-0.404487" y3="0.310293" z3="0.271055"/>
  <atom id="a2" elementType="F" x3="-1.387820" y3="-0.263361" z3="-1.005676"/>
  <atom id="a3" elementType="F" x3="0.173190" y3="-0.401702" z3="1.715100"/>
  <atom id="a4" elementType="F" x3="0.106858" y3="1.928912" z3="0.061578"/>
  <atom id="a5" elementType="F" x3="-1.885256" y3="0.169764" z3="1.115781"/>
  <atom id="a6" elementType="F" x3="0.672698" y3="-0.834895" z3="-0.402895"/>
 </atomArray>
 <bondArray>
  <bond atomRefs2=" a1  a2" order=" 1"/>
  <bond atomRefs2=" a1  a3" order=" 1"/>
  <bond atomRefs2=" a1  a4" order=" 1"/>
  <bond atomRefs2=" a1  a5" order=" 1"/>
  <bond atomRefs2=" a1  a6" order=" 1"/>
 </bondArray>
</molecule>