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/usr/share/avogadro/builder/amino/d-tyr.zmat is in avogadro-data 1.0.3-10.1.

This file is owned by root:root, with mode 0o644.

The actual contents of the file can be viewed below.

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N    0.000000    0.000000    0.000000     0   0   0   -0.244958  N 
C    1.480833    0.000000    0.000000     1   0   0    0.091600  CA
C    1.528790  106.214453    0.000000     2   1   0    0.218041  C 
O    1.205711  130.378984   55.542040     3   2   1   -0.287197  O 
C    1.546546  115.506141  120.238516     2   1   3   -0.003640  CB
H    1.111072  109.874924  187.435781     5   2   1    0.033301  HB1
H    1.110411  110.062040  302.232678     5   2   1    0.033301  HB2
C    1.501288  111.057666   65.667887     5   2   1   -0.045196  CG
C    1.406912  120.233635  255.084816     8   5   2   -0.055064  CD2
H    1.090664  120.006566  359.768808     9   8   5    0.062142  HD2
C    1.391500  120.722244  180.146715     9   8   5   -0.019921  CE2
H    1.088152  121.962416  179.702625    11   9   8    0.065402  HE2
C    1.405748  118.379457  359.936433    11   9   8    0.116879  CZ
C    1.401779  122.162812    0.044131    13  11   9   -0.019921  CE1
H    1.085244  121.108719  179.923895    14  13  11    0.065402  HE1
C    1.396118  118.300278    0.064659    14  13  11   -0.055064  CD1
H    1.090332  119.227292  179.816935    16  14  13    0.062142  HD1
O    1.373933  115.150104  180.035788    13  11   9   -0.506769  OH
H    0.988327  112.215925  180.022664    18  13  11    0.292132  HH 
H    1.127794  107.867120  243.306007     2   1   3    0.056017  HA 
H    1.017797  110.484171  176.007696     1   2   3    0.141371  H